Multicomponent membranes for gas separations
First Claim
1. A multicomponent membrane for gas separation comprising a coating in occluding contact with a porous separation membrane of material, which material exhibits selective permeation of at least one gas of a gaseous mixture over that of one or more remaining gases of the gaseous mixture, said porous separation membrane having a substantial void volume, wherein, with respect to at least one pair of gases, the material of the porous separation membrane exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the material of said coating, and the multicomponent membrane exhibits a separation factor significantly greater than the determined intrinsic separation factor of the material of said coating and greater than the separation factor exhibited by the porous separation membrane.
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Accused Products
Abstract
Multicomponent membranes for gas separation are disclosed which are effective for separating at least one gas from gaseous mixtures by permeation wherein the multicomponent membranes are comprised of a coating in occluding contact with a porous separation membrane. The multicomponent membranes advantageously exhibit less resistance to permeate gas flow for the at least one gas than for at least one remaining gas in the gaseous mixture. For at least one pair of gases the separation factor of the multicomponent membrane is significantly greater than the determined intrinsic separation factor of the material of the coating. Processes and apparatus for gas separation utilizing the multicomponent membranes are also disclosed.
442 Citations
78 Claims
- 1. A multicomponent membrane for gas separation comprising a coating in occluding contact with a porous separation membrane of material, which material exhibits selective permeation of at least one gas of a gaseous mixture over that of one or more remaining gases of the gaseous mixture, said porous separation membrane having a substantial void volume, wherein, with respect to at least one pair of gases, the material of the porous separation membrane exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the material of said coating, and the multicomponent membrane exhibits a separation factor significantly greater than the determined intrinsic separation factor of the material of said coating and greater than the separation factor exhibited by the porous separation membrane.
- 2. A multicomponent membrane for gas separation comprising a coating and a porous separation membrane of material, which material exhibits selective permeation of at least one gas of a gaseous mixture over that of one or more remaining gases of the gaseous mixture, said porous separation membrane being anisotropic having a substantial void volume and at least one relatively dense region within its thickness in barrier flow relationship to gas flow across the porous separation membrane, wherein the coating is in occluding contact with at least one relatively dense region, wherein with respect to at least one pair of gases consisting of one of hydrogen, helium, ammonia and carbon dioxide and one of carbon monoxide, nitrogen, argon, sulfur hexafluoride, methane and ethane, the material of the porous separation membrane exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the material of said coating, and the multicomponent membrane exhibits a separation factor significantly greater than the determined intrinsic separation factor of the material of the coating and greater than the separation factor exhibited by the porous separation membrane.
- 33. A multicomponent membrane for gas separation comprising a coating in occluding contact with a porous separation membrane of a material, which material exhibits selective permeation of at least one gas of a gaseous mixture over that of one or more remaining gases of the gaseous mixture, said coating being applied using an essentially liquid substance suitable for forming the coating, wherein, with respect to at least one pair of gases, the material of the porous separation membrane exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the material of said coating, and the multicomponent membrane exhibits a separation factor significantly greater than the determined intrinsic separation factor of the material of said coating and greater than the separation factor exhibited by the porous separation membrane.
- 40. A multicomponent membrane for gas separation comprising a coating in occluding contact with a porous separation membrane comprising polysulfone wherein, with respect to at least one pair of gases, the polysulfone exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the material of said coating, and the multicomponent membrane exhibits a separation factor significantly greater than the determined intrinsic separation factor of the material of said coating and greater than the separation factor exhibited by the porous separation membrane.
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45. A multicomponent membrane for gas separation comprising a coating and a hollow fiber porous separation membrane of material, which material exhibits selective permeation of at least one gas of a gaseous mixture over that of one or more remaining gases of the gaseous mixture, said porous separation membrane being anisotropic having a substantial void volume and at least one relatively dense region within its thickness in barrier flow relationship to gas flow across the porous separation membrane, wherein the coating is in occluding contact with at least one relatively dense region, wherein, with respect to at least one pair of gases, the material of the porous separation membrane exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the material of said coating, and the multicomponent membrane exhibits a separation factor at least about 35 percent greater than the determined intrinsic separation factor of the material of said coating and greater than the separation factor exhibited by the porous separation membrane.
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46. A multicomponent membrane for a gas separation comprising a coating in occluding contact with a porous separation membrane of a material, which material exhibits selective permeation of at least one gas of a gaseous mixture over that of one or more remaining gases of the gaseous mixture, in which the porous separation membrane has a substantial void volume, wherein, with respect to at least one pair of gases, the material of the porous separation membrane exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the material of said coating, and the multicomponent membrane exhibits a separation factor at least about 35 percent greater than the determined intrinsic separation factor of the material of said coating and at least about 10 percent greater than the separation factor exhibited by the porous separation membrane.
