Method for the manufacture of an electrochemical cell or battery and battery made by the method

• US 4,233,371 A
• Filed: 09/10/1979
• Issued: 11/11/1980
• Est. Priority Date: 09/13/1978
• Status: Expired due to Term

• Current Assignee: Electrochemische Energieconversie NV
• Original Assignee: Electrochemische Energieconversie NV
• Inventors: Dorrestijn, Antoon
• Primary Examiner(s): LeFevour, Charles F.
• Application Number:
  US06/074,099
• Time in Patent Office: 428 Days
• Field of Search: 429/149-155, 429/162, 29/623.1, 29/623.5
• US Class Current: 429/152
• CPC Class Codes: B01D 61/50 Stacks of the plate-and-frame type
• CPC Class Codes: B01D 63/081 Manufacturing thereof
• CPC Class Codes: C25B 9/00 Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
• CPC Class Codes: H01M 10/0413 Large-sized flat cells or batteries for motive or stationary systems with plate-like electrodes
• CPC Class Codes: H01M 8/2404 Processes or apparatus for grouping fuel cells
• CPC Class Codes: H01M 8/2418 Grouping by arranging unit cells in a plane H01M8/2425, H01M8/244 take precedence
• CPC Class Codes: H01M 8/242 comprising framed electrodes or intermediary frame-like gaskets H01M8/2425, H01M8/244 take precedence
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y10T 29/4911 including sealing
• CPC Class Codes: Y10T 29/49114 including adhesively bonding

Abstract

The invention relates to a method for the manufacture of an electrochemical cell or battery, consisting of a stack of plate-shaped elements, each of which consists of a sheet or plate of electrode material which is mounted in a frame made of electrically insulating fibrous-web material impregnated with a non-polymerized thermosetting synthetic material, which elements in a first compression molding stage are heated under pressure for a relatively short primary time at a relatively low primary temperature under which conditions the thermosetting synthetic material flows well but polymerizes only to a minor degree, thereafter the elements are combined with other battery components are stacked into an electrochemical cell package which in a second compression molding stage is formed into a coherent block by compression for a relatively long secondary time and at a relatively high secondary temperature to set the thermosetting synthetic material.

Claims

1. A method for the manufacture of an electrochemical cell or battery, consisting of a stack of plate-shaped elements, including at least two electrode elements, each of which consists of a sheet or plate of electrode material which is mounted in a frame made of an electrically insulating fibrous-web material impregnated with a thermosetting synthetic material, which elements, prior to setting, are stacked to form a package of the desired composition in such a way that gas or liquid chambers are formed between the elements, after which the stack is subjected to a compression molding operation at a temperature causing the thermosetting synthetic material to polymerize, thus forming the stack into a coherent block, wherein the improvement comprises the steps of employing a first compression molding operation stage wherein the individual plate-shaped elements are manufactured by placing a sheet of electrode material in a press mold between frame sections made of electrically insulating fibrous web impregnated with a non-polymerized thermosetting synthetic material and heating the assembly under pressure for a relatively short primary time at a relatively low primary temperature, at which temperature the thermosetting synthetic material flows well, but polymerizes only to a minor degree at most, after which the resulting plate-shaped elements, together with any other cell or battery components, are stacked into a package of the desired composition, which package in a second compression molding operation stage is formed into a coherent block by compressing it for a relatively long secondary time and at a relatively high secondary temperature, at which the thermosetting synthetic material sets.

2. The method according to claim 1, wherein said relatively short primary time is in the range of about 5 to 60 seconds.

3. The method according to claim 1 or 2 wherein said relatively low primary temperature is in a range of about 70°

to 90°

C.

4. The method according to claim 1 or 2 wherein said relatively long secondary time is in the range of about 10 to 60 minutes.

5. The method according to claims 1 or 2 wherein said relatively low primary temperature is in the range of about 70°

to 90°

C. and said relatively long secondary time is in the range of about 10 to 60 minutes.

6. The method according to one of the claims 1 or 2 wherein said relatively high secondary temperature is in the range of about 110°

to 180°

C.

7. The method according to claim 1 or 2 wherein said relatively low primary temperature is in the range of about 70°

to 90°

C., said relatively long secondary time is in the range of about 10 to 60 minutes and said relatively high secondary temperature is in the range of about 110°

to 180°

C.

8. The method according to one of the claims 1 or 2 wherein said press mold for the primary compression molding operation includes the further step of employing insert pieces, the dimensions and position of which correspond to the strips to be placed in the stacked package for the formation of channels.

9. The method according to one of the claims 1 or 2 wherein said press mold for the primary compression molding operation includes the further steps of employing pins, the dimensions and place of which correspond with those of the desired continuous channels through the elements in the finished block.

10. The method according to claim 9 wherein the stacked package has been provided with pins, the dimensions and place of which correspond with those of the desired continuous channels through the finished block.

11. The method according to one of the claims 1 or 2 wherein the thermosetting synthetic material is an epoxy resin.

12. An electrochemical cell or battery constructed in accordance with claim 1 or 2.