Titanium trichloride catalyst component for propylene polymerization

• US 4,211,670 A
• Filed: 01/25/1979
• Issued: 07/08/1980
• Est. Priority Date: 01/25/1979
• Status: Expired due to Term

• Current Assignee: Himont USA Incorporated
• Original Assignee: Hercules Incorporated (Ashland Global Holdings, Inc.)
• Inventors: Vandenberg, Edwin J.
• Primary Examiner(s): Garvin, Patrick
• Application Number:
  US06/006,970
• Time in Patent Office: 530 Days
• Field of Search: 252/429 B
• US Class Current: 502/107
• CPC Class Codes: C08F 10/06 Propene
• CPC Class Codes: C08F 4/651 Pretreating with non-metals or metal-free compounds

Abstract

An improved titanium trichloride catalyst component is prepared by treating a crude titanium trichloride composition with two different electron donor compounds via successive treatment with first one of the donor compounds and then with the other. The treated composition provides greater stereospecificity in the polymerization and copolymerization of propylene.

Claims

1. A process for preparing a titanium trichloride composition of improved stereospecificity for use as a catalyst component in the polymerization of propylene, said process consisting essentially of the steps of 1) washing a crude titanium trichloride composition, prepared by reducing titanium tetrachloride with an organoaluminum compound, with an inert diluent, 2) suspending the washed titanium trichloride solids in an inert diluent containing a first electron donor compound, 3) maintaining said solids in suspension at a temperature of from about room temperature up to the boiling point of the diluent or the donor compound for a period of from about 15 minutes to about 100 hours, 4) separating the solids from the inert diluent containing the electron donor compound, 5) washing the separated solids with an inert diluent, and then 6) repeating steps 2, 3, 4 and 5 using a second electron donor compound in place of said first electron donor compound, said first electron donor compound being selected from the group consisting of dialkyl, diaryl and alkyl aryl ethers and thioethers wherein each alkyl group contains from one to ten carbon atoms and each aryl group contains from six to 12 carbon atoms, said second electron donor compound being selected from the group consisting of aromatic carboxylic acids containing seven to 12 carbon atoms;

alkyl and aryl esters of aliphatic carboxylic acids, said esters containing four to 24 carbon atoms;

alkyl and aryl esters of aromatic carboxylic acids, said esters containing eight to 24 carbon atoms;

alkyl alkanesulfonates;

alkyl arylsulfonates;

ketoesters;

chloroesters;

ortho esters;

N,N-dialkyl amides of aliphatic carboxylic acids, said amides containing four to 24 carbon atoms;

N,N-dialkyl amides of aromatic carboxylic acids, said amides containing nine to 24 carbon atoms;

N-alkyl lactams containing five to 15 carbon atoms;

aliphatic ketones containing three to 15 carbon atoms;

aromatic ketones containing eight to 15 carbon atoms;

halogenated dialkyl ethers containing two to 20 carbon atoms;

diethers containing three to 20 carbon atoms;

dialkyl thioethers, sulfoxides, sulfones and disulfides containing two to 20 carbon atoms;

aromatic sulfides or diaryl thioethers containing 12 to 20 carbon atoms;

sulfoxides, sulfones and disulfides corresponding to said diaryl thioethers;

phosphines and phosphite and phosphate esters containing three to 21 carbon atoms;

metal coordinating hydrocarbons having multiple double bonds and containing seven to 28 carbon atoms;

aliphatic nitriles containing two to 12 carbon atoms;

aromatic nitriles containing seven to 12 carbon atoms;

aliphatic amines containing one to 20 carbon atoms; and

heterocyclic amines possessing aromatic characteristics and containing three to 15 carbon atoms, said inert diluent being selected from the group consisting of a) saturated aliphatic hydrocarbons having from three to 20 carbon atoms, b) aromatic hydrocarbons having from six to 20 carbon atoms, said aromatic hydrocarbons being either unsubstituted or substituted by alkyl radicals having from one to 20 carbon atoms, aralkyl radicals having from seven to 15 carbon atoms or aryl radicals having from six to eight carbon atoms, c) halogenated aromatic hydrocarbons having from six to 16 carbon atoms, and d) mixtures thereof, with the proviso that, when a thioether is used as either the first or the second electron donor compound in said process, a thioether is not also used as the other electron donor compound in the process.

2. The process of claim 1 wherein the first electron donor compound is a dialkyl ether wherein each alkyl group contains from one to ten carbon atoms.

3. The process of claim 2 wherein the dialkyl ether is diethyl ether.

4. The process of claim 2 wherein the dialkyl ether is di-n-butyl ether.

5. The process of claim 1 wherein the first electron donor compound is a dialkyl thioether wherein each alkyl group contains from one to ten carbon atoms.

6. The process of claim 5 wherein the dialkyl thioether is di-n-butyl thioether.

7. The process of claim 1 wherein the second electron donor compound is an alkyl ester of an aromatic carboxylic acid, said ester containing eight to 24 carbon atoms.

8. The process of claim 7 wherein said ester is ethyl benzoate.

9. A process of claim 1 wherein the second electron donor compound is a dialkyl thioether wherein each alkyl group contains from one to ten carbon atoms.

10. The process of claim 9 wherein the dialkyl thioether is di-n-butyl thioether.