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49. A process for separating at least one gas in a gaseous mixture from at least one other gas in said gaseous mixture by selective permeation and providing a permeated product containing at least one permeating gas, comprising:
- contacting the gaseous mixture with one surface of a multicomponent membrane, which, with respect to at least one pair of gases of said gaseous mixture, multicomponent membrane exhibits selective permeation of one gas of said pair of gases over that of the remaining gas of said pair of gases, and which multicomponent membrane comprises a coating in occluding contact with a porous separation membrane having a substantial void volume, wherein, with respect to said pair of gases, the material of the porous separation membrane exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the material of said coating, and the multicomponent membrane exhibits a separation factor significantly greater than the determined intrinsic separation factor of the material of the coating and greater than the separation factor exhibited by the porous separation membrane;
maintaining the opposite surface of the multicomponent membrane at a lower chemical potential for said at least one permeating gas than the chemical potential at the said surface;
permeating said at least one permeating gas into and through the multicomponent membrane; and
removing from the vicinity of said opposite surface a permeated product having a different proportion of said at least one gas of said gaseous mixture to said at least one other gas of said gaseous mixture than the proportion in the gaseous mixture of said at least one gas to said at least one other gas.
- contacting the gaseous mixture with one surface of a multicomponent membrane, which, with respect to at least one pair of gases of said gaseous mixture, multicomponent membrane exhibits selective permeation of one gas of said pair of gases over that of the remaining gas of said pair of gases, and which multicomponent membrane comprises a coating in occluding contact with a porous separation membrane having a substantial void volume, wherein, with respect to said pair of gases, the material of the porous separation membrane exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the material of said coating, and the multicomponent membrane exhibits a separation factor significantly greater than the determined intrinsic separation factor of the material of the coating and greater than the separation factor exhibited by the porous separation membrane;
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50. A process for separating at least one gas in a gaseous mixture from at least one other gas in said gaseous mixture by selective permeation and providing a permeated product containing at least one permeating gas, comprising:
- contacting the gaseous mixture with one surface of a multicomponent membrane, which, with respect to at least one pair of gases of said gaseous mixture multicomponent membrane exhibits selective permeation of one gas of said pair of gases over that of the remaining gas of said pair of gases, and which multicomponent membrane comprises a coating and a porous separation membrane being anisotropic having a substantial void volume and at least one relatively dense region within its thickness in barrier flow relationship to gas flow across the porous separation membrane, wherein the coating is in occluding contact with at least one relatively dense region, wherein, with respect to said pair of gases, the material of the porous separation membrane exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the material of said coating, and the multicomponent membrane exhibits a separation factor significantly greater than the determined intrinsic separation factor of the material of the coating and greater than the separation factor exhibited by the porous separation membrane;
maintaining the opposite surface of the multicomponent membrane at a lower chemical potential for said at least one permeating gas than the chemical potential at the said surface;
permeating said at least one permeating gas into and through the multicomponent membrane; and
removing from the vicinity of said opposite surface a permeated product having a different proportion of said at least one gas of said gaseous mixture to said at least one other gas of said gaseous mixture than the proportion in the gaseous mixture of said at least one gas to said at least one other gas. - View Dependent Claims (51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75)
- contacting the gaseous mixture with one surface of a multicomponent membrane, which, with respect to at least one pair of gases of said gaseous mixture multicomponent membrane exhibits selective permeation of one gas of said pair of gases over that of the remaining gas of said pair of gases, and which multicomponent membrane comprises a coating and a porous separation membrane being anisotropic having a substantial void volume and at least one relatively dense region within its thickness in barrier flow relationship to gas flow across the porous separation membrane, wherein the coating is in occluding contact with at least one relatively dense region, wherein, with respect to said pair of gases, the material of the porous separation membrane exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the material of said coating, and the multicomponent membrane exhibits a separation factor significantly greater than the determined intrinsic separation factor of the material of the coating and greater than the separation factor exhibited by the porous separation membrane;
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76. A process for separating at least one gas in a gaseous mixture from at least one other gas in said gaseous mixture by selective permeation and providing a permeated product containing at least one permeating gas comprising:
- contacting the gaseous mixture with one surface of a multicomponent membrane, which, with respect to at least one pair of gases of said gaseous mixture, multicomponent membrane exhibits selective permeation of one gas of said pair of gases over that of the remaining gas of said pair of gases, and which multicomponent membrane comprises a coating in occluding contact with a porous separation membrane having a substantial void volume, wherein, with respect to said pair of gases, the material of the porous separation membrane exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the material of said coating, and the multicomponent membrane exhibits a separation factor at least about 35 percent greater than the determined intrinsic separation factor of the material of the coating and at least about 10 percent greater than the separation factor exhibited by the porous separation membrane;
maintaining the opposite surface of the multicomponent membrane at a lower chemical potential for said at least one permeating gas than the chemical potential at the said one surface;
permeating said at least one permeating gas into and through the multicomponent membrane; and
removing from the vicinity of said opposite surface a permeated product having a different proportion of said at least one gas of said gaseous mixture to said at least one other gas of said gaseous mixture than that proportion in the gaseous mixture of said at least one gas to said at least one other gas.
