High surface area permeable material

• US 4,231,979 A
• Filed: 10/12/1979
• Issued: 11/04/1980
• Est. Priority Date: 10/12/1979
• Status: Expired due to Term

• Current Assignee: Research Corporation
• Original Assignee: Research Corporation
• Inventors: Hanusiak, William M., White, Eugene W., White, Rodney A.
• Primary Examiner(s): Cohan, Alan
• Application Number:
  US06/084,126
• Time in Patent Office: 389 Days
• Field of Search: 137/1, 137/15, 210/22, 210/321 B, 210/500 M, 264/44, 264/321, 264/317 X, 264/DIG. 48, 264/137, 264/221, 264/331
• US Class Current: 264/81
• CPC Class Codes: B01D 63/066 with a porous block having membrane coated passages
• CPC Class Codes: B01D 69/106 Membranes in the pores of a support, e.g. polymerized in the pores or voids
• CPC Class Codes: B01J 19/0013 Controlling the temperature of the process
• CPC Class Codes: B01J 2219/00164 controlling the flow
• CPC Class Codes: C04B 38/00 Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof treating slag with gases or gas generating material C04B5/06 ; expanded graphite C04B35/536
• CPC Class Codes: C08J 9/26 by elimination of a solid phase from a macromolecular composition or article, e.g. leaching out
• CPC Class Codes: F28F 13/003 by using permeable mass, perforated or porous materials F28F13/18 takes precedence
• CPC Class Codes: F28F 21/04 of ceramic; of concrete; of natural stone
• CPC Class Codes: F28F 7/02 Blocks traversed by passages for heat-exchange media F28D7/0008 takes precedence
• CPC Class Codes: Y10T 137/8593 Systems

Abstract

Three-dimensional structures providing a plurality of separate interpenetrating, three-dimensional domains or channels or flowpaths, each of said domains or channels or flowpaths being a closed system of connected porosity or permeability and each of said domains or channels or flowpaths being interpenetrating within said structure, have been prepared. These structures are prepared from porous permeable precursor materials having a single three-dimensional domain or channel or flowpath as described above. Suitable precursor materials are provided by the abundant porous carbonate skeletal material of marine life, e.g. the coral Porites skeletal aragonite. For example, by coating the surfaces of such materials with a liquid material capable of being cured or set to a solid, followed by curing or setting and dissolution, e.g. chemical etching, of the coated skeletal material, there is produced a three-dimensional structure in accordance with this invention possessing two separate interpenetrating, three-dimensional domains or channels or flowpaths defined by the residual cured or set coating material. The resulting structure of this invention can be adapted such that a fluid can be applied to one side or face of the structure to flow into and out of such structure via only one of said channels or flowpaths and when so adapted can be employed in apparatus for the treatment or handling of one or more of the fluid streams flowing therethrough.

Claims

1. A method of producing an integral, three-dimensional structure providing a plurality of separate, interpenetrating, three-dimensional domains or channels, each of said domains or channels being a closed system of connected porosity or permeability with multiple interconnections only with respect to its respective domain or channel, each of said domains or channels being interpenetrating within said structure, which comprises filling or impregnating with a settable or curable liquid a porous, permeable, three-dimensional structure characterized by having a single interpenetrating, three-dimensional, multiple-connected channel or flowpath therein defined by solid material making up said three dimensional structure such that said flowpath or channel is occupied by said settable or curable liquid, removing said settable or curable liquid from said three-dimensional structure such that the surface of the solid material originally making up said three-dimensional structure and defining said flowpath or channel therein is coated with said settable or curable liquid, curing or setting said curable or settable liquid on said surface and removing from said structure the resulting coated solid material originally making up said structure thereby creating a second interpenetrating, three-dimensional, multiple-connected channel or flowpath within said structure, said second channel or flowpath being defined by the resulting cured or set curable or settable liquid coating the surface of the solid material originally making up said structure.

2. A method in accordance with claim 1 wherein said resulting coated solid material originally making up said structure is removed by chemical etching.

3. A method in accordance with claim 1 wherein said resulting coated solid material originally making up said structure is removed by dissolution in a solvent for said solid material.

4. A method of producing a structure in accordance with claim 1 wherein subsequent to removing from said structure the resulting coated solid material originally making up said structure the resulting structure is filled or impregnated with another settable or curable liquid, said other settable or curable liquid being removed from the resulting treated structure so that said first mentioned cured or set curable or settable liquid is coated with a coating of said other settable or curable liquid and removing from said structure the resulting coated first mentioned set or cured liquid, thereby creating a third interpenetrating, three-dimensional, multiple-connected channel or flowpath within said structure, said third channel or flowpath being defined by the resulting cured or set other curable or settable liquid coating the surface of the aforesaid cured or set liquid.

