Thermoplastic elastomer composition, blends of the composition with olefin plastic, and foamed products of the composition and the blends

• US 4,212,787 A
• Filed: 05/26/1978
• Issued: 07/15/1980
• Est. Priority Date: 05/26/1977
• Status: Expired due to Term

• Current Assignee: Mitsui Petrochemical Industries, Ltd. (Mitsui Chemicals)
• Original Assignee: Mitsui Petrochemical Industries, Ltd. (Mitsui Chemicals)
• Inventors: Matsuda, Akira, Abe, Shunji, Shimizu, Shizuo
• Primary Examiner(s): Seccuro, Carman J.
• Application Number:
  US05/910,086
• Time in Patent Office: 781 Days
• Field of Search: 260/897 A, 260/889, 260/33.6 AQ
• US Class Current: 525/211
• CPC Class Codes: C08J 2323/02 not modified by chemical after treatment
• CPC Class Codes: C08J 9/0061 characterized by the use of several polymeric components
• CPC Class Codes: C08K 5/14 Peroxides
• CPC Class Codes: C08L 2205/03 containing three or more polymers in a blend
• CPC Class Codes: C08L 23/02 not modified by chemical after-treatment
• CPC Class Codes: C08L 23/10 Homopolymers or copolymers of propene
• CPC Class Codes: C08L 23/16 Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
• CPC Class Codes: C08L 23/22 Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
• CPC Class Codes: C08L 2312/00 Crosslinking
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 91/00 Compositions of oils, fats or waxes; Compositions of derivatives thereof

Abstract

Dynamically partially cured composition comprising a peroxide-curable olefin copolymer rubber (such as EDPM) and a peroxide-decomposing olefin plastic (such as PE and PP) is improved by effecting the dynamic heat-treatment with addition of a peroxide-non-curable hydrocarbon rubber (such as PIB) and/or a mineral oil softener (process oil). The dynamic heat-treatment is preferably carried out not only in the presence of an organic peroxide but also in the presence of divinyl benzene. The elastomeric composition is thermoplastic and, with or without further blending with an olefin plastic, is processable by techniques conventionally used for thermoplastic resins. This elastomer composition and blends of the elastomer composition and olefin plastic can be used for producing foamed product in combination with decomposition type foaming agent (such as azodicarbonamide).

Claims

1. A thermoplastic composition which comprises:

100 to 5 parts by weight of (A) a partially cured elastomer composition obtained by dynamic heat-treatment, in the presence of an organic peroxide, of a mixture of 100 to 40 parts by weight of (a) peroxide-curable olefin copolymer rubber selected from the group consisting of ethylene-propylene copolymer rubber and ethylene-propylene-non conjugated diene terpolymer rubber,

0 to 60 parts by weight of (b) a peroxide-decomposing olefin plastic selected from the group consisting of isotactic polypropylene and propylene- alpha olefin copolymer.

wherein the sum of the component (a) and the component (b) is 100 parts by weight, and

5 to 100 parts by weight of (c) at least one member of peroxide-non curable hydrocarbon rubbery material selected from the group consisting of polyisobutylene and butyl rubber, and (d) mineral oil softener; and

0 to 95 parts by weight of (B) an olefin plastic selected from the group consisting of hompolymers of an alpha olefin selected from the group consisting of ethylene, propylene, 1-butene, 1-pentene, 3-methyl-1-butene, 1-hexene, 3-methyl-1-pentene, 4-methyl-1-pentene and 1-octene;

copolymers therebetween; and

copolymers thereof with 15 mole % or less of another copolymerizable monomer;

wherein the sum of the component (b) and the component B account for not less than 5 parts by weight among 100 parts by weight of the final composition.

2. A thermoplastic composition according to claim 1, which comprises a partially cured elastomer composition obtained by dynamic heat-treatment in the presence of an organic peroxide of a mixture ofto 40 parts by weight of said (a) peroxide-curable olefin copolymer rubber,to 60 parts by weight of said (b) peroxide-decomposing olefin plastic,

wherein the sum of said component (a) and said component (b) is 100 parts by weight, and

5 to 100 parts by weight of at least one member of said (c) peroxide-non-curable hydrocarbon rubbery material and said (d) mineral oil softener.

3. A thermoplastic composition according to claim 1, which comprises 100 parts by weight of (A) a partially cured elastomer composition obtained by dynamic heat-treatment in the presence of an organic peroxide of a mixture ofto 5 parts by weight of said (a) peroxide-curable olefin copolymer rubber,

0 to 50 parts by weight of said (b) peroxide-decomposing olefin plastic,

wherein the sum of said component (a) and said component (b) is 100 parts by weight, and

5 to 100 parts by weight of at least one member of said (c) peroxide-non-curable hydrocarbon rubbery material and said (d) mineral oil softener;

and

0 to 95 parts by weight of said (B) olefin plastic, wherein the sum of said component (b) and said component (B) account for not less than 5 parts by weight among 100 parts by weight of the final composition.

