Coextruded multilayer film

• US 4,233,367 A
• Filed: 01/06/1977
• Issued: 11/11/1980
• Est. Priority Date: 01/06/1977
• Status: Expired due to Term

• Current Assignee: American National Can Company (Ball Corporation)
• Original Assignee: American Can Co (Citigroup Incorporated)
• Inventors: Ticknor, William G., Rein, Arnold R.
• Primary Examiner(s): Thurlow, Jeffery R.
• Application Number:
  US05/757,140
• Time in Patent Office: 1,405 Days
• Field of Search: 264/95, 264/173, 264/171, 264/563, 264/514, 428/474, 428/500, 428/521, 428/476.3, 428/476.9, 428/515, 156/244, 156/244.12, 156/244.13, 156/244.14
• US Class Current: 428/476.3
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 48/09 Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
• CPC Class Codes: B29C 48/10 flexible, e.g. blown foils
• CPC Class Codes: B29C 48/21 the layers being joined at their surfaces
• CPC Class Codes: B29C 48/307 specially adapted for bringing together components, e.g. melts within the die
• CPC Class Codes: B29C 48/335 Multiple annular extrusion nozzles in coaxial arrangement, e.g. for making multi-layered tubular articles
• CPC Class Codes: B32B 2309/022 Temperature vs pressure profiles
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 7/10 at least one layer having inter-reactive properties
• CPC Class Codes: Y10T 428/3175 Next to addition polymer from unsaturated monomer[s]
• CPC Class Codes: Y10T 428/31757 Polymer of monoethylenically unsaturated hydrocarbon
• CPC Class Codes: Y10T 428/31909 Next to second addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31931 Polyene monomer-containing

Abstract

A multilayer film is prepared by coextruding nylon with a chemically modified polyolefin which has functional groups added to the basic polymer to provide strong adhesion to the nylon after coextrusion. The multiple layer film combines the strength and protection properties of the nylon with desired properties in the modified polyolefin. Multiple layer films may be produced by coextruding nylon layers with multiple layers of the modified polyolefin, and with additional layers of nonmodified polyolefins and other polymers. Suitable commercially available modified polyolefins for use in the multilayer film include Plexar-1 and Plexar-3 described in U.S. patent application Ser. No. 616,035, and Plexar-2 described in U.S. patent application Ser. No. 616,374, both filed in September, 1975, now abandoned, and respective continuation-in-parts thereof Ser. No. 808,080, now U.S. Pat. No. 4,087,588, and Ser. No. 808,079, now U.S. Pat. No. 4,087,587.

Claims

1. A process for producing a multilayer film, comprising:

coextruding nylon and a chemically modified polyolefin selected from the group consisting of ethylene vinyl acetate polymer, high density polyethylene and rubber modified high density polyethylene, each chemically modified by the provision of functional groups to the polymer which have a strong affinity for nylon and which will form a strong bond to nylon under heat and pressure of coextrusion.

2. The process of claim 1 wherein said modified polyolefin is a Plexar polymer.

3. The process of claim 1 wherein the nylon is coextruded between two layers of the modified polyolefin.

4. The process of claim 1 wherein a polyolefin is coextruded with said nylon and said chemically modified polyolefin.

5. A multilayer film comprising:

a coextrusion of nylon and a chemically modified polyolefin selected from the group consisting of ethylene vinyl acetate polymer, high density polyethylene, and rubber modified high density polyethylene, each chemically modified by the provision of functional groups to the polymer which have a strong affinity for nylon and which will form strong bonds to nylon under the heat and pressure of coextrusion.

6. The multilayer film of claim 5 wherein said coextrusion includes a layer of nylon between two layers of chemically modified polyolefin having strong adhesion to nylon after coextrusion.

7. The multilayer film of claim 5 wherein said modified polyolefin is a Plexar polymer.

8. A process for producing a multi-layer film, comprising:

tubular blown film coextruding nylon and a chemically modified polyolefin selected from the group consisting of ethylene vinyl acetate polymer, high density polyethylene and rubber modified high density polyethylene, each chemically modified by the provision of functional groups to the polymer which have a strong affinity for nylon and which will form a strong bond to nylon under heat and pressure of coextrusion.

9. A process for producing a multi-layer film, comprising:

coextruding nylon, a chemically modified polyolefin, and a polymer, said chemically modified polyolefin being selected from the group consisting of ethylene vinyl acetate polymer, high density polyethylene and rubber modified high density polyethylene, each chemically modified by the provision of functional groups to the polymer which have a strong affinity for nylon and which will form a strong bond to nylon under heat and pressure of coextrusion, said polymer being selected from the group consisting of low, medium, and high density polyethylene, ionomers, ethylene vinyl acetate polymer, and ethylene acrylic acid polymer.

10. A multi-layer film comprising:

a coextrusion of nylon, a chemically modified polyolefin, and a polymer layer bonded to said modified polyolefin, said modified polyolefin selected from the group consisting of ethylene vinyl acetate polymer, high density polyethylene, and rubber modified high density polyethylene, each chemically modified by the provision of functional groups to the polymer which have a strong affinity for nylon and which will form strong bonds to nylon under the heat and pressure of coextrusion, said polymer layer being selected from the group consisting of high, medium and low density polyethylene, ionomers, ethylene vinyl acetate polymer, ethylene acrylic acid polymer, and rubber modified polyethylene.

11. A multi-layer film comprising:

a coextrusion of nylon between two layers of a chemically modified polyolefin and a layer of polymer bonded to each of said layers of said modified polyolefin, said modified polyolefin being selected from the group consisting of ethylene vinyl acetate polymer, high density polyethylene, and rubber modified high density polyethylene, each chemically modified by the provision of functional groups to the polymer which have a strong affinity for nylon and which will form strong bonds to nylon under the heat and pressure of coextrusion, and said polymer being selected from the group consisting of high, medium, and low density polyethylene, ionomers, ethylene vinyl acetate polymer, ethylene acrylic acid polymer, and rubber modified polyethylene.