Process for extracting bitumen from tar sands

• US 4,229,281 A
• Filed: 08/14/1978
• Issued: 10/21/1980
• Est. Priority Date: 08/14/1978
• Status: Expired due to Term

• Current Assignee: Phillips Petroleum Company (ConocoPhillips)
• Original Assignee: Phillips Petroleum Company (ConocoPhillips)
• Inventors: Alquist, Henry E., Ammerman, Allen M.
• Primary Examiner(s): Gantz, Delbert E.
• Assistant Examiner(s): Boska, Joseph A.
• Application Number:
  US05/933,346
• Time in Patent Office: 799 Days
• Field of Search: 208/11 LE
• US Class Current: 208/424
• CPC Class Codes: C10C 3/007 winning and separation of asphalt from mixtures with aggregates, fillers and other products, e.g. winning from natural asphalt and regeneration of waste asphalt
• CPC Class Codes: C10G 1/045 Separation of insoluble materials
• CPC Class Codes: C10G 1/047 Hot water or cold water extraction processes

Abstract

Bitumen is recovered from tar sand by extraction with a solvent. The bitumen solution is washed with water containing a cationic surfactant in order to remove sand fines therefrom.

Claims

1. A process for recovering bitumen from tar sands wherein bitumen is extracted from the tar sands with a solvent which process comprises contacting the bitumen solution comprising said solvent, bitumen and sand fines with water containing about 0.01 to about 0.10 weight percent of a cationic surfactant to effect the removal of said sand fines from said bitumen solution,

recovering the resulting bitumen solution thereafter and recovering bitumen from said bitumen solution.

2. A process in accordance with claim 1 wherein said cationic surfactant comprises 80 percent methyldodecylbenzyl trimethylammonium chloride and 20 percent methyldodecylxylylene-bis-(trimethylammonium chloride).

3. A process in accordance with claim 1 wherein said solvent is an aromatic hydrocarbon solvent.

4. A process for recovering bitumen from tar sands comprising the steps of:

(a) mixing the tar sands with an extractive solvent,

(b) allowing the mixture of step (a) to settle into a fine sand-bitumen solvent phase and a coarse sand phase,

(c) removing the fine sand-bitumen solvent phase,

(d) contacting said fine sand-bitumen solvent phase with water containing a cationic surfactant wherein the amount of said cationic surfactant present in the water is the range of about 0.01 to about 0.10 weight percent and allowing the mixture to settle into a solvent phase, an interface zone where the fines collect, and an aqueous phase, and

(e) removing the solvent phase and separating said phase into solvent and bitumen product.

5. A process in accordance with claim 4 which further comprises

diluting the solvent phase to be separated into solvent and bitumen product prior to said separation with a high boiling solvent in order to reduce the viscosity of the bitumen during solvent recovery.

6. A process in accordance with claim 4 wherein said solvent is an aromatic hydrocarbon solvent.

7. A process in accordance with claim 6 wherein said aromatic hydrocarbon solvent is toluene and the cationic surfactant comprises 80 percent methyldodecylbenzyl trimethylammonium chloride and 20 percent methyldodecylxylene-bis-(trimethylammonium chloride).