4. A thermoplastic composition according to claim 1, which comprises:

5 to 95 parts by weight (A) a partially cured elastomer composition obtained by dynamic heat-treatment in the presence of an organic peroxide of a mixture of 90 to 50 parts by weight of said (a) peroxide curable olefin copolymer rubber,

10 to 50 parts by weight of said (b) peroxide-decomposing olefin plastic,

wherein the sum of said component (a) and said component (b) is 100 parts by weight, and 5 to 50 parts by weight of at least one member of said (c) peroxide non curable hydrocarbon rubbery material and said (d) mineral oil softener; and

95 to 5 parts by weight of said (B) olefin plastic.

5. A composition according to claim 1, 2, 3 or 4, wherein said ethylene-propylene non-conjugated diene copolymer rubber is ethylene-propylene-ethylidene norbornene copolymer rubber.

6. A composition according to claim 1, 2, 3 or 4, wherein the mooney viscosity ML 1+4 (100 c) of the said (a) peroxide curable olefin copolymer rubber is in the range of 40 to 80.

7. A composition according to claim 1, 2, 3 or 4, wherein the (b) peroxide-decomposing olefin plastic is propylene-alpha-olefin copolymer.

8. A composition according to claim 1, 2, 3 or 4, wherein said (c) peroxide-non-curable hydrocarbon rubbery material is mixed in an amount of 5 to 20 parts by weight with 100 parts by weight in total of said component (a) and said component (b).

9. A composition according to claim 1, 2, 3 or 4, wherein said (d) mineral oil softener is mixed in an amount of 10 to 40 parts by weight with 100 parts by weight in total of said component (a) and said component (b).

10. A composition according to claim 1, 2, 3 or 4, wherein the Melt Index (ASTM D-1238-65T) of said (B) olefin plastic is from 10 to 50 measured at 230°

C. when said olefin plastic is a propylene homopolymer or a copolymer wherein the predominant monomer is propylene; and

190°

C. for other of said olefin plastics.

11. A method of producing a thermoplastic composition, which comprises dynamically heat-treating, in the presence of an organic peroxide, a mixture of 100 to 40 parts by weight of (a) a peroxide-curable olefin copolymer rubber selected from the group consisting of ethylene-propylene copolymer rubber and ethylene-propylene-non conjugated diene terpolymer rubber,

0 to 60 parts by weight of (b) a peroxide-decomposing olefin plastic selected from the group consisting of isotactic polypropylene and propylene-alpha olefin copolymer,

wherein the sum of component (a) and component (b) is 100 parts by weight,

5 to 100 parts by weight of at least one member of (c) peroxide-non-curable hydrocarbon rubbery material selected from polyisobutylene and butyl rubber, and (d) mineral oil softeners;

to obtain a thermoplastic elastomer composition (A); and

then, homogeneously blending 100 to 5 parts by weight of said composition (A) and 0 to 95 parts by weight of (B) an olefin plastic selected from the group consisting of homopolymers of an alpha olefin selected from the group consisting of ethylene, propylene, 1-butene, 1-pentene, 3-methyl-1-butene, 1-hexene, 3-methyl-1-pentene, 4-methyl-1-pentene and 1-octene;

copolymers therebetween; and

copolymers thereof with 15 mole % or less of another copolymerizable monomer;

wherein the sum of said component (b) and said component (B) account for not less than 5 parts by weight among 100 parts of the final product.

12. A method according to claim 11, wherein said organic peroxide is 1,3-bis(tert.-butyl peroxyisopropyl) benzene

13. A method according to claim 11, wherein said organic peroxide is used in an amount of 0.05 to 1.0% by weight based on the mixture to be heat-treated.

14. A method according to claim 11, wherein said mixture is heat-treated in the presence of an organic peroxide and divinyl benzene.

15. A method according to claim 14, wherein divinyl benzene is used in amount of 0.1 to 2% by weight based on the mixture to be heat-treated.

16. A method according to claim 14, wherein said organic peroxide is added to said mixture as a dispersion in divinyl benzene.

19. A method according to claim 14, wherein said organic peroxide is added to said mixture as a dispersion in divinyl benzene.

20. A method according to claim 11 or 17, wherein the temperature of said heat-treatment is 150°

to 280°

C.

17. A method of producing a thermoplastic elastomer composition, which comprises dynamically heat-treating, in the presence of an organic peroxide and divinyl benzene, a mixture of 90 to 40 parts by weight of (a) a peroxide-curable olefin copolymer rubber selected from the group consisting of ethylene-propylene copolymer rubber and ethylene-propylene-non conjugated diene copolymer rubber andto 60 parts by weight of (b) a peroxide-decomposing olefin plastic selected from the group consisting of isotactic polypropylene and propylene-alpha olefin copolymer,

wherein the sum of these components is 100 parts by weight.

18. A method according to claim 17, wherein divinyl benzene is used in an amount of 0.1 to 2.0% by weight of the mixture to be heat-treated.