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Polycrystalline diamond body/silicon nitride substrate composite

  • US 4,234,661 A
  • Filed: 03/12/1979
  • Issued: 11/18/1980
  • Est. Priority Date: 03/12/1979
  • Status: Expired due to Term
First Claim
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1. A composite consisting essentially of a polycrystalline diamond body integrally bonded to a substrate of polycrystalline silicon nitride, said polycrystalline diamond body consisting essentially of a mass of diamond crystals adherently bonded together by a bonding medium consisting essentially of silicon carbide and a carbide and/or silicide of a metal component which forms a silicide with silicon and which forms a eutectiferous alloy with silicon, said metal component of said metal silicide being selected from the group consisting of cobalt, chromium, iron, hafnium, manganese, molybdenum, niobium, nickel, palladium, platinum, rhenium, rhodium, ruthenium, tantalum, thorium, titanium, uranium, vanadium, tungsten, yttrium, zirconium and alloys thereof, said metal component of said metal carbide being selected from the group consisting of chromium, hafnium, titanium, zirconium, tantalum, vanadium, tungsten, molybdenum, and alloys thereof, said diamond crystals ranging in size from about 1 micron to about 1000 microns, the volume of said diamond crystals ranging from at least about 70% by volume up to about but less than 90% by volume of said body, said bonding medium being present in an amount ranging up to about 30% by volume of said body, said bonding medium being distributed substantially uniformly throughout said body, the portion of said bonding medium in contact with the surfaces of said diamond crystals being at least in a major amount silicon carbide, said diamond body being substantially pore-free, said substrate consisting essentially of a hot-pressed or sintered polycrystalline silicon nitride body ranging in density from about 80% to about 100% of the theoretical density of silicon nitride and containing silicon nitride in an amount of at least 90% by weight of said substrate and being free of constituents which have a significantly deleterious effect on the mechanical properties of said composite, said polycrystalline diamond body forming an interface with said silicon nitride substrate wherein said bonding medium extends from said polycrystalline diamond body into contact with said silicon nitride substrate at least substantially filling pores throughout said interface so that said interface is substantially pore-free, the distribution and thickness of the bonding medium throughout said interface being substantially the same as the distribution and thickness of the bonding medium throughout said polycrystalline diamond body of said composite.

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