Antistatic coated polyester film

• US 4,214,035 A
• Filed: 01/31/1979
• Issued: 07/22/1980
• Est. Priority Date: 01/31/1979
• Status: Expired due to Term

• Current Assignee: American Hoechst Corporation (Sanofi )
• Original Assignee: American Hoechst Corporation (Sanofi )
• Inventors: Heberger, John M.
• Primary Examiner(s): Cannon, James C.
• Application Number:
  US06/008,012
• Time in Patent Office: 538 Days
• Field of Search: 428/340, 428/323, 428/483, 428/910, 428/341, 427/407 G, 427/40, 427/171, 427/172, 427/173, 427/209, 427/211, 427/428, 96/87 A
• US Class Current: 428/340
• CPC Class Codes: C08J 2367/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds; C08J2367/06 takes precedence
• CPC Class Codes: C08J 2433/00 Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
• CPC Class Codes: C08J 7/0427 with only one layer of a composition containing a polymer binder with more layers C08J7/042
• CPC Class Codes: C08J 7/043 Improving the adhesiveness of the coatings per se, e.g. forming primers adhesives in the form of films or foils characterised by the primer layers between the polymer carriers and the adhesives C09J7/50
• CPC Class Codes: C08J 7/044 Forming conductive coatings; Forming coatings having anti-static properties
• CPC Class Codes: C08J 7/046 Forming abrasion-resistant coatings; Forming surface-hardening coatings
• CPC Class Codes: Y10T 428/27 Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
• CPC Class Codes: Y10T 428/273 of coating
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers

Abstract

A polyester film coated with an antistatic coating is provided. The film includes a polyester film support coated on one side with a latex coating. The coating includes stearamidopropyldimethyl-β-hydroxy-ethylammonium nitrate present in a concentration in the range of between about 2.75 percent and 3.25 percent by weight, based on the total weight of the latex coating. The coating further includes a crosslinkable methylmethacrylate-ethylacrylate-methacrylamide terpolymer having a glass transition temperature in the range of between about 40° C. and 50° C. The terpolymer is present in a concentration in the range of between about 0.75 percent and 1.25 percent by weight, based on the total weight of the latex coating. The weight ratio of the nitrate to the terpolymer ranges between about 2.75:1 to below 3:1.

A process for forming the above film is also disclosed. In this process a latex coating of the composition described above is coated onto a uniaxially drawn polyester film support. The uniaxially drawn film is then heated to drive off the water and thereafter the uniaxially coated film is stretched in a direction normal to that of the uniaxial drawn film.

Claims

1. A biaxially oriented polyester film comprising a polyester film support coated on one side with a latex coating, said coating including:

stearamidopropyldimethyl-β

-hydroxy-ethylammonium nitrate, present in a concentration in the range of between 2.75% and 3.25% by weight, based on the total weight of the latex coating; and

a crosslinkable methylmethacrylate-ethyl acrylate-methacrylamide terpolymer, having a glass transition temperature in the range of between about 40°

C. and 50°

C., present in a concentration in the range of between about 0.75% and 1.25% by weight based on the total weight of the latex coating wherein the weight ratio of said stearamidopropyldimethyl-β

-hydroxy-ethylammonium nitrate to said crosslinkable methylmethacrylate-ethyl acrylate-methacrylamide terpolymer is in the range of between about 2.75;

1 and 3.25;

1.

2. A biaxially oriented polyester film in accordance with claim 1 wherein the total dry coating weight of said coating on said polyester film is at least 0.003 pound per 1000 square feet of biaxially oriented film.

3. A polyester film in accordance with claim 2 wherein said total dry coating weight is in the range of between about 0.003 and 0.007 pound per 1000 square feet of biaxially stretched film.

4. A film in accordance with claim 1 wherein the weight ratio of said stearamidopropyldimethyl-β

-hydroxy-ethylammonium nitrate to said crosslinkable methylmethacrylate-ethyl acrylate-methacrylamide terpolymer is in the range of between about 2.75;

1 and 3.0;

1.