5. A method of producing an integral, three-dimensional structure providing a plurality of separate, interpenetrating, three-dimensional domains or channels, each of said domains or channels being a closed system of connected porosity or permeability with multiple interconnections only with respect to its respective domain or channel, each of said domains or channels being interpenetrating within said structure, which comprises filling or impregnating with a settable or curable liquid a porous, permeable, three-dimensional structure characterized by having a single interpenetrating, three-dimensional, multiple-connected channel or flowpath therein defined by the solid material making up said three-dimensional structure such that said flowpath or channel is occupied by said settable or curable liquid, removing said settable or curable liquid from said three-dimensional structure such that the surface of the solid material originally making up said three-dimensional structure and defining said flowpath or channel therein is coated with said settable or curable liquid, curing or setting said curable or settable liquid on said surface, skin coating and skin impregnating the outside surfaces of said three-dimensional structure with a curable or settable liquid, setting or curing said settable or curable liquid thereon, removing from opposite or opposed surfaces of said skin coated or skin impregnated three-dimensional structure a portion of said set for cured liquid to expose the solid material originally making up said three-dimensional structure and skin etching the resulting exposed solid material originally making up said three-dimensional structure to remove the same, coating and filling the resulting exposed and etched spaces with a settable or curable liquid and setting or curing the same, removing the outside surface portions of the resulting filled spaces from said opposite or opposed surfaces or sides or said resulting treated three-dimensional structure such that said structure presents at said opposite or opposed surfaces or sides said spaces filled with said cured or set liquid, removing the coating of cured or set liquid from the other sides or remaining surfaces of the resulting treated three-dimensional structure to expose the solid material originally making up said three-dimensional structure and removing, such as by etching or dissolution, said solid material from said three-dimensional structure, thereby establishing a first flowpath in the resulting structure originally defined by the solid material making up said three-dimensional structure and a second flowpath defined by the void space originally present in said three-dimensional structure, said first flowpath capable of having a direction of flow across said three-dimensional structure from one side to the other side and transversely with respect to said second flowpath and said second flowpath capable of having a directional flow transversely with respect to said first flowpath in the direction from one end to the other end of said resulting structure.

6. A method of producing an integral, three-dimensional structure providing a plurality of separate, interpenetrating, three-dimensional domains or channels, each of said domains or channels being a closed system of connected porosity or permeability with multiple interconnections only with respect to its respectively domain or channel, each of said domains or channels being interpenetrating within said structure, which comprises depositing a first solid coating on the solid material of a porous, permeable, three-dimensional structure having a single first interpenetrating, three-dimensional, multiple-connected channel or flowpath defining said three-dimensional, multiple-connected channel or flowpath such that there is formed on the surface of said solid material defining said first channel or flowpath therein a continuous first solid coating thereon and removing from said structure the coated solid material originally making up said structure and defining said single first channel or flowpath, thereby creating a second interpenetrating, three-dimensional, multiple-connected channel or flowpath within said structure, said first and second channel or flowpath being defined by the first solid coating deposited on the surface of the solid material originally defining said single first channel or flowpath.

7. A method in accordance with claim 6 wherein said first solid coating is deposited from a liquid phase.

8. A method in accordance with claim 6 wherein said first solid coating is deposited by vapor phase deposition.

9. A method in accordance with claim 8 wherein said first solid coating is deposited from a fluid which deposits said first solid coating onto said solid material upon contact of said fluid with said solid material defining said single first channel or flowpath.

10. A method in accordance with claim 6 wherein a second continuous solid coating is deposited on said first solid coating defining said first and second channel or flow-path and removing said first solid coating, thereby creating a third interpenetrating, three-dimensional, multiple-connected channel or flowpath within said structure, said first, said second and said third channel or flowpath being defined by the second solid coating deposited on the surface of said first solid coating previously defining said first and second channel or flowpath.

11. A method in accordance with claim 10 wherein said second solid coating is deposited from a liquid phase.

12. A method in accordance with claim 10 wherein said second solid coating is deposited by vapor phase deposition.

13. A method in accordance with claim 10 wherein said second solid coating is deposited from a fluid which deposits said second continuous solid coating onto said first coating upon contact of said fluid with said first coating defining said first and said second channel or flow-path.