Process and plant for the recovery of water from humid air

• US 4,219,341 A
• Filed: 11/24/1978
• Issued: 08/26/1980
• Est. Priority Date: 11/25/1977
• Status: Expired due to Term

• Current Assignee: Mittex AG
• Original Assignee: Mittex AG
• Inventors: Hussmann, Peter
• Primary Examiner(s): Spitzer, Robert H.
• Application Number:
  US05/963,647
• Time in Patent Office: 641 Days
• Field of Search: 34/79-81, 34/DIG. 1, 55/31, 55/33, 55/34, 55/35, 55/74, 55/75, 55/208, 55/387, 55/389, 62/94, 62/271, 202/234, 203/10, 203/11, 203/DIG. 1
• US Class Current: 96/127
• CPC Class Codes: B01D 5/0003 by using heat-exchange surfaces for indirect contact between gases or vapours and the cooling medium
• CPC Class Codes: B01D 53/265 by refrigeration (condensation)
• CPC Class Codes: C02F 1/18 Transportable devices to obtain potable water
• CPC Class Codes: E03B 3/28 from humid air condensing of vapours in general B01D5/00; dehumidification of air for air-conditioning F24F3/14
• CPC Class Codes: Y02A 20/00 Water conservation; Efficient water supply; Efficient water use

Abstract

Disclosed are a process and plant for the recovery of water from humid air, in which at night cool humid air is passed through an adsorbent medium layer which adsorbs water from the air and in which, by day, air heated by solar energy up to a temperature which is above the ambient temperature is passed first through this layer to absorb water from the layer and then is cooled down so that the water condenses. The daytime air, when entering the adsorbent layer, is heated by solar energy with a radiator which is preferably a black anodized aluminum web in which the adsorbent medium may be embedded and/or by the adsorbent medium layer which is colored black for better absorption of sun rays. By using reflectors, the solarization upon the adsorbent medium layer and/or the radiator may be intensified.

Claims

1. A plant for carrying out a process for recovering water from humid air, comprising:

a layer of an air-permeable water adsorbent silica gel capable of adsorbing water from humid night air at a first temperature and desorbing the adsorbed water when exposed to daytime air at a second temperature higher than said first temperature, said layer being oriented for exposure of its principal surface to the sun'"'"'s rays and being dark colored at least on its exposed surface for absorption of solar heat;

means, including a blower, for propelling a stream of ambient daytime air through said water adsorbent silica gel layer to define an upstream and a downstream direction in the ambient daytime air stream;

means, including at least one generally flat component having a colored surface oriented for exposure to the sun'"'"'s rays and being permeable to air and the sun'"'"'s rays, said flat component being positioned above and upstream of said water adsorbent silica gel layer in the stream of daytime air and having a portion which is capable of conducting heat and which projects into said silica gel layer, for heating ambient daytime air to a higher temperature;

a cold-storage type condenser located downstream from said water adsorbent silica gel layer in the stream of daytime air for removing water from the stream of daytime air after it has passed through said water adsorbent silica gel layer; and

means, including a blower, for propelling a stream of ambient humid night air at a temperature lower than said daytime air first through said condenser and thereafter through said layer of silica gel.

2. The plant according to claim 1, wherein the flat component permeable to air and light comprises a web or net of metal wires.

3. The plant according to claim 1, wherein the flat component permeable to air and light comprises a perforated sheet.

4. The plant according to claim 1, wherein said flat component comprises a metal capable of conducting heat and wherein said portion projecting into said layer of silica gel is shaped in such a way that the air passes through the portion of component within the layer while passing through said layer of silica gel.

5. The plant according to claim 4, wherein said flat metal component comprises a downwardly extending serpentine into said layer of silica gel and said silica gel is contained between the individual transversely extending serpentine layers of the component.

6. The plant according to claim 5, wherein the metal component is interconnected at each of its serpentine bend-points, by two lateral web sections, with the uppermost transversely extending layer of the serpentine metal component.

7. The plant according to claim 6, further including spacers arranged between said lateral web sections, said spacers connecting the lateral web sections extending within the silica gel layer with the web section located immediately above.

8. The plant according to claim 7, wherein the surface of the silica gel layer exposed to the sun'"'"'s rays is corrugated or zigzag-shaped.

9. The plant according to claim 5, wherein said flat component comprises a web of black anodized aluminum.

10. The plant according to claim 1, further comprising at least one reflector for reflecting the sun'"'"'s rays onto at least one of said flat component and said surface layer of said water adsorbent silica gel layer.

11. The plant according to claim 10, comprising a plurality of absorption and adsorption packages comprising one of said serpentine shaped flat metal components, whereby the silica gel layer together with the metal component forms a pre-fabricated, compact, box-type flat package, said packages being joined and sealed against each other.

12. The plant according to claim 11, wherein each said reflector comprises a flat or parabolic mirror arranged at the upper periphery of the water adsorbent silica gel layer so that it directs the incident sun rays onto the surface of at least one of said flat component and said exposed surface of said silica gel layer.

13. The plant according to claim 12, wherein said absorption and adsorption packages are spaced apart horizontally and the space between the individual packages is covered by said mirrors projecting upwardly.

