Metal-halogen battery having reduced dendrite growth

• US 4,218,521 A
• Filed: 12/08/1978
• Issued: 08/19/1980
• Est. Priority Date: 12/08/1978
• Status: Expired due to Term

• Current Assignee: Electric Power Research Institute Incorporated
• Original Assignee: Electric Power Research Institute Incorporated
• Inventors: Putt, Ronald A., Montgomery, Mark J.
• Primary Examiner(s): Walton, Donald L.
• Application Number:
  US05/967,863
• Time in Patent Office: 620 Days
• Field of Search: 429/101, 429/38, 429/39, 429/15, 429/70, 429/51, 429/34, 429/81, 429/105
• US Class Current: 429/508
• CPC Class Codes: H01M 10/365 Zinc-halogen accumulators
• CPC Class Codes: H01M 12/085 Zinc-halogen cells or batteries
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A metal-halogen battery, specifically a zinc-bromine battery of the rechargeable type, is disclosed herein and includes a housing, spaced positive and negative electrode plates located within the housing and an arrangement for providing continuous flow of electrolyte solution through the housing between the plates. This battery also includes a network of electrically non-conductive projecting ribs which engage the negative electrode plate for providing a fixed spacing between the two plates but which, at the same time, are specifically designed to reduce dendrite growth.

Claims

1. A metal-halogen battery, comprising:

(a) a housing;

(b) a positive electrode plate located within said housing;

(c) a negative electrode plate located within said housing in spaced relation with and confronting said positive plate;

(d) means for providing a continuous flow of electrolyte solution through said housing and past the confronting face of said negative plate; and

(e) means for maintaining uniform spacing between said plates, said means including

(i) a main body located between said plates in a fixed position relative to said positive plate, and

(ii) a plurality of electrically non-conductive, spaced projections, each of which extends out from said main body a distance sufficient to engage the confronting face of said negative plate at its free end, each of said projections having a cross-section which is wider at predetermined points between said engaging free end and main body than at its plate engaging free end.

2. A battery according to claim 1 wherein at least a section of the cross-section of each of said projections including said plate engaging free ends tapers outwardly from said free end toward said main body.

3. A battery according to claim 2 wherein the tapering section of each projection tapers at an angle of about 45°

with the axis of the projection.

4. A battery according to claim 1 wherein said main body is in the form of an electrically non-conductive grid sufficiently open to allow said electrolyte solution to pass therethrough, said grid supporting said projections on one side thereof.

5. A battery according to claim 4 including:

(a) means for providing a second continuous flow of electrolyte solution through said housing and through said positive electrode plate; and

(b) an electrolyte solution separator between said space maintaining means and said positive electrode for separating said firstmentioned and second electrolyte solutions from one another, said separator engaging said main body on one of its sides and including means engaging the confronting face of said positive plate on its other side.

6. A battery according to claim 1 wherein each of said projections extends longitudinally along the length of and parallel with the confronting face of said negative electrode plate.

7. A metal-halogen battery, comprising:

(a) a housing;

(b) a positive electrode plate located within said housing;

(c) a negative electrode plate located within said housing in spaced relation with and confronting said positive plate;

(d) means for maintaining a fixed spacing between said plates, said space maintaining means including a plurality of electrically non-conductive, spaced projections normal to said negative plate and having free ends in engagement with the confronting face thereof, each of said projections having at least a segment which is spaced from its free end and which is wider in cross section than said free end such that the current density of the battery at said negative plate directly adjacent the plate engaging free end of each projection is sufficiently small to prevent dendrite growth at said free end regardless of the flow rate of said electrolyte solution thereat.