Process for producing cracked distillate and hydrogen from heavy oil

• US 4,224,140 A
• Filed: 03/21/1979
• Issued: 09/23/1980
• Est. Priority Date: 01/30/1979
• Status: Expired due to Term

• Current Assignee: Japan Energy Corporation (ENEOS Holdings, Inc.)
• Original Assignee: Nippon Mining Co Ltd (ENEOS Holdings, Inc.)
• Inventors: Aizawa, Shirou, Suzuka, Teruo, Fujimori, Kuniaki, Satomi, Yoshihito
• Primary Examiner(s): Levine, Herbert
• Assistant Examiner(s): Schmitkons, G. E.
• Application Number:
  US06/022,385
• Time in Patent Office: 552 Days
• Field of Search: 208/124, 208/255, 423/658, 423/148
• US Class Current: 208/124
• CPC Class Codes: B01J 23/745 Iron
• CPC Class Codes: B01J 37/0018 Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
• CPC Class Codes: C10G 11/04 Oxides
• CPC Class Codes: C10G 11/18 according to the "fluidised-bed" technique
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

A process for producing a cracked distillate and hydrogen from a heavy oil which comprises cracking the heavy oil in the presence of laterite or a laterite-containing catalyst while simultaneously depositing coke on said laterite or laterite-containing catalysts, reducing the laterite or laterite-containing catalyst on which the coke is deposited, and forming a hydrogen-rich gas by contacting the reduced laterite or laterite-containing catalyst with steam.

Claims

1. A process for producing a cracked distillate and hydrogen from a heavy oil which comprises cracking the heavy oil in the presence of laterite or a laterite-containing catalyst while simultaneously depositing coke on said laterite or laterite-containing catalyst, reducing the laterite or laterite-containing catalysts on which the coke is deposited while simultaneously burning the coke in a reducing atmosphere, and forming a hydrogen-rich gas by contacting the reduced laterite or laterite-containing catalyst with steam.

2. The process of claim 1, wherein said laterite contains about 30 to 60% by weight of iron.

3. The process of claim 1, wherein said cracking is conducted at a temperature of about 450°

to 600°

C. under a pressure of about 0 to 15 kg/cm² G.

4. The process of claim 1, wherein said coke is deposited on said catalyst in an amount of about 2% to 15% by weight based on the weight of the catalyst.

5. The process of claim 1, wherein said coke is deposited on said catalyst in an amount of about 2 to 8% by weight based on the weight of the catalyst.

6. The process of claim 1, wherein said catalyst having coke deposited thereon is reduced at a temperature of about 750°

to 900°

C.

7. The process of claim 1, wherein said reduced catalyst is contacted with steam at a temperature of about 600°

to 950°

C. under a pressure of about 0 to 15 kg/cm² G whereby hydrogen is formed.

11. The process of claim 1 or claim 8, wherein said laterite-containing catalyst is a mixture of laterite and up to about 30% by weight of at least one member selected from nickel ore, pyrite cinder, magnetite, alumina, limestone, dolomite and calcium hydroxide.

12. The process of claim 1 or claim 8, wherein said laterite or laterite-containing catalyst is prepared by pulverizing natural laterite or a laterite mixed material, granulating to form particles having an average particle size of about 60 to 500 microns and sintering at 900°

C. or more.

13. The process of claim 1 or claim 8, wherein the reduction of said laterite or laterite-containing catalyst is carried out by introducing an oxygen-containing gas in an amount of about 0.1 to 0.7 mole per mole of carbon in the coke calculated as oxygen.

14. The process of claim 1 or claim 8, wherein when reducing said laterite or laterite-containing catalyst, sulfur compounds present in the coke are converted to iron sulfide which is then decomposed by steam when forming hydrogen.

8. A fluidized bed process for producing a cracked distillate and hydrogen from a heavy oil which comprises introducing said heavy oil into a first reaction zone containing a fluidized bed of laterite or a laterite-containing catalyst at a temperature of about 450°

to 600°

C. under a pressure of about 0 to 15 kg/cm² G and simultaneously depositing coke on said catalyst, removing the cracked distillate from said reaction zone and circulating said coke deposited laterite catalyst to a second reaction zone wherein said coke deposited laterite catalyst is fluidized and reduced at a temperature of about 750°

to 950°

C. under a pressure of about 0 to 15 kg/cm² G while simultaneously burning the coke in a reducing atmosphere, circulating said reduced laterite catalyst to a third reaction zone wherein said catalyst is fluidized and contacted with steam at a temperature of about 600°

to 950°

C. under a pressure of about 0 to 15 kg/cm² whereby a hydrogen-rich gas is formed.

9. The process of claim 8, wherein upon completion of the reaction in said third reaction zone, said oxidized laterite catalyst is recirculated to said first reaction zone for reuse.

10. The process of claim 9, wherein said laterite or laterite-containing catalyst contains about 30 to 60% by weight of iron.

15. The process of claim 9, wherein a part of said laterite or laterite-containing catalyst in the second reaction zone is circulated into the first reaction zone.