Method for removing organic acid soil from surfaces

• US 4,236,935 A
• Filed: 09/28/1979
• Issued: 12/02/1980
• Est. Priority Date: 09/28/1979
• Status: Expired due to Term

• Current Assignee: Reckitt & Colman Subsidiary Corporation
• Original Assignee: Church & Dwight Company Incorporated
• Inventors: Petersen, Arthur W., Schoenholz, Daniel, Northup, Marcus A. Jr.
• Primary Examiner(s): Caroff, Marc L.
• Application Number:
  US06/080,053
• Time in Patent Office: 431 Days
• Field of Search: 134/2, 134/40, 134/19, 134/22 R, 252/90, 252/156, 252/158, 252/174.14
• US Class Current: 134/2
• CPC Class Codes: C11D 3/0057 Oven-cleaning compositions
• CPC Class Codes: C11D 3/10 Carbonates ; Bicarbonates
• CPC Class Codes: C11D 3/2041 Dihydric alcohols
• CPC Class Codes: C11D 3/2065 Polyhydric alcohols
• CPC Class Codes: C11D 3/2075 Carboxylic acids-salts thereof
• CPC Class Codes: C11D 3/2093 Esters; Carbonates
• CPC Class Codes: C11D 3/221 Mono, di- or trisaccharides or derivatives thereof
• CPC Class Codes: C11D 3/43 Solvents

Abstract

Soils containing free or combined organic acids are removed from surfaces, such as oven surfaces, by contacting the soil at a temperature of 250°-550° F. with a weakly alkaline composition comprising (A) at least one polyhydric alchol or a lower aliphatic ether or ester thereof having at least 2 free hydroxy groups, (B) 1.0 to 500% by weight of at least one alkali metal bicarbonate based on the weight of the polyhydric alcohol and (C) 5.0 to 1000% by weight of at least one alkali metal salt of a weak organic acid based on the weight of the polyhydric alcohol, and then removing soil residue.

Claims

1. A method for the removal of soil containing free or combined organic acids from surfaces comprising applying to soil containing free or combined organic acids an effective amount of a composition comprising (A) at least one polyhydric alcohol or a lower aliphatic ether or ester thereof having at least 2 free hydroxy groups, (B) 1.0 to 500% by weight of at least one alkali metal bicarbonate based on the weight of the polyhydric alcohol and (C) 5.0 to 1000% by weight of at least one alkali metal salt of a weak organic acid based on the weight of the polyhydric alcohol, heating the composition to a temperature of 250°

to 550°

F. and removing the soil residue.

2. The method of claim 1 wherein the alkali metal salt of the weak organic acid is a mixture of at least 2 alkali metal salts of acetic acid.

3. The method of claim 1 wherein the alkali metal salt(s) is an eutectic mixture of the sodium, potassium and lithium acetates.

4. The method of claim 2 wherein there is also present in the composition a member selected from the group consisting of an alkali metal glycolate and an alkali metal glycinate.

5. The method of claim 1 wherein the polyhydric alcohol is selected from the group consisting of ethylene glycol, diethylene glycol, triethylene glycol, glycerol, diglycerol, triglycerol, pentaerythritol, sorbitol, mannitol, inositol, trimethylol propane, trimethylol ethane, and partial esters of polyols having at least 2 free hydroxyl group and aliphatic carboxylic acids of 1 to 7 carbon atoms.

6. The method of claim 1 wherein the temperature is 300°

to 350°

F.

7. The method of claim 1 wherein the weak organic acid is at least one member selected from the group consisting of aliphatic and alicyclic carboxylic acids of one to 10 carbon atoms.

8. The method of claim 1 wherein the polyhydric alcohol is mannitol or sorbitol.