Method of making a nitrogen dioxide sensing element

• US 4,236,307 A
• Filed: 11/02/1978
• Issued: 12/02/1980
• Est. Priority Date: 11/02/1978
• Status: Expired due to Term

• Current Assignee: Johnson Controls Technology Company (Johnson Controls International plc)
• Original Assignee: Johnson Controls, Inc. (Johnson Controls International plc)
• Inventors: Thoma, Paul E., Colla, Jeannine O.
• Primary Examiner(s): Husar, Francis S.
• Assistant Examiner(s): Arbes, C. J.
• Application Number:
  US05/956,884
• Time in Patent Office: 761 Days
• Field of Search: 29/628, 252/500, 338/34, 338/35, 324/715 N, 324/65 R, 23/232 R, 204/195 G, 204/195 R, 204/195 S, 204/195 P, 340/521, 55/68, 55/387, 55/528, 131/262 R, 131/269, 264/29.1, 264/29.7
• US Class Current: 29/857
• CPC Class Codes: G01N 27/12 of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid , for detecting components in the fluid
• CPC Class Codes: G01N 33/0037 NOx
• CPC Class Codes: H01C 17/20 by pyrolytic processes
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y10T 29/49174 Assembling terminal to elongated conductor
• CPC Class Codes: Y10T 436/178459 Only nitrogen dioxide

Abstract

A method of making an element for sensing the presence of nitrogen dioxide gas in the environment. The element is formed by heating a film of an electrically non-conductive polyaromatic polymer to a temperature sufficiently high to pyrolyze the polymer and render the polymer semi-conductive. The pyrolyzed film is mounted on an electrically non-conductive base. Electrical leads are attached at spaced locations to the film and are connected in an electrical circuit with a signalling or control mechanism. The presence of nitrogen dioxide gas will cause a change in the electrical characteristics of the film to thereby activate the mechanism. A heating element can be associated with the base to insure constant temperature and humidity conditions.

Claims

1. A method of making an element capable of sensing the presence of nitrogen dioxide in the environment, comprising the steps of heating a film of an electrically non-conductive polyaromatic polymer to a temperature in the range of 540°

C. to 750°

C. in a non-oxidizng atmosphere to pyrolyze the polymer and render said polymer semi-conductive, and attaching electrical leads at spaced locations to said pyrolyzed film.

2. The method of claim 1, and including the step of selecting said polymer from the group consisting of polyamides, polyamideimides, polyimides and polybenzimidazoles.

3. The method of claim 1, and including the step of bonding the pyrolyzed film to a surface of an electrically non-conductive base.

4. The method of claim 1, and including the step of placing the film between sheets of porous graphite prior to the step of heating.

5. The method of claim 1, and including the step of depositing layers of a non-corroding metal at spaced locations on said film, and attaching said electrical leads to said layers.

6. The method of claim 5, wherein the step of depositing layers of a non-corroding metal comprises depositing said metal by electroless chemical plating.

7. The method of claim 1, wherein the step of heating comprises heating the film in a vacuum environment of less than 1×

10^-2 torr.

8. The method of claim 1, and including the step of selecting a polymer that contains nitrogen as a part of the polymer structure.

9. The method of claim 3, wherein said bonding comprises the step of utilizing an epoxy resin to bond the film to said surface.

10. The method of claim 5, wherein the step of depositing layers comprising depositing said layers by vapor deposition.

11. The method of claim 5, wherein said step of attaching electrical leads comprises attaching with a solder.

12. The method of claim 5, wherein said step of attaching electrical leads comprises attaching with an electrically conductive epoxy resin.

13. The method of claim 3, and including the step of applying a heating means to the opposite surface of said base.

14. The method of claim 13, including the step of providing an electrical heating element as said heating means.

15. A method of making an element capable of sensing the presence of nitrogen dioxide in the environment, comprising the steps of heating a film of an electrically non-conductive polyaromatic polymer to a temperature in the range of 540°

C. to 750°

C. in a non-oxidizing atmosphere to pyrolyze the polymer and render said polymer semi-conductive, said polymer being selected from the group consisting of polyamides, polyamideimides, polyimides and polybenzimidazoles, bonding the pyrolyzed film to an electrically non-conductive base and attaching electrical leads at spaced locations to said pyrolyzed film.