Fabric treatment compositions containing polyglycerol esters

• US 4,214,038 A
• Filed: 01/22/1979
• Issued: 07/22/1980
• Est. Priority Date: 01/22/1979
• Status: Expired due to Term

• Current Assignee: Riley Stoker Corporation (Babcock Power Incorporated)
• Original Assignee: The Procter & Gamble Company
• Inventors: Seiden, Paul, McCarty, Charles B.
• Primary Examiner(s): Herbert, Jr., Thomas J.
• Application Number:
  US06/005,114
• Time in Patent Office: 547 Days
• Field of Search: 252/8.6, 252/8.8, 252/8.9, 252/153, 252/334, 428/219, 428/213, 428/411, 428/245, 427/237, 427/421, 427/240, 427/424, 427/11, 427/242, 8/137, 118/76, 34/12
• US Class Current: 427/242
• CPC Class Codes: C11D 1/667 Neutral esters, e.g. sorbitan esters
• CPC Class Codes: C11D 17/047 Arrangements specially adapted for dry cleaning or laundry dryer related applications
• CPC Class Codes: D06M 13/148 Polyalcohols, e.g. glycerol or glucose
• CPC Class Codes: Y10T 428/249995 Constituent is in liquid form
• CPC Class Codes: Y10T 442/2352 Coating or impregnation functions to soften the feel of or improve the "hand" of the fabric

Abstract

A non-staining, anti-static fabric softening composition comprising particular "polyglycerol esters" is applied to fabrics in an automatic laundry dryer.

Claims

1. An article adapted for providing fabric softening within an automatic clothes dryer, said article comprising:

(a) a fabric softening amount of softening composition comprising a fatty alkyl polyglycerol ester softener component having the formula ##STR3## wherein R₁ is a C₉ to C₂₃ aliphatic acylic hydrocarbyl group, and R₂ and R₃ are selected from the group consisting of hydrogen and C₈ to C₂₄ fatty acyl groups and n is from about 2 to about 4, wherein the crystal melting point of said fatty polyglycerol ester is above about 38°

C., and wherein the degree of esterification of said polyglycerol ester is from about 0.2 to about 0.6; and

(b) a dispensing means which provides for release of said softening composition within an automatic laundry dryer at dryer operating temperatures, wherein when said dispensing means is a flexible substrate in a sheet configuration the softening composition is impregnated or coated onto the substrate to provide a weight ratio of softening composition to dry substrate ranging from about 10;

1 to 0.5;

1.

2. An article according to claim 1 wherein the dispensing means is an aerosol device.

3. An article according to claim 1 wherein in the fatty polyglycerol ester component R₁ is a C₁₁ to C₂₁ saturated acyclic hydrocarbyl group and R₂ and R₃ can be the same or different from each other and are selected from the group consisting of hydrogen and C₁₂ to C₂₂ saturated fatty acyl groups, and wherein said polyglycerol ester comprises at least 70% by weight of said softening composition.

4. An article acording to claim 3 wherein the dispensing means is an aerosol device.

5. An article according to claim 3 wherein the substrate is a foamed plastic sheet having an absorbent capacity of from about 15 to about 22.

6. An article according to claim 3 wherein the dispensing means comprises a flexible substrate in a sheet configuration having an absorbent capacity of from about 2 to about 25 and wherein the softening composition is impregnated in the substrate to provide a weight ratio of softening composition to dry substrate ranging from about 10:

1 to 0.5;

1.

7. An article according to claim 6 wherein the substrate is a woven or non-woven cellulosic cloth or paper and has an absorbent capacity of from about 4 to about 12.

8. An article according to claim 7 wherein the substrate comprises a non-woven cloth having an absorbent capacity of from about 5 to 7 and wherein the weight ratio of softening composition to substrate on a dry weight basis ranges from about 5:

1 to 1;

1.

9. A method of imparting a softening and anti-static effect to fabrics in an automatic laundry dryer, comprising the steps of

(a) placing damp fabrics into the dryer;

(b) applying to said fabrics a fabric softening composition comprising a fatty polyglycerol ester of the formula ##STR4## wherein R₁ is a C₉ to C₂₃ aliphatic acylic hydrocarbyl group, and R₂ and R₃ are selected from the groups consisting of hydrogen and C₈ to C₂₄ fatty acyl groups and n is from about 2 to about 4, wherein the cyrstal melting point of said fatty polyglycerol ester is above about 38°

C., and wherein the degree of esterification of said polyglycerol ester is from about 0.2 to about 0.6, said application being at the rate of from .01 gram to about 12 grams of polyglycerol ester per 5 pounds of fabrics on a dry fabric weight basis; and

(c) operating the dryer to dry the fabrics at a temperature of at least equal to or higher than the melting point of the composition for a period of from about 10 minutes to 60 minutes.

10. The method of claim 9 wherein the rate of application of said polyglycerol ester is from about 1 gram to about 5 grams per 5 pounds of fabrics on a dry fabric weight basis.

11. The method of claim 10 wherein R₁ is a C₁₁ to C₂₁ saturated acyclic hydrocarbyl group and R₂ and R₃ can be the same or different from each other and are selected from the group consisting of hydrogen and C₁₂ to C₂₂ saturated fatty acyl groups.

12. The method of claim 11 wherein the composition is dispensed within the dryer from a flexible substrate sheet having the softener composition releasably affixed thereto.

13. The method of claim 11 wherein the composition is dispensed onto the interior surface of the cold dryer drum from an aerosol dispenser prior to addition of fabrics.