Aqueous heat-storage compositions containing fumed silicon dioxide and having prolonged heat-storage efficiencies

• US 4,237,023 A
• Filed: 03/20/1979
• Issued: 12/02/1980
• Est. Priority Date: 03/20/1979
• Status: Expired due to Term

• Current Assignee: Cabot Corporation, Massachusetts Institute of Technology
• Original Assignee: Cabot Corporation, Massachusetts Institute of Technology
• Inventors: Giuffrida, John, Johnson, Timothy E.
• Primary Examiner(s): Pitlick, Harris A.
• Application Number:
  US06/022,232
• Time in Patent Office: 623 Days
• Field of Search: 252/70, 126/400
• US Class Current: 252/70
• CPC Class Codes: C09K 5/063 Materials absorbing or liberating heat during crystallisation; Heat storage materials
• CPC Class Codes: F24S 60/10 using latent heat
• CPC Class Codes: Y02E 10/40 Solar thermal energy, e.g. solar towers
• CPC Class Codes: Y10S 165/902 Heat storage

Abstract

Aqueous heat-storage compositions useful in space heating applications are disclosed which contain a phase-change material which absorbs and stores heat as it is heated above its phase-change temperature and releases stored heat as it is cooled below its phase-change temperature. These compositions include fumed silicon dioxide which acts as a stabilizing agent and provides dramatically prolonged heat-storage efficiency for these compositions as they undergo repetitive cycling through their phase-change temperature. Articles containing such compositions and methods of forming such compositions are additionally disclosed.

Claims

1. In an aqueous heat-storage composition containing a phase-change material which absorbs and stores heat as it is heated above its phase-change temperature and releases stored heat as it is cooled below its phase-change temperature and a stabilizing agent to prolong heat-storage efficiency as the composition is repeatedly cycled through its phase-change temperature:

the improvement wherein said stabilizing agent comprises fumed silicon dioxide uniformly dispersed throughout said composition in a stable dispersion thereof.

2. The improvement of claim 1 wherein said fumed silicon dioxide was pyrogenically prepared by hydrolysis of a silicon halide feedstock.

3. An aqueous composition adapted to reversibly store heat energy as its temperature is raised above a predetermined temperature and to release stored heat energy as it is cooled below said predetermined temperature, comprising a uniform and stable dispersion of:

an inorganic salt capable of forming a salt hydrate in said aqueous composition and having a theoretical heat-of-fusion at its phase temperature of at least about 80 BTU/lb.;

a quantity of water sufficient to supply the hydration requirements of said inorganic salt in its hydrated form; and

,

fumed silicon dioxide present in an effective amount to significantly prolong the heat-storage efficiency of said composition as it is repetitively thermally cycled through its phase-change temperature.

4. An aqueous composition of claim 3 wherein said fumed silicon dioxide was pyrogenically prepared by hydrolysis of a silicon halide feedstock.

5. An aqueous composition of claim 4 additionally including an inorganic recrystallization temperature depressing salt which forms a eutectic mixture with said inorganic salt, said eutectic mixture having a phase-change temperature corresponding to said predetermined temperature.

6. An aqueous composition of claim 5 additionally including a nucleating agent to promote recrystallization and inhibit supercooling of said inorganic salt as said composition is cooled below its phase-change temperature.

7. An aqueous composition of claim 6 wherein said inorganic salt comprises sodium sulfate.

8. An aqueous composition of claim 7 wherein said recrystallization temperature depressing salt comprises an alkali metal halide.

9. An aqueous composition of claim 8 wherein said nucleating agent comprises an alkali metal borate.

10. An aqueous composition of claim 9 wherein said alkali metal borate is sodium borate.

11. An aqueous composition of claim 10 wherein said alkali metal halide is sodium chloride.

12. An aqueous dispersion consisting essentially of, by weight:

about 37.9%--anhydrous sodium sulfate

about 7.8%--sodium chloride

about 2.6%--sodium borate

about 3.4%--fumed silicon dioxide

about 48.3%--water.

13. A heat-storage article comprising a water vapor-impermeable, thermally conducting container and an aqueous composition adapted to reversibly store heat energy as its temperature is raised above a predetermined temperature and to release stored heat energy as it is cooled below said predetermined temperature, said composition containing an inorganic salt capable of forming a salt hydrate in said aqueous composition and having a theoretical heat-of-fusion at its phase temperature of at least about 80 BTU/lb.;

a quantity of water sufficient to supply the hydration requirements of said inorganic salt in its hydrated form; and

, fumed silicon dioxide present in an effective amount to significantly prolong the heat-storage efficiency of said composition as it is repetitively thermally cycled through its phase-change temperature.

14. A heat-storage article of claim 13 wherein the thickness of said aqueous composition within said container is limited to a thickness which allows recrystallization of the phase-change material to occur primarily by diffusion.

15. A heat storage article of claim 14 wherein said container comprises a flexible resilient pouch.

16. A heat-storage article of claim 14 wherein said container comprises a rigid shell forming a core volume therein.

17. A heat-storage article of claims 15 or 16 wherein said inorganic salt is anhydrous sodium sulfate.

18. A heat-storage article of claim 17 wherein the maximum thickness of said core volume is about one centimeter.

19. A method of forming a heat-storage composition comprising an inorganic heat-of-fusion salt having fumed silicon dioxide homogeneously dispersed therein, comprising:

a. adding fumed silicon dioxide to water maintained at an elevated temperature under high shear mixing conditions to thereby form a stable, high-solids, low-viscosity aqueous predispersion of fumed silicon dioxide; and

,

b. adding said inorganic heat-of-fusion salt into said predispersion at an elevated temperature and under low speed mixing conditions to thereby form said homogeneous dispersion of inorganic heat-of-fusion salt and fumed silicon dioxide.

20. A method of claim 19 wherein said inorganic heat-of-fusion salt comprises anhydrous sodium sulfate.

21. A heat-storage composition formed by the method of claim 20.