Josephson tunnel junction with polycrystalline silicon, germanium or silicon-germanium alloy tunneling barrier

• US 4,220,959 A
• Filed: 03/23/1979
• Issued: 09/02/1980
• Est. Priority Date: 03/23/1979
• Status: Expired due to Term

• Current Assignee: Sperry Corporation
• Original Assignee: Sperry Corporation
• Inventors: Kroger, Harry
• Primary Examiner(s): Edlow, Martin H.
• Application Number:
  US06/023,487
• Time in Patent Office: 529 Days
• Field of Search: 357/5, 307/306, 324/248, 29/599
• US Class Current: 257/32
• CPC Class Codes: H10N 60/12 Josephson-effect devices
• CPC Class Codes: Y10S 505/874 with josephson junction, e.g. squid
• CPC Class Codes: Y10T 29/49014 Superconductor

Abstract

A Josephson tunnel junction device having niobium nitride superconductive electrodes includes a polycrystalline semiconductor tunnelling barrier therebetween comprised of silicon, germanium or an alloy thereof preferably deposited on the lower superconductive electrodes by chemical vapor deposition. The barrier height of the junction is precisely controlled by precision doping of the semiconductor material.

Claims

1. A Josephson tunnel junction device comprising

first and second layers of superconductive material superposed with respect to each other,

at least said first layer comprising a refractory compound superconductive material, and

a barrier layer superposed between said first and second superconductive layers whereby Josephson tunnelling current can flow therethrough between said superconductive layers,

said barrier layer comprised of polycrystalline semiconductor material selected from the group consisting of silicon, germanium and alloys thereof.

2. The device of claim 1 in which at least said first layer of superconductive material comprises niobium nitride.

3. The device of claim 1 in which said barrier layer comprises said polycrystalline semiconductor deposited on said first superconductive layer by chemical vapor deposition.

4. The device of claim 1 in which said barrier layer comprises doped polycrystalline semiconductor material selected from the group consisting of silicon, germanium and alloys thereof.

5. The device of claim 4 in which said barrier layer is doped by a column III material thereby providing p-type semiconductor material.

6. The device of claim 4 in which said barrier layer is doped by a column V material thereby providing n-type semiconductor material.

7. The device of claim 1 in which said barrier layer is deposited on said first superconductive layer by evaporative deposition.

8. The device of claim 1 in which said barrier layer is deposited on said first superconductive layer by sputter deposition.

9. The device of claim 7 or 8 in which said barrier layer comprises said polycrystalline semiconductor material deposited on said first superconductive layer which is so heated that said polycrystalline semiconductor forms thereon.

10. The device of claim 7 or 8 in which said barrier layer comprises said polycrystalline semiconductor material deposited on said first superconductive layer which is at such a temperature that such deposition produces amorphous semiconductor material which is crystallized into said polycrystalline semiconductor material by a technique selected from the group consisting of thermal annealing, laser annealing, electron beam annealing and combinations thereof.

11. The device of claim 2 in which at least said first layer of niobium nitride is deposited by reactive sputtering of niobium in a partial nitrogen atmosphere onto a suitably heated substrate.

12. The device of claim 2 in which at least said first layer of niobium of nitride is deposited onto a substrate by chemical vapor deposition.

13. The device of claim 1 further including an insulator layer disposed between said first and second superconductive layers having at least one opening therethrough for defining the Josephson tunnelling barrier area of said device.

14. The device of claim 5 in which said barrier layer is doped by a dopant selected from the group consisting of boron, aluminum, gallium and indium.

15. The device of claim 6 in which barrier layer is doped by a dopant selected from the group consisting of phosphorous, arsenic and antimony.

16. The device of claim 1 further including control line means proximate said superconductive layers and electrically insulated therefrom for providing a control magnetic field to said barrier layer thereby controlling said Josephson tunnelling current flowing therethrough.

17. The device of claim 16 further including superconductive ground plane means with said first and second superconductive layers superposed between said control line means and said ground plane means.

24. A method of manufacturing the device of claim 1 comprising the steps of:

depositing a first layer of refractory compound superconductive material on a substrate,

depositing an insulator layer on said first superconductive layer,

forming at least one opening through said insulator layer,

depositing a layer of polycrystalline semiconductor on said first insulator layer by chemical vapor deposition thereby depositing said polycrystalline semiconductor material in said opening,

said semiconductor material selected from the group consisting of silicon, germanium and alloys thereof, and

depositing a second layer of superconductive material on said layer of semiconductor material,

said semiconductor material within said opening forming a Josephson tunnelling barrier between said first and second superconductive layers.

26. The method of claim 24 in which said step of depositing a first layer of refractory compound superconductive material comprises the step of depositing a layer of niobium nitride on said substrate.

27. The method of claim 24 further including the step of doping said semiconductor material during said chemical vapor deposition thereof.

18. A Josephson tunnel junction device for use as a switch in superconductive circuits comprising:

a superconductive ground plane,

a dielectric layer deposited on said ground plane,

a first layer of refractory compound superconductive material deposited on said dielectric layer,

a first insulator layer deposited on said first superconductive layer with at least one opening therethrough for defining a Josephson tunnelling barrier area,

a barrier layer of polycrystalline semiconductor material deposited on said first insulator layer and into said opening,

said semiconductor material selected from the group consisting of silicon, germanium and alloys thereof,

a second layer of superconductive material deposited on said layer of semiconductor material,

said semiconductor material deposited in said opening forming a Josephson tunnelling barrier between said first and second superconductive layers whereby Josephson tunnelling current can flow therethrough between said superconductive layers,

a second insulator layer deposited on said second superconductive layer, and

superconductive control line means deposited on said second insulator layer for providing a control magnetic field to said barrier thereby controlling the Josephson tunnelling current flowing between said superconductive layers through said barrier.

19. The device of claim 18 in which said first layer of superconductive material comprises niobium nitride.

20. The device of claim 19 in which said barrier layer comprises said polycrystalline semiconductor material deposited on said first superconductive layer by chemical vapor deposition.

21. The device of claim 20 in which said barrier layer comprises doped polycrystalline semiconductor material selected from the group consisting of silicon, germanium and alloys thereof.

22. A method of manufacturing the device of claim 18 comprising the steps of:

depositing a dielectric layer on a superconductive ground plane,

depositing a first layer of refractory compound superconductive material on said dielectric layer,

depositing a first insulator layer on said first superconductive layer,

forming at least one opening through said first insulator layer,

depositing a layer of polycrystalline semiconductor material by chemical vapor deposition on said first insulator layer thereby depositing said polycrystalline semiconductor material in said opening,

said semiconductor material selected from the group consisting of silicon, germanium and alloys thereof,

depositing a second layer of superconductive material on said layer of semiconductor material,

said semiconductor material within said opening forming a Josephson tunnelling barrier between said first and second superconductive layers,

depositing a second insulator layer on said second superconductive layer, and

depositing superconductive control line means on said second insulator layer.

23. The method of claim 22 further including the step of doping said semiconductor material during said chemical vapor deposition thereof.

25. The method of claim 22 in which said step of depositing a first layer of refractory compound superconductive material comprises the step of depositing a layer of niobium nitride on said dielectric layer.