Method of preparing a cathode current collector for use in an electrochemical cell

• US 4,219,443 A
• Filed: 12/20/1978
• Issued: 08/26/1980
• Est. Priority Date: 12/20/1978
• Status: Expired due to Term

• Current Assignee: Yardney Technical Products, Inc. (Vectra Corp.)
• Original Assignee: GTE Laboratories Incorporated (Lumen Technologies, Inc.)
• Inventors: Klinedinst, Keith A., Murphy, Francis G.
• Primary Examiner(s): Konopka, P. E.
• Application Number:
  US05/971,571
• Time in Patent Office: 615 Days
• Field of Search: 252/425.3, 429/196, 429/42, 427/115, 427/122
• US Class Current: 502/101
• CPC Class Codes: H01M 4/86 Inert electrodes with catalytic activity, e.g. for fuel cells
• CPC Class Codes: H01M 6/14 Cells with non-aqueous electrolyte
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

Disclosed is a primary electrochemical cell having an improved cathode current collector and a method for making the current collector. The cell comprises an oxidizable active anode material; and electrolytic solution comprising a reducible soluble cathode and an electrolyte solute dissolved therein; and a cathode current collector comprising a layer of finely-divided catalyst for reducing the solvent, bonded to an inert, electrically-conductive substrate. Preferably, a bonding layer, comprising a finely-divided polymer and a minor amount of conductive material, bonds the catalyst layer to the substrate. The bonding and catalyst layers preferably can be formed by sequentially applying respective dispersions thereof to the substrate, drying, and heating to bond the materials. Soluble cathode cells employing cathode current collectors of the type described have exceptionally rapid discharge properties.

Claims

1. A process for preparing a cathode current collector for use in a primary electrochemical cell comprising an oxidizable anode material;

a cathode current collector comprising a layer comprising finely-divided catalyst for reducing the soluble cathode; and

an electrolyte solution, in contact with the anode and cathode current collector, comprising a reducible soluble cathode and an electrolyte solute;

wherein the process comprises;

positioning a porous, inert, electrically-conductive substrate between a first zone at a first pressure and a second zone at a second, higher pressure;

preparing a bonding layer dispersion comprising a liquid vehicle, a finely-divided thermoplastic polymer and a minor amount, based on the weight of the polymer, of an inert, electrically-conductive material;

preparing a catalyst layer dispersion comprising a liquid vehicle, a finely-divided catalyst and a minor amount, based on the weight of the catalyst, of a thermoplasticpolymer;

forming a bonding layer on the substrate by applying the bonding layer dispersion to the surface of the substrate in the second zone and forming a catalyst layer on the porous substrate by applying the catalyst layer dispersion to the bonding layer dispersion, the solid particles of the dispersions being forced against the substrate and the liquid being forced through the substrate; and

heating the substrate, the bonding layer, and the catalyst layer at a temperature and for a time effective to fuse them into a unitary, porous cathode current collector.

2. A process according to claim 1 wherein the catalyst is a member selected from the group consisting of gold, platinum, carbon black, nickel oxide, and copper sulfide.

3. A process according to claim 1 wherein the thermoplastic polymer comprises polytetrafluoroethylene.

4. A process according to claim 1 wherein the finely-divided catalyst and polymer are dispersed in the liquid vehicle by applying ultrasonic energy to a mixture of the catalyst layer dispersion ingredients.

5. A process for preparing a cathode current collector for use in a primary electrochemical cell comprising an oxidizable anode material;

a cathode current collector comprising a layer of finely-divided catalyst for reducing the solvent;

an electrolytic solution, in contact with the anode and cathode current collector, comprising a reducible soluble cathode and an electrolyte solute;

wherein the process comprises;

providing an inert, electrically-conductive substrate;

preparing a bonding layer dispersion comprising a liquid vehicle, a finely-divided thermoplastic polymer and a minor amount, based on the weight of the polymer, of an inert, electrically-conductive material;

forming a bonding layer on the substrate in a plurality of cycles by alternately applying a thin layer of the bonding layer dispersion to the surface of the substrate and drying to remove the liquid until a thickness of at least 5 micrometers is built up;

preparing a catalyst layer dispersion comprising a liquid vehicle, a finely-divided catalyst and a minor amount, based on the weight of the catalyst, of a thermoplastic polymer;

forming a catalyst layer on the bonding layer in a plurality of cycles by alternately applying a thin layer of the catalyst layer dispersion to the bonding layer and drying to remove the liquid until a thickness of at least 25 micrometers is built up; and

heating the substrate, the bonding layer, and the catalyst layer at a temperature and for a time effective to fuse them into a unitary, porous cathode current collector.

6. A process according to claim 5 wherein the thermoplastic polymer comprises polytetrafluoroethylene and the catalyst is a member selected from the group consisting of gold, platinum, carbon black, nickel oxide, and copper sulfide.

7. A process according to claim 5 wherein the surface of the substrate is made more receptive to bonding by roughening prior to applying the bonding layer.

8. A process according to claim 5 wherein the bonding and catalyst layer dispersions are prepared by dispersing the solid components in the liquid vehicle for each phase by ultrasonic energy, and the dispersion is applied to the substrate by spraying.