Fabric conditioning compositions

• US 4,234,627 A
• Filed: 02/04/1977
• Issued: 11/18/1980
• Est. Priority Date: 02/04/1977
• Status: Expired due to Term

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Schilling, Kenneth J.
• Primary Examiner(s): Lawrence, Evan K.
• Application Number:
  US05/765,510
• Time in Patent Office: 1,383 Days
• Field of Search: 427/242, 252/316, 252/8.8 AJ, 252/8.8 AO, 252/8.8 AM, 252/8.9, 252/8.7, 252/8.75, 252/135, 252/174.11, 252/174.13
• US Class Current: 8/137
• CPC Class Codes: C11D 1/146 Sulfuric acid esters
• CPC Class Codes: C11D 1/22 derived from aromatic compounds
• CPC Class Codes: C11D 1/29 Sulfates of polyoxyalkylene ethers
• CPC Class Codes: C11D 17/0039 Coated compositions or coated components in the compositions, (micro)capsules
• CPC Class Codes: C11D 3/0015 liquid
• CPC Class Codes: D06M 23/12 Processes in which the treating agent is incorporated in microcapsules making microcapsules B01J13/02

Abstract

Fabric conditioning compositions suitable for effectively imparting fabric conditioning agents to fabrics during the home laundering operation via friable microcapsules containing such agents. A method for delivery of the agents is also provided.

Claims

1. A granular laundry presoaking/washing composition comprising:

(A) from about 3% to 20% by weight of a granular fabric treatment mixture, the granules within said mixture comprising

(i) water-insoluble, friable microcapsules varying in size from about 5 to 500 microns, each microcapsule consisting essentially of

(a) a liquid core containing fabric conditioning agent; and

(b) a solid thin polymeric shell completely surrounding said core;

said shell having an average thickness ranging between about 0.1 and 50 microns; and

(ii) a substantially water-insoluble, fabric substantive capsule transfer agent having a melting point between about 40°

C. and 150°

C.;

said capsule transfer agent surrounding each microcapsule;

the weight ratio of microcapsules to capsule transfer agent within each granule of the fabric treatment mixture between about 0.002;

1 and 2000;

1; and

(B) from about 5% to 90% by weight of a presoaking/washing adjuvant selected from the group consisting of water-soluble detersive surfactants, detergency builders and mixtures of water-soluble detersive surfactants and detergency builders.

2. A composition in accordance with claim 1 wherein

(A) the microcapsule shell wall material is selected from the group consisting of polyurethanes, polyolefins, polyamides, polyesters, polysaccharides, silicone resins, epoxy resins and aminoplast polymers derived from urea and aldehydes;

(B) the fabric conditioning agent is a perfume; and

(C) the capsule transfer agent is selected from the group consisting of cationic and nonionic organic materials and mixtures thereof.

3. A composition in accordance with claim 2 wherein the presoaking/washing adjuvant comprises from about 5% to 25% by weight of the composition of a water-soluble detersive surfactant and from about 30% to 50% by weight of the composition of a detergency builder.

4. A composition in accordance with claim 2 wherein the presoaking/washing adjuvant comprises

(A) from about 0% to 7% by weight of the composition of a detersive surfactant selected from the group consisting of linear alkyl benzene sulfonates having from 11 to 14 carbon atoms in the alkyl group, alkylsulfates having from 12 to 20 carbon atoms in the alkyl group, alkyl glyceryl sulfonates having from 8 to 18 carbon atoms in the alkyl group, alkyl ether sulfates having from 14 to 18 carbon atoms in the alkyl group and an average degree of ethoxylation between 1 and 6, the water-soluble ethoxylates of aliphatic alcohols containing from 10 to 20 carbon atoms and mixtures of these surfactants;

and

(B) from about 30% to 90% by weight of a detergency builder selected from the group consisting of water-soluble phosphates, pyrophosphates, orthophosphates, polyphosphates, carbonates, bicarbonates, borates, silicates, polyacetates, carboxylates, polycarboxylates and succinates.

5. A composition in accordance with claim 4 wherein the capsule transfer agent is a nonionic fabric softening agent selected from the group consisting of the C₁₄ to C₁₈ alkyl sorbitan tri- and tetra-esters.

