Hydrophobic polyurethane foams, their manufacture and use

• US 4,237,237 A
• Filed: 04/30/1979
• Issued: 12/02/1980
• Est. Priority Date: 08/25/1977
• Status: Expired due to Term

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Jarre, Wolfgang, Wurmb, Rolf
• Primary Examiner(s): Welsh, Maurice J.
• Application Number:
  US06/034,541
• Time in Patent Office: 582 Days
• Field of Search: 521/128, 521/157, 521/905, 405/60, 210/36, 210/39, 210/40
• US Class Current: 521/128
• CPC Class Codes: C02F 1/681 by addition of solid materials for removing an oily layer on water
• CPC Class Codes: C08G 18/281 Monocarboxylic acid compounds
• CPC Class Codes: C08G 18/36 Hydroxylated esters of higher fatty acids
• CPC Class Codes: C08G 18/3825 containing amide groups C08G18/3821 takes precedence
• CPC Class Codes: C08G 2110/005 < 50kg/m3
• CPC Class Codes: C08G 2110/0083 prepared using water as the sole blowing agent
• CPC Class Codes: C08J 2375/04 Polyurethanes
• CPC Class Codes: C08J 9/0023 containing oxygen
• CPC Class Codes: C08J 9/0028 containing nitrogen
• CPC Class Codes: C08K 5/09 Carboxylic acids; Metal salts thereof; Anhydrides thereof
• CPC Class Codes: C08K 5/10 Esters; Ether-esters
• CPC Class Codes: C08K 5/20 Carboxylic acid amides
• CPC Class Codes: C08L 75/04 Polyurethanes
• CPC Class Codes: Y10S 521/905 Hydrophilic or hydrophobic cellular product

Abstract

Hydrophobic polyurethane foams which have densities of from 4 to 15 g/liter and in which the number of closed cells is from 2 to 30%, and the number of open cells from 98 to 70%, based on the total number of cells, are obtained from polyisocyanates, polyhydroxy compounds, catalysts and water, with or without lipophilic compounds, the components being reacted in such amounts that the ratio of hydrogen atoms capable of undergoing a Zerewitinoff reaction to NCO groups is from 1.3 to 10:1. The foams are suitable for the absorption of oil and/or by hydrophobic solvents, which may or may not contain halogen, from water.

Claims

1. Hydrophobic polyurethane foams, which have densities of from 4 to 15 g/liters and in which the number of closed cells is from 2 to 30%, and the number of open cells from 98 to 70%, based on the total number of cells, and which are prepared by reacting organic polyisocyanates, polyhydroxy compounds, catalysts and water, with or without blowing agents, lipophilic compounds, chain extenders, assistants and additives, the starting components being reacted in such amounts that

(a) the ratio of all hydrogen atoms capable of undergoing a Zerewitinoff reaction--there hydrogen atoms being bonded to the polyhydroxy compound and water and to the lipophilic compound and chain extender if used--to the NCO groups of the polyisocyanate is from 1.3 to 10:

1, and

(b) the ratio of hydrogen atoms capable of undergoing a Zerewitinoff reaction--these hydrogen atoms being bonded to the polyhydroxy compound and to the lipophilic compound and chain extender if used--to the NCO groups of the polyisocyanate is from 0.7 to 1.3;

1.

2. Hydrophobic polyurethane foams as set forth in claim 1, in the manufacture of which lipophilic compounds selected from the group consisting of unsubstituted, substituted, saturated and unsaturated aliphatic fatty acids of 10 to 25 carbon atoms and their esters and amides are co-used.

3. Hydrophobic polyurethane foams as set forth in claim 2, wherein the molar ratio of polyhydroxy compound to lipophilic compounds is from 1:

3 to 1;

20.

4. A process for separating hydrophobic compounds from water, said hydrophobic compounds being selected from the group consisting of oil, crude oil, fuel oil, diesel oil, hexane, benzene, toluene, aniline, chloroform, carbon tetrachloride, dichloroethane and hexachlorocyclopentadiene which comprises:

contacting said hydrophobic compound with a hydrophobic polyurethane foam of claim 1.