- contacting the gaseous mixture with one surface of a multicomponent membrane, which, with respect to at least one pair of gases of said gaseous mixture, multicomponent membrane exhibits selective permeation of one gas of said pair of gases over that of the remaining gas of said pair of gases, and which multicomponent membrane comprises a coating in occluding contact with a porous separation membrane having a substantial void volume, wherein, with respect to said pair of gases, the material of the porous separation membrane exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the material of said coating, and the multicomponent membrane exhibits a separation factor at least about 35 percent greater than the determined intrinsic separation factor of the material of the coating and at least about 10 percent greater than the separation factor exhibited by the porous separation membrane;
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77. A process for separating at least one gas comprising hydrogen in a gaseous mixture from at least one other gas comprising at least one of carbon monoxide, carbon dioxide, helium, nitrogen, oxygen, argon, hydrogen sulfide, nitrous oxide, ammonia and hydrocarbon of 1 to about 5 carbon atoms, in said gaseous mixture by selective permeation and providing a permeated product containing at least one permeating gas comprising:
- contacting the gaseous mixture with one surface of a multicomponent membrane which, with respect to at least one pair of gases of said gaseous mixture, multicomponent membrane exhibits selective permeation of one gas of said pair of gases over that of the remaining gas of said pair of gases, in which said multicomponent membrane comprises a coating in occluding contact with a porous separation membrane, wherein, with respect to said pair of gases, the material of the porous separation membrane exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the material of said coating, and the multicomponent membrane exhibits a separation factor significantly greater than the determined intrinsic separation factor of the material of the coating and greater than the separation factor exhibited by the porous separation membrane;
maintaining the opposite surface of the multicomponent membrane at a lower chemical potential for said at least one permeating gas than the chemical potential at the said one surface;
permeating said at least one permeating gas into and through the multicomponent membrane; and
removing from the vicinity of said opposite surface a permeated product having a different proportion of said at least one gas to said at least one other gas than that proportion in said gaseous mixture of said at least one gas to said at least one other gas.
- contacting the gaseous mixture with one surface of a multicomponent membrane which, with respect to at least one pair of gases of said gaseous mixture, multicomponent membrane exhibits selective permeation of one gas of said pair of gases over that of the remaining gas of said pair of gases, in which said multicomponent membrane comprises a coating in occluding contact with a porous separation membrane, wherein, with respect to said pair of gases, the material of the porous separation membrane exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the material of said coating, and the multicomponent membrane exhibits a separation factor significantly greater than the determined intrinsic separation factor of the material of the coating and greater than the separation factor exhibited by the porous separation membrane;
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78. A process for separating at least one gas in a gaseous mixture from at least one other gas in said gaseous mixture by selective permeation and providing a permeated product containing at least one permeating gas comprising:
- contacting the gaseous mixture with one surface of a multicomponent membrane which, with respect to at least one pair of gases of said gaseous mixture, multicomponent membrane exhibits selective permeation of one gas of said pair of gases over that of the remaining gas of said pair of gases, and which membrane comprises a coating in occluding contact with a porous separation membrane comprising polysulfone, wherein, with respect to said pair of gases, the polysulfone exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the material of said coating, and the multicomponent membrane exhibits a separation factor at least about 35 percent greater than the determined intrinsic separation factor of the material of the coating and greater than the separation factor exhibited by the porous separation membrane;
maintaining the opposite surface of the multicomponent membrane at a lower chemical potential for said at least one permeating gas than the chemical potential at the said one surface;
permeating said at least one permeating gas into and through the multicomponent membrane; and
removing from the vicinity of said opposite surface a permeated product having a different proportion of said at least one gas to said at least one other gas than that proportion in said gaseous mixture of said at least one gas to said at least one other gas.
- contacting the gaseous mixture with one surface of a multicomponent membrane which, with respect to at least one pair of gases of said gaseous mixture, multicomponent membrane exhibits selective permeation of one gas of said pair of gases over that of the remaining gas of said pair of gases, and which membrane comprises a coating in occluding contact with a porous separation membrane comprising polysulfone, wherein, with respect to said pair of gases, the polysulfone exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the material of said coating, and the multicomponent membrane exhibits a separation factor at least about 35 percent greater than the determined intrinsic separation factor of the material of the coating and greater than the separation factor exhibited by the porous separation membrane;
Specification