Process for the production of polyisocyanate-polyester-silicate plastic

• US 4,211,848 A
• Filed: 01/26/1979
• Issued: 07/08/1980
• Est. Priority Date: 06/14/1972
• Status: Expired due to Term

• Current Assignee: David H. Blount
• Original Assignee: David H. Blount
• Inventors: Blount, David H.
• Primary Examiner(s): Marquis, Melvyn I.
• Application Number:
  US06/006,585
• Time in Patent Office: 529 Days
• Field of Search: 525/28, 525/440, 525/455, 260/18 TN, 260/18 S, 260/858, 260/859 R, 260/37 N, 521/100, 521/116, 521/131, 521/133, 521/99, 521/154, 521/172, 528/26, 528/28, 528/39, 528/44, 528/46, 528/48, 528/50, 528/55, 528/56, 528/58, 528/80, 528/81, 528/83, 528/84, 528/425
• US Class Current: 521/154
• CPC Class Codes: C01B 33/00 Silicon; Compounds thereof C01B6/00, C01B21/00, C01B23/00 take precedence; persilicates C01B15/14; carbides C01B32/956
• CPC Class Codes: C08G 18/0885 using additives, e.g. absorbing agents
• CPC Class Codes: C08G 18/68 Unsaturated polyesters

Abstract

A polyisocyanate is reacted with an unsaturated polyester containing a vinyl monomer and a water-binding agent, then cured with water containing an oxidated silicon compound and an initiator such as a peroxide to produce solid or cellular solid inorganic-organic plastic.

Claims

1. The process for the production of polyisocyanate-polyester silicate plastic by mixing the following components:

(a) 20 to 70 parts by weight of an organic polyisocyanate or polythiocyanate;

(b) 3 to 80 parts by weight of an unsaturated polyester resin;

(c) catalytic amount of a free-radical initiator to polymerize the unsaturated polyester resin;

(d) 0% to 100% by weight of an inorganic water-binding component, said water-binding component being capable of absorbing water to form a solid or a gel, and based on the total weight of components (a) and (b);

(e) 10% to 100% by weight of a polyisocyanate curing agent, based on the total weight of components (a), (b) and (d), but with the proviso that the polyisocyanate curing agent is added last.

2. The process of claim 1 wherein the organic polyisocyanate is selected from the group consisting of tolylene-2,4 and -2,6-diisocyanate, polyphenyl-polymethylene-isocyanates and mixtures thereof.

3. The process of claim 1 wherein the water-binding agent is selected from the group consisting of a hydraulic cement, synthetic anhydrite, gypsum or burnt lime.

4. The process of claim 1 wherein the initiator is selected from the group consisting of an organic peroxide, an inorganic peroxide, alkali metal persulfate, ammonium persulfate, a redox system and a peroxide with a metal catalyst.

5. The process of claim 1 wherein the curing agent is selected from the group consisting of water, when an oxidated silicon compound has been added to other components;

water containing 10% to 70% by weight of an alkali metal silicate, selected from the group consisting of sodium silicate and potassium silicate;

water containing 10% to 70% by weight of silica sol and mixtures thereof.

6. The process of claim 1 wherein from 0% to 50% by weight, based on the reaction mixture, of a chemically inert blowing agent, boiling within the range of from -25°

C. to 80°

C. is added simultaneously with component (e) and the reaction mixture is allowed to react to completion while foaming.

7. The process of claim 1 wherein the mixture contains 0.001% to 10% by weight, based on the reaction mixture of an activator selected from the group consisting of tertiary amines, organo-metallic compounds and silaamines, and is added with component (e) of claim 1.

8. The process of claim 1 wherein the mixture contains from 0% to 20% by weight of surface-active additives and is added with Component (e).

9. The process of claim 1, wherein the reaction is accompanied by foaming produced by the reaction of water in the curing agent with the polyisocyanate to produce carbon dioxide which acts as the blowing agent.

10. The process of claim 1, wherein inorganic or organic particulate or pulverulent filler materials are added to the reaction mixture before, or with, Component (e).

11. The product of the process of claim 1.

12. The process of claim 1 where, in addition to the polyisocyanate, hardeners are used for the alkali metal silcate, which is water-soluble or is dispersed in water, and are added simultaneously with component (e).

13. The process of claim 1 wherein an oxidated silicon compound, selected from the group consisting of silica, alkali metal silicates, alkaline earth metal silicates, natural silicates containing free silicic acid groups and mixtures thereof, is added in the ratio of oxidated silicon compound to polyisocyanate and unsaturated polyester of 70:

30 to 20;

80 parts by weight to component (a) of claim 1.

14. The process of claim 1, wherein an organic hydroxyl compound is added with the organic polyisocyanate compound in the ratio of 50 to 99 mols of organic polyisocyanate compound to 1 to 50 mols of organic hydroxyl compound.

15. The process of claim 1 wherein the polyisocyanate, unsaturated polyester, water-binding component, initiator, activator and curing agent of claim 1 are simultaneously mixed;

then at a predetermined temperature ranging from 0°

C. to 150°

C., the blowing agent is added to the mixture, thereby producing a polyurethane silicate cellular solid.

16. The process of claim 12 wherein the hardener is selected from the group consisting of mineral acids, hydrogen-containing salts of mineral acids, organic acids, polyfunctional alkylating agents and monofunctional alkylating agents.