Cathode materials

• US 4,223,110 A
• Filed: 10/16/1978
• Issued: 09/16/1980
• Est. Priority Date: 10/16/1978
• Status: Expired due to Term

• Current Assignee: Medtronic Incorporated (Medtronic Plc)
• Original Assignee: Medtronic Incorporated (Medtronic Plc)
• Inventors: Untereker, Darrel F., Phillips, Gary M.
• Primary Examiner(s): Hamrock, William F.
• Application Number:
  US05/951,862
• Time in Patent Office: 701 Days
• Field of Search: 526/43
• US Class Current: 525/356
• CPC Class Codes: H01M 4/60 of organic compounds
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

Methods for the preparation of polyvinylpyridine and iodine (PVP.nI₂) as cathode materials for electrochemical cells.

Claims

1. In the method of preparing cathode material comprising the steps of mixing polymeric material selected from the group consisting of P2VP, P4VP, and mixtures thereof with a quantity of iodine and heating the mixture, the improvement comprising placing the mixture in a sealed container in the presence of a protective atmosphere prior to heating and heating to a temperature of at least about 150°

C.

2. The improved method of claim 1 wherein the protective atmosphere is a vacuum.

3. The improved method of claim 2 wherein the polymeric material is P2VP.

4. The improved method of claim 1 wherein the atmosphere is inert.

5. The improved method of claim 4 wherein the atmosphere is argon.

6. The method of claim 1 wherein the heating temperature is between about 225°

C. and about 350°

C.

7. The method of claim 6 wherein the time of heating is less than about 8 hours.

8. The method according to any of the preceding claims 1, 2, 3, 4, 5, 6 or 7 wherein additional iodine is added to the material following the heating step.

10. The method of either of the preceding claims 2 or 9 wherein the vacuum level is about 1 mm of Hg.

11. The method of either of the preceding claims 2 or 9 wherein the vacuum level is less than about 100 mm of Hg.

14. The method of claim 1 wherein the heating temperature is in excess of about 225°

C.

15. The method of claim 14 wherein the time of heating is less than about 8 hours.

16. The method according to either of the preceding claims 1 or 14 wherein additional iodine is added to the material following the heating step.

9. In the method of preparing cathode material comprising the steps of mixing polymeric material selected from the group consisting of P2VP, P4VP, and mixtures thereof with a quantity of iodine and heating the mixture, the improvement comprising placing the mixture in a container and subjecting it to a treatment sequence selected from the group consisting of:

A. sealing the mixture in the container under vacuum and heating the mixture for a time to a temperature of at least about 150°

C.

B. sealing the mixture in the container with an inert atmosphere and heating the mixture for a time to a temperature of at least about 150°

C., and

C. sealing the mixture in the container with an atmosphere selected from the group consisting of ambient, inert, and vacuum, heating the mixture for a time to a temperature of at least about 150°

C., and subjecting the mixture to a vacuum for a time following the heating step to remove volatiles.

12. The method of claim 9 wherein additional iodine is added to the material following the heating step.

13. The method of claim 9 wherein the inert atmosphere of items B and C is selected from the group consisting of argon, helium and mixtures thereof.

17. The method of claim 9 wherein additional iodine is added to the material following the heating step.

18. The method of claim 9 wherein the heating temperature in items A, B and C is in excess of about 225°

C.

19. The method of claim 18 wherein the heating temperature is below about 350°

C.

20. The method of claim 9 wherein the heating temperature in items A, B and C is less than about 350°

C.

21. The method of claim 9 wherein the heating temperature in items A, B and C is in excess of about 350°

C.