6. A composition in accordance with claim 4 wherein the capsule transfer agent is a water-insoluble mixture of nonionic and cationic fabric softeners, said mixtures being selected from the group consisting of

(a) mixtures of C₁₀ to C₂₂ alkyl sorbitan tri- and tetra-esters with C₁₂ to C₂₂ dialkyl, dimethylammonium salts in a sorbitan ester/quaternary salt weight ratio of from about 1:

4 to 4;

1, and

(b) mixtures of C₁₀ to C₂₂ alkyl sorbitan tri- and tetra-esters and C₁₄ to C₂₀ fatty alcohols with C₁₂ to C₂₀ dialkyl, dimethyl ammonium salts in a total nonionic/quaternary salt weight ratio of from about 1;

4 to 4;

1.

7. A composition in accordance with claim 4 wherein the capsule transfer agent is selected from the group consisting of 2:

1 mixtures of sorbitan tristearate with ditallowdimethylammonium methylsulfate and 1;

1;

1 mixtures of sorbitan tristearate, tallow alcohol and ditallowdimethylammonium methylsulfate.

8. A composition in accordance with claim 2 wherein

(A) the microcapsule shell wall material is a urea-formaldehyde polymer having an average shell wall thickness of from about 0.4 to 4.0 microns;

(B) the microcapsules vary in size between 10 and 100 microns; and

(C) the weight ratio of microcapsules to capsules transfer agent varies between 0.008;

1 and 3;

1.

9. A composition in accordance with claim 2 which additionally contains a detergent adjuvant selected from the group consisting of a peroxygen bleaching agent present to the extent of from about 1% to 45% by weight a detergency enzyme component present to the extent of from about 0.1% to 1% by weight and mixtures of said bleaching agent and enzyme components.

10. A process for conditioning fabrics comprising the steps of:

(A) contacting said fabrics in an aqueous bath with an effective amount of a composition comprising;

1. from about 3% to 20% by weight of a granular fabric treatment mixture, the granules within said mixture comprising

(i) water-insoluble;

friable microcapsules varying in size from about 5 to 500 microns, each microcapsule consisting essentially of

(a) a liquid core containing fabric conditioning agent; and

(b) a solid thin polymeric shell completely surrounding said core;

said shell having an average thickness ranging between about 0.1 and 50 microns; and

(ii) a substantially water-insoluble, fabric substantive capsule transfer agent having a melting point between about 40°

C. and 150°

C.;

said capsule transfer agent surrounding each microcapsule;

the weight ratio of microcapsules to capsule transfer agent within each granule of the fabric treatment mixture ranging between about 0.002;

1 and 2000;

1; and

12. A process according to claim 10 wherein the fabric conditioning agent is a perfume.

11. from about 5% to 90% by weight of a presoaking/washing adjuvant selected from the group consisting of water-soluble detersive surfactants, detergency builders and mixtures of water-soluble detersive surfactants and detergency builders;

and

(B) manipulating said fabrics in an automatic clothes dryer at a temperature of from about 38°

C. to about 100°

C.

13. A process according to claim 11 wherein the capsule transfer agent is a nonionic fabric softening agent selected from the group consisting of the C₁₄ to C₁₈ alkyl sorbitan tri- and tetra-esters.

14. A process according to claim 11 wherein the presoaking/washing adjuvant comprises:

(A) from about 0% to 7% by weight of the composition of a detersive surfactant selected from the group consisting of linear alkyl benzene sulfonates having from 11 to 14 carbon atoms in the alkyl group, alkylsulfates having from 12 to 20 carbon atoms in the alkyl group, alkyl glyceryl sulfonates having from 8 to 18 carbon atoms in the alkyl group, alkyl ether sulfates having from 14 to 18 carbon atoms in the alkyl group and an average degree of ethoxylation between 1 and 6, the water-soluble ethoxylates of aliphatic alcohols containing from 10 to 20 carbon atoms and mixtures of these surfactants; and

(B) from about 30% to 90% by weight of a detergency builder selected from the group consisting of water-soluble phosphates, pyrophosphates, orthophosphates, polyphosphates, carbonates, bicarbonates, borates, silicates, polyacetates, carboxylates, polycarboxylates and succinates.