Hydrogen gas generation utilizing a bromide electrolyte, an amorphous silicon semiconductor and radiant energy

• US 4,236,984 A
• Filed: 11/21/1979
• Issued: 12/02/1980
• Est. Priority Date: 11/21/1979
• Status: Expired due to Term

• Current Assignee: United Technologies Corporation (Raytheon Technologies Corporation d/b/a RTX)
• Original Assignee: United Technologies Corporation (Raytheon Technologies Corporation d/b/a RTX)
• Inventors: Grantham, Daniel H.
• Primary Examiner(s): Weisstuch, Aaron
• Application Number:
  US06/096,596
• Time in Patent Office: 377 Days
• Field of Search: 204/128, 204/129, 204/DIG. 3, 429/111
• US Class Current: 205/340
• CPC Class Codes: C25B 1/55 Photoelectrolysis
• CPC Class Codes: Y02P 20/133 Renewable energy sources, e.g. sunlight
• CPC Class Codes: Y10S 204/03 Auxiliary internally generated electrical energy

Abstract

Radiant energy in conjunction with an n-type amorphous silicon semiconducting photoanode to at least partially power an electrolytic cell is used in the generation of hydrogen, utilizing a bromide, preferably hydrogen bromide, as the essential electrolyte component in the electrolytic cell to solve overvoltage and corrosion problems associated with the use of conventional electrolytes in similar environments. The use of the bromide electrolyte results in the broadening of the selection of semiconductor electrodes which can be used in the process and apparatus of the present invention enabling the amorphous silicon semiconducting electrode to be used with superior anticorrosive and radiant energy gathering results over conventional systems. To insure against corrosion, the amorphous silicon semiconductor should preferably be used with a thin layer of platinum overcoating. The hydrogen generated from such system can be used to power a fuel cell.

Claims

1. A process for producing hydrogen gas from an electrolyte solution in an electrolytic cell, wherein the improvement comprises utilizing a solution of a bromide compound as the electrolyte in conjunction with radiant energy and an n-type semiconducting amorphous silicon photo anode to at least partially power the electrolytic cell.

5. The process of claims 1, 2, 3 or 4 wherein the bromide electrolyte comprises a compound selected from the group consisting of HBr, NaBR, KRr, LiBr, CsBr, SrBr₂ and mixtures thereof.

6. The process of claim 5 wherein the bromide compound is present in an amount of up to about 50% by weight and the solvent is water.

7. The process of claims 1, 2, 3 or 4 wherein the radiant energy is solar energy.

8. The process of claims 1, 2, 3 or 4 wherein the radiant energy is laser radiation.

9. The process of claims 1, 2, 3 or 4 wherein the radiant energy is produced by a light emitting solid state diode.

10. The process of claims 1, 2, 3 or 4 wherein the radiant energy is light of wavelength up to about 7,250 A.

11. The process of claims 1, 2, 3 or 4 wherein the electrolyte is a 48% by weight solution of HBr in water.

12. The process of claims 1, 2, 3 or 4 wherein the amorphous silicon is on a supportive substrate and contains a layer of platinum less than 100 A thick on that side of the silicon opposite the substrate.

2. The process of producing hydrogen gas in an electrolytic cell comprising:

providing an electrolytic cell enclosure containing a bromide electrolyte solution;

immersing an n-type semiconducting amorphous silicon photo anode and a nonphoto active cathode into the bromide electrolyte solution;

separating said electrodes by a hydrogen ion permeable membrane also immersed in said bromide electrolyte solution;

exposing the semiconducting electrode to radiant energy of proper wavelength and sufficient intensity to cause the evolution of hydrogen gas at the cathode and bromine liquid at the anode.

3. A process of producing hydrogen gas in an electrolytic cell comprising:

providing an electrolytic cell enclosure containing a bromide electrolyte solution;

placing a platinum cathode and an n-type semiconducting amorphous silicon photo anode into the bromide electrolyte solution, wherein the semiconducting electrode also forms part of the wall of the electrolytic cell enclosure containing the platinum cathode and bromide solution;

irradiating the semiconducting photo anode from that side of the semiconducting photo anode which represents the wall portion of the cell containing the bromide solution with radiant energy of proper wavelength and sufficient intensity to evolve hydrogen gas at the platinum cathode and liquid bromine at the semiconducting photo anode.

4. The process of producing hydrogen gas in an electrolytic cell comprising providing an electrolytic cell enclosure containing a bromide electrolyte solution;

placing a platinum cathode and an n-type semiconducting amorphous silicon photo anode in a bromide electrolyte solution;

subjecting the semiconducting photo anode to a radiant energy source of proper wavelength and sufficient intensity to evolve hydrogen gas at the platinum cathode in the space between the two electrodes and liquid bromine at the semiconductor photo anode into the solution between the area defined by the electrodes.