5. A film in accordance with claim 1 wherein said polyester is polyethylene terephthalate.

6. A film in accordance with claim 1 wherein said stearamidopropyldimethyl-β

-hydroxy-ethylammonium nitrate is present in said latex coating in a concentration in the range of between about 2.9% and 3.1% by weight, based on the total weight of said latex coating.

7. A film in accordance with claim 6 wherein said stearamidopropyldimethyl-β

-hydroxy-ethylammonium nitrate is present in said latex coating in a concentration in the range of between about 3.0% by weight, based on the total weight of said latex coating.

8. A film in accordance with claim 1 wherein said crosslinkable methylmethacrylate-ethyl acrylate-methacrylamide terpolymer is present in said latex coating in a concentration in the range of between about 0.9% and 1.1% by weight based on the total weight of said latex coating.

9. A film in accordance with claim 8 wherein said crosslinkable methylmethacrylate-ethyl acrylate-methacrylamide terpolymer is present in said latex coating in a concentration in the range of about 1.0% by weight, based on the total weight of said latex coating.

10. A film in accordance with claim 1 wherein said crosslinkable methylmethacrylate-ethylacrylate-methacrylamide terpolymer has a glass transition temperature of between about 43°

C. and 47°

C.

11. A film in accordance with claim 10 wherein said crosslinkable methylmethacrylate-ethylacrylate-methacrylamide terpolymer has a glass transition temperature of 45°

C.

12. A film in accordance with claim 1 wherein opposite said latex coating is coated with a second latex coating, said second latex coating comprising a crosslinkable methylmethacrylate-ethylacrylate-methacrylamide terpolymer having a glass transition temperature in the range of between about 40°

C. and 50°

C., and present in a concentration of between about 3.0% and 4.0% by weight, based on the total weight of said second latex coating.

13. A process for forming an antistatic biaxially oriented polyester film comprising the steps of:

applying a latex coating, said coating comprising stearamidopropyldimethyl-β

-hydroxy-ethylammonium nitrate, present in a concentration in the range of between about 2.75% and 3.25% by weight, based on the total weight of said latex coating, and a crosslinkable methylmethacrylate-ethylacrylate-methacrylamide terpolymer having a glass transition temperature in the range of between about 40°

C. and 50°

C. and present in a concentration in the range of between about 0.75% and 1.25% by weight based on the total weight of the latex coating wherein the weight ratio of said nitrate to said terpolymer is in the range of between about 2.75;

1 and 3.25;

1, to a uniaxially drawn polyester film;

heating said coated, uniaxially drawn film at a temperature in the range of between about 90°

C. and 110°

C. wherein said coating is dried;

stretching said coated uniaxially drawn film in a direction normal to the direction of the uniaxially drawn film wherein biaxially drawn film is produced.

14. A process in accordance with claim 13 wherein said polyester is polyethylene terephthalate.

15. A process in accordance with claim 14 wherein said biaxially drawn film is heat set at a temperature in the range of between about 190°

C. and 240°

C.

16. A process in accordance with claim 13 wherein said coating of said uniaxially drawn film is applied by roller coating.

17. A process in accordance with claim 16 wherein said uniaxially drawn film is applied by reverse gravure coating.

18. A process in accordance with claim 13 wherein said uniaxially drawn film coated with said latex coating is longitudinally drawn film.

19. A process in accordance with claim 13 wherein said uniaxially drawn film is coated with a second coating on the side opposite said first coated side, said second coating comprising a latex coating including a crosslinkable methylmethacrylate-ethyl acrylate-methacrylamide terpolymer having a glass transition temperature in the range of between about 40°

C. and 50°

C., present in a concentration in the range of between 3.0% and 4.0% by weight, based on the total weight of said second latex coating.

20. A process in accordance with claim 13 wherein said uniaxially drawn film is subjected to a corona discharge prior to the coating of said film.