14. The plant according to claim 11, further comprising a translucent roof arranged above said absorption and adsorption packages.

15. The plant according to claim 14, further comprising an insulated layer permable to air arranged between said absorption and adsorption packages and said condenser.

16. The plant according to claim 10, wherein said at least one reflector comprises a plurality of flat mirrors incorporated in and being distributed over the surface of said silica gel layer.

17. The plant according to claim 16, wherein said reflector comprises a sun ray-reflecting powder distributed in said silica gel layer.

18. The plant according to claim 1, wherein said cold-storage condenser comprises a package of stones serving as a cold sink and being arranged below said water adsorbent silica gel layer.

19. The plant according to claim 1, further comprising a heat exchanger having an integral condenser surface, said heat exchanger being located between said silica gel layer and said condenser.

20. The plant according to claim 19, wherein said heat exchanger is arranged above said cold-storage condenser and below said silica gel layer.

21. The plant according to claim 1, wherein said adsorbent silica gel layer comprises a silica gel capable of adsorbing from humid air having a relative humidity from about 25 to 30% at temperatures up to about 30°

C. a water quantity of at least one of (A) from about 30 to 40% of its total absorption capacity and (B) 40 to 60% of its own weight.

22. The plant according to claim 21, wherein said silica gel is colored deep black with soot.

23. The plant according to claim 22, wherein said silica gel is used in the form of coarse-grained spheres or granulate.

24. The plant according to claim 23, wherein said adsorbent silica gel layer comprises a plurality of stacked layers of silica gels having different adsorption and desorption characteristics.

28. The plant according to claim 7, further including spacers arranged between said lateral web sections, said spacers connecting the lateral web sections extending within the adsorbent medium layer with the web section located immediately above.

29. The plant according to claim 28, wherein the surface of the adsorbent medium layer exposed to the sun'"'"'s rays is corrugated or zigzag-shaped.

25. A plant for carrying out a process for recovering water from humid air, comprising:

a layer of an air-permeable water adsorbent medium capable of adsorbing water from humid night air at a first temperature and desorbing the adsorbed water when exposed to daytime air at a second temperature higher than said first temperature;

means for propelling a stream of ambient daytime air through said adsorbent medium layer to define an upstream and a downstream direction in the ambient daytime air stream;

means, including at least one air-permeable dark colored layer comprising a radiator member and a dark colored surface layer of adsorbent medium layer oriented for exposure to the sun'"'"'s rays and positioned upstream of said adsorbent medium layer in the stream of daytime air, for heating ambient daytime air to a higher temperature, said radiator member comprising a flat structural component permeable to air and light, which is arranged above the adsorbent medium layer to be penetrated by the flow of daytime air entering the adsorbent medium layer, said flat structural component comprising a metal capable of conducting heat and including a portion passing downwardly from the top through the adsorbent medium layer in such a way that the air passes through the structural component within the layer while passing through the adsorbent medium layer, said portion being passed downwardly from the top in a serpentine line and the adsorbent medium being embedded between the individual sections of the serpentine portion, whereby the adsorbent medium together with the metal component forms a pre-fabricated, compact, box-type, flat absorption and adsorption package;

a condenser located downstream from said adsorbent medium layer in the stream of daytime air for removing water from the stream of daytime air after it has passed through said adsorbent medium layer; and

at least one reflector for reflecting the sun'"'"'s rays onto at least one of said radiator member and said surface layer of said adsorbent medium layer.

26. The plant according to claim 25 wherein said flat structural component comprises a web of black anodized aluminum.

27. The plant according to claim 26, wherein the web is interconnected at each of its bend-points, by two lateral web sections, with the uppermost transversely extending section of the web.

30. The plant according to claim 25, including a plurality of said absorption and adsorption packages joined and sealed against each other.

31. The plant according to claim 30, wherein each said reflector comprises a flat or parabolic mirror arranged at the upper periphery of the adsorbent medium layer so that it directs the incident sun rays onto the surface of at least one of the adsorbent medium layer and the radiator.

32. The plant according to claim 31, wherein said absorption and adsorption packages are spaced apart horizontally and the space between the individual packages is covered by said mirrors projecting upwardly.

33. The plant according to claim 30, wherein said at least one reflector comprises a plurality of flat mirrors incorporated in and being distributed over the surface of said adsorbent medium layer.

34. The plant according to claim 25 wherein said condenser comprises a package of stones serving as a cold sink and being arranged below said adsorbent medium layer.

35. The plant according to claim 25, wherein said condenser comprises a heat exchanger having an integral condenser surface.

36. The plant according to claim 35, wherein said heat exchanger is combined with a cold sink, said heat exchanger being arranged above said cold sink.

37. The plant according to claim 25, wherein said adsorbent medium comprises a silica gel capable of adsorbing from humid air having a relative humidity from about 25 to 30% at temperatures up to about 30°

C. a water quantity of at least one of (A) from about 30 to 40% of its total absorption capacity and (B) 40 to 60% of its own weight.

38. The plant according to claim 25, further comprising a translucent roof arranged above said absorption and adsorption packages.

39. The plant according to claim 38, further comprising an insulating layer permeable to air arranged between said absorption and adsorption packages and said condenser.