Catalyst for dehydrogenating organic compounds, in particular amines, thiols, and alcohols, and a process for its preparation

• US 4,224,190 A
• Filed: 07/19/1978
• Issued: 09/23/1980
• Est. Priority Date: 07/22/1977
• Status: Expired due to Term

• Current Assignee: Carl E. Moller, Hans Livbjerg, John Villadsen
• Original Assignee: Carl E. Moller, Hans Livbjerg, John Villadsen
• Inventors: Villadsen, John, Moller, Carl E., Livbjerg, Hans
• Primary Examiner(s): Dees, Carl F.
• Application Number:
  US05/925,930
• Time in Patent Office: 797 Days
• Field of Search: 252/463, 252/475, 252/447
• US Class Current: 502/253
• CPC Class Codes: C07C 45/002 by dehydrogenation

Abstract

Alcohols are dehydrogenated to form ketones, using a catalyst containing liquid indium dispersed and retained in the pore structure of a porous carrier. The catalyst is prepared by mixing powdered In₂ O₃ and MgO, firing the mixture at 900°-1150° C. for 5-20 hours, and activating the catalyst by passing through a reducing gas.

Claims

1. A catalyst for dehydrogenating an organic compound reactant in the gaseous phase comprising a solid state carrier material having a porosity of from about 0.2 to 0.7 cm³ /cm³, and an active catalytic metal selected from the group consisting of indium and zinc within the pores of said carrier, said catalytic metal being in the liquid state at the reaction temperature of the gaseous reactant and forming droplets having diameters ranging from about 0.3 to 2.0 microns, said droplets being encased in pores forming cavities having diameters greater than the diameters of the respective droplets therein contained, said cavities being interconnected to other pores having diameters less than the diameters of the metal droplets and forming a system of interconnected ducts connecting the external surface of the carrier with the surfaces of the metal droplets, and said carrier material having a contact angle of more than 90°

in contacting the liquid metal droplets.

2. A catalyst according to claim 1, wherein the carrier has a BET-surface area of from about 0.5 to 10 m² /g.

3. A catalyst according to claim 1, wherein the active catalytic metal is indium, which is present in an amount of from about 0.05 to 10.0 g./100 g. of fired catalyst.

4. A catalyst according to claim 3, wherein the indium content is from about 0.5 to 1.5 g/100 g of fired catalyst.

5. A process for preparing a catalyst for dehydrogenating organic compounds comprising mixing a powdered source of an active catalytic metal selected from the group consisting of In₂ O₃ and ZnO with a carrier material selected from the group consisting of oxides and hydroxides of Mg, Al, Si, Ca, Ti, Cr, Zn, W and mixtures thereof, firing the resulting mixture at a temperature of from about 900°

to 1150°

C. for about 5 to 20 hours, activating the catalyst by subjecting the same at a temperature of from about 320°

to 440°

C. to contact with a gas selected from the group consisting of reducing gases and an organic compound to be dehydrogenated, until 2 to 3 times the calculated stoichiometric amount of gas for complete reduction of In₂ O₃ to In or ZnO to Zn respectively has passed through the catalyst.

6. A process according to claim 5, wherein powdered In₂ O₃ is mixed with powdered MgO containing a lubricant, and the mixture is compressed into pellets before firing the same.

7. A process according to claim 5, wherein powdered In₂ O₃ is mixed with an aqueous Mg(OH)₂ gel while grinding to form a paste containing In₂ O₃ granules under 5u in size uniformly dispersed in the Mg(OH)₂ gel, drying the paste at about 100°

to 150°

C. to a dryness of from about 40 to 60% and extruding the so dried product before firing the same.