Detection of uranium by light induced luminescence

• US 4,236,071 A
• Filed: 05/21/1979
• Issued: 11/25/1980
• Est. Priority Date: 05/21/1979
• Status: Expired due to Term

• Current Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Original Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Inventors: Chimenti, Robert J. L.
• Primary Examiner(s): Willis, Davis L.
• Application Number:
  US06/040,900
• Time in Patent Office: 554 Days
• Field of Search: 250/253, 250/302, 250/372, 250/461 R
• US Class Current: 250/253
• CPC Class Codes: G01N 21/64 Fluorescence; Phosphorescence
• CPC Class Codes: G01N 21/6408 with measurement of decay time, time resolved fluorescence
• CPC Class Codes: G01V 8/02 Prospecting

Abstract

A method for the detection and identification of uranium bearing materials in media found in nature such as rocks, soils, surface and sub-surface waters, vegetation, or in material which has been subjected to physical or chemical processing comprises the steps of: irradiating the media with a light, having a single wavelength or narrow band of wavelengths in the range of about 2400 to 5000A for a time equal to or less than about 100 microseconds; waiting for a period of time, which is dependent on twice the distance of the light-source to the irradiated medium, followed by measurement of the intensity and decay time of the luminescent light emitted by the irradiated media in a narrow spectral range, having a wavelength greater than the wavelength of the light used to irradiate the media. The method is useful for remote geochemical prospecting for uranium using laser induced luminescence and in monitoring products and effluents from installations processing or utilizing uranium compounds, such as in elemental or isotopic separation, purification, recovery and ore beneficiation.

Claims

1. Method for detecting the presence of uranium in a substance present in a target area in which the uranium is present in said substance as a hexavalent uranyl ion which comprises:

(a) irradiating said target area with light from a light source, said light having a wavelength in the range of about 2400 to 5000 A for a period of time equal to or less than about 100 microseconds to induce luminescence in said substance;

(b) waiting for a period of time equal to twice the propagation time for the light to travel from said light source to said target, plus about 50 microseconds; and

(c) measuring the intensity, decay time and spectral distribution of said luminescence.

2. Method according to claim 1 wherein said light is a laser beam having a wavelength in the range of 3700 to 4500 A and said light source is a laser generator.

3. Method according to claim 1 wherein said light is a laser beam having a wavelength in the range of about 2800 to 3500 A and said light source is a laser generator.

4. Method according to claim 1 wherein said measurement of the luminescence intensity, decay time and spectral distribution is over a period of about 50 to 1000 microseconds.

5. Method according to claim 1 wherein the initial intensity of said luminescence is in the ratio of at least about 25 to 1 over the background radiation noise and other sources of noise.

6. Method according to claim 1 wherein said decay time is equal to the time for the intensity to decrease to e^-1 of the initial intensity of said luminescence.

7. Method according to claim 1 wherein said measurement of the spectral distribution of said luminescence is in the range of about 5000 A to 6000 A.

8. Method according to claim 1 wherein said substance is a mineral selected from the group consisting of autunite, zippeite and saleeite.

9. Method according to claim 1 wherein said target area is part of the terrain and said light source is located remote from said terrain.

10. Method for detecting the presence of surface deposits of uranium minerals comprising hexavalent uranyl ions in a target area remote from an observation point comprises:

(a) irradiating said target area with a beam of light having a wavelength in a range from 2800 to 3500 A as 3700 to 4500 A emitted by a laser positioned at said observation point for a period of time equal to or less than about 100 microseconds;

(b) waiting for a period of time equal to twice the time required for the propagation of said light from said laser to said target area, plus about 50 microseconds; and

(c) measuring the intensity and the decay time at a wavelength of 5250 A, by means of an optical receiver, for a period of up to 1000 microseconds the luminescence induced in said mineral by said irradiation.

11. An apparatus for the remote detection of uranium minerals which emit luminescence when irradiated with light having a wavelength in the range of about 2400 to 5000 A, said minerals being located at a target area at ground level, which comprises:

(a) a transmitter comprised of a laser excitation source emitting light in the range of about 2400 to 5000 A in combination with an optical system to transmit the laser radiation to the target area;

(b) a receiver, comprised of an optical system to collect a portion of the emitted luminescence;

(c) means for limiting the spectral band width of the collected luminescence and converting the luminescence to an electric signal by means of a gated photomultiplier;

(d) a data handling system to provide means to record the distance of the light source to the target area;

background light and noise and means for automatically maintaining the detector focused on the target for about 1000 microseconds after termination or irradiation; and

(e) means for recording the intensity, decay time and spectral distribution of the luminescence and converting these data to uranium concentration.

12. The apparatus of claim 11 in which said wavelength is in the range of about 3700 to 4500 A.

13. The apparatus of claim 11 in which said wavelength is in the range of about 2800 to 3500 A.

14. The apparatus of claim 11 in which the laser excitation source emits continuous wave radiation.

15. The apparatus of claim 14 in which the continuous wave radiation is pulsed or chopped.

16. The apparatus of claim 14 in which the continuous wave radiation is modulated.