Conductometric gas analysis cell

• US 4,228,400 A
• Filed: 03/28/1978
• Issued: 10/14/1980
• Est. Priority Date: 03/28/1978
• Status: Expired due to Term

• Current Assignee: Research Corporation
• Original Assignee: Research Corporation
• Inventors: Bruckenstein, Stanley, Martinchek, Gregory A.
• Primary Examiner(s): Tokar, Michael J.
• Application Number:
  US05/890,951
• Time in Patent Office: 931 Days
• Field of Search: 324/30 B, 324/30 R, 204/195 R, 204/195 M, 204/195 P, 340/237 R, 73/23
• US Class Current: 324/450
• CPC Class Codes: G01N 27/07 Construction of measuring vessels; Electrodes therefor
• CPC Class Codes: G01N 33/0027 concerning the detector

Abstract

A conductometric gas analysis cell comprised of a porous Teflon membrane supporting interdigited electrodes separates a thin layer of deionized water from a gas phase to be analyzed. Volatile species in the gas phase pass through the membrane and increase the conductance of the water which results in increased current flow between the interdigited electrodes.

Claims

1. A conductometric gas analysis apparatus, comprising:

a conductivity cell; and

said conductiviy cell comprises a gas permeable membrane having a liquid side and a gas side;

a first electrode on said liquid side;

a second electrode on said liquid side and spaced from the first electrode;

a liquid chamber means for applying and renewing a thin film of liquid over said gas permeable membrane liquid side and said first and second electrodes, a gas chamber means associated with the gas side of the gas permeable membrane, liquid inlet and outlet means for said liquid chamber means, gas inlet means for said gas chamber means, and means for continuously supplying a liquid to the liquid inlet and a gas to be analyzed to the gas inlet.

2. A conductometric gas analysis apparatus, comprising:

a conductivity cell; and

said conductivity cell comprises a gas porous membrane having a liquid side and a gas side;

a first electrode supported on said gas porous membrane liquid side;

a second electrode supported on said gas porous membrane liquid side and spaced from the first electrode;

a water chamber means for applying a thin film of water over said gas porous membrane liquid side and said first and second electrodes; and

a gas chamber means for applying a gas to be analyzed to said gas porous membrane gas side, wherein said first and said second electrodes incorporate a plurality of interdigited elements.

3. A conductometric gas analysis apparatus as defined in claim 2, comprising:

a water reservoir;

means for deionizing water;

means for transporting water from said water reservoir to said means for deionizing water; and

means for transporting water from said water deionizing means to said water chamber.

4. A conductometric gas analysis apparatus as defined in claim 3, comprising:

a gas pump; and

means to couple gas from said pump to said gas chamber.

5. A conductometric gas analysis apparatus as defined in claim 4 wherein said means to couple gas from said gas pump to said gas chamber comprises a filter means to eliminate predetermined gas constituents from said gas being transported from said gas pump to said gas chamber.

6. A conductometric gas analysis apparatus as defined in claim 5 wherein said filter means includes an absorbent.

7. A conductometric gas analysis apparatus as defined in claim 5 wherein said filter means includes a reactant.

8. A conductometric gas analysis apparatus as defined in claim 5, comprising:

electric circuit means to apply an electric current between said first and said second electrodes; and

means responsive to current flow between said first and said second electrodes for providing an indication representating the magnitude of said current flow.

9. A conductometric gas analysis apparatus as defined in claim 8, comprising:

a thermistor responsive to the temperature within said water chamber; and

means responsive to said thermistor for altering said indication.

10. A conductometric gas analysis apparatus as defined in claim 5 wherein said gas permeable member is a hydrophobic porous membrane.

11. A conductometric gas analysis apparatus as defined in claim 5 wherein said gas permeable member is a porous Teflon membrane.

12. A conductometric gas analysis apparatus as defined in claim 5 wherein said first and second electrodes are gold.

13. A conductometric gas analysis apparatus, comprising:

a conductivity cell; and

said conductivity cell comprises a gas permeable membrane having a liquid side and a gas side;

a first electrode on said liquid side;

a second electrode on said liquid side and spaced from the first electrode;

a liquid chamber means for applying a thin film of liquid over said gas permeable membrane liquid side and said first and second electrodes, and a gas absorbent for said apparatus, said gas absorbent selected from the group consisting of activated charcoal treated with sodium bisulfate, activated charcoal treated with sodium bicarbonate, firebrick treated with brucine sulfate in sulfuric acid and firebrick treated with basic absorbants.