Nonaqueous electrochemical cell

• US 4,218,523 A
• Filed: 02/28/1979
• Issued: 08/19/1980
• Est. Priority Date: 02/28/1979
• Status: Expired due to Term

• Current Assignee: Eveready Battery Company Incorporated (Energizer Holdings, Inc.)
• Original Assignee: Union Carbide Corporation (Dow, Inc.)
• Inventors: Kalnoki-Kis, Tibor
• Primary Examiner(s): Walton, Donald L.
• Application Number:
  US06/015,938
• Time in Patent Office: 538 Days
• Field of Search: 429/101, 429/196, 429/48
• US Class Current: 429/101
• CPC Class Codes: H01M 6/14 Cells with non-aqueous electrolyte

Abstract

A non-aqueous cell comprising an active metal anode, such as lithium, a liquid cathode-electrolyte comprising a solute dissolved in a solvent which is an oxyhalide of an element of Group V or Group VI of the Periodic Table and wherein elemental sulfur or a sulfur compound is incorporated into the cathode-electrolyte so as to substantially eliminate initial voltage delay of the cell during discharge.

Claims

1. A nonaqueous cell comprising an active metal anode, a cathode collector and an ionically conductive cathode-electrolyte solution containing a solute dissolved in at least one liquid oxyhalide of an element of Group V or Group VI of the Periodic Table, the improvement comprising incorporating into said cathode-electrolyte at least one sulfurcontaining member represented by the formula M_x S_y Y_z wherein M is an alkali or alkaline earth metal, S is sulfur and Y is chlorine or bromine and wherein x is an integer having a value of 0 to 2, y is an integer having a value of 1 to 14, and z is an integer having a value of 0 to 2, with the proviso that when z is other than 0 then x is 0, that when x is other than 0 then z is 0, when x and z are 0 and the oxyhalide employed does not form sulfur as a cell discharge product, then the sulfur incorporated in the cathode-electrolyte is from 1 weight percent based on the weight of the cathode-electrolyte up to the quantity of sulfur that will dissolve in the cathode-electrolyte at ambient temperature and pressure, and that when x or z are other than 0, then the sulfur-containing member is incorporated in the cathode-electrolyte contains sulfur in an amount between about 0.05 and about 10 weight percent based on the weight of the cathode-electrolyte.

2. The nonaqueous cell of claim 1 wherein y is an integer having a value of 1 to 6.

3. The nonaqueous cell of claim 1 wherein x or z is other than 0 and the sulfur in the sulfur-containing member is between about 0.05 and about 1.5 weight percent based on the weight of the cathode-electrolyte.

4. The nonaqueous cell of claim 1 wherein the anode is coated with a vinyl polymer film.

5. The nonaqueous cell of claim 1 wherein the at least one sulfur-containing member is selected from the group consisting of lithium sulfide (Li₂ S), sulfur monochloride (S₂ Cl₂) and sulfur dichloride (SCl₂).

6. The nonaqueous cell of claim 5 wherein the anode is coated with a vinyl polymer film.

7. The nonaqueous cell of claim 4 wherein the at least one sulfur-containing member is selected from the group consisting of lithium sulfide and sulfur monochloride.

8. The nonaqueous cell of claim 7 wherein the anode is coated with a vinyl polymer film.

9. The nonaqueous cell of claim 4 wherein the sulfur-containing member is lithium sulfide.

10. The nonaqueous cell of claim 9 wherein the anode is coated with a vinyl polymer film.

11. The nonaqueous cell of claim 1 wherein the at least one liquid oxyhalide is selected from the group consisting of thionyl chloride, sulfuryl chloride, phosphorous oxychloride, thionyl bromide, chromyl chloride, vanadyl tribromide and selenium oxychloride.

12. The nonaqueous cell of claim 11 wherein the at least one liquid oxyhalide is selected from the group consisting of thionyl chloride and sulfuryl chloride.

13. The nonaqueous cell of claim 11 wherein the anode is lithium coated with a vinyl polymer film, the liquid oxyhalide is thionyl chloride and the at least one sulfur-containing member is selected from the group consisting of lithium sulfide and sulfur monochloride.

14. The nonaqueous cell of claim 11 wherein the anode is lithium coated with a vinyl polymer film, the liquid oxyhalide is sulfuryl chloride and the at least one sulfur-containing member is selected from the group consisting of lithium sulfide and sulfur monochloride.

15. The nonaqueous cell of claim 1 wherein the solute is a complex salt of a Lewis acid and an inorganic ionizable salt.

16. The nonaqueous cell of claim 1 wherein the anode is selected from the group consisting of lithium, sodium, calcium and potassium.