Process for the preparation of polyurethanes which are dispersible in water

• US 4,237,264 A
• Filed: 11/08/1977
• Issued: 12/02/1980
• Est. Priority Date: 11/11/1976
• Status: Expired due to Term

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: Nachtkamp, Klaus, Pedain, Josef, Noll, Klaus
• Primary Examiner(s): Briggs, Sr., Wilbert J.
• Assistant Examiner(s): Koeckert, Arthur H.
• Application Number:
  US05/849,690
• Time in Patent Office: 1,120 Days
• Field of Search: 260/29.2 TN, 528/67, 528/68, 528/69, 528/71
• US Class Current: 528/67
• CPC Class Codes: C08G 18/0828 containing sulfonate groups or groups forming them
• CPC Class Codes: C08G 18/10 Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
• CPC Class Codes: C08G 18/283 Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
• CPC Class Codes: C08G 18/3225 Polyamines
• CPC Class Codes: C08G 18/722 Combination of two or more aliphatic and/or cycloaliphatic polyisocyanates

Abstract

The instant invention is directed to novel polyurethanes which have a substantially linear molecular structure and which are dispersible in water, and the method of producing such polyurethanes. The polyurethanes of the present invention are characterized by an ethylene oxide unit content of from 0.5 to 10%, by weight, and by an ionic content of from 0.1 to 15 milliequivalents per 100 grams of polyurethane.

Claims

1. A process for the preparation of water dispersible, substantially linear polyurethanes characterized by a content of from 0.5 to 10%, by weight, of ethylene oxide units built into terminal polyether chains and from 0.1 to 15 milliequivalents of ionic groups per 100 grams of polyurethane, said process comprising reacting:

(a) an organic diisocyanate,

(b) an organic compound, which behaves as a difunctional material in the reaction with the diisocyanate and which contains isocyanate reactive hydrogen atoms,

(c) a first hydrophilic material selected from the group consisting of

(i) monoisocyanates which contain hydrophilic chains containing ethylene oxide (i.e., --CH₂ --CH₂ --O--) units,

(ii) compounds which are monofunctional in the isocyanate polyaddition reaction, which contain isocyanate reactive hydrogen atoms, and which contain ethylene oxide units, and

(iii) mixtures thereof, and

(d) a second hydrophilic material selected from the group consisting of

(i) mono- and/or diisocyanates which contain ionic groups and/or groups capable of conversion into ionic groups,

(ii) compounds which are mono- and/or difunctional in the isocyanate polyaddition reaction, which contain isocyanate reactive hydrogen atoms and which contain ionic groups and/or groups capable of conversion into ionic groups.

2. The process of claim 1 wherein component (d) contains ionizable groups and wherein said ionizable groups are converted to ionic groups during or after the reaction of the polyurethane components.

3. The process of claim 1 wherein component (b) is a compound having a molecular weight selected from the group consisting of

(i) from 300 to 6000,

(ii) less than 300, and

(iii) mixtures thereof.

4. The process of claim 3, wherein component (c) is a compound of the formula:

space="preserve" listing-type="equation">H--Y'"'"'--X--Y--R'"'"'

wherein

X represents the divalent radical obtained by removal of terminal oxygen atom from a polyalkylene oxide group having from 5 to 90 alkylene oxide units, at least 40% of which are ethylene oxide units,

Y and Y'"'"' represent oxygen or --NR"--, where R" corresponds to R'"'"', or, in the case of Y'"'"', R" can be hydrogen, and

R'"'"' represents a monovalent hydrocarbon group containing from 1 to 12 carbon atoms.

5. The process of claim 4, wherein the balance of the alkylene oxide units are propylene oxide, butylene oxide or styrene oxide units.

6. The process of claim 5 wherein component (d) is selected from the group consisting of

(i) diols containing sulfonate groups and aliphatically bound hydroxyl groups, and

(ii) diamines having aliphatically bound primary and/or secondary amino groups.

7. The process of claim 1 wherein said polyurethane contains from 2 to 8 percent, by weight, of ethylene oxide units and from 0.4 to 12 milliequivalents of ═

N═

.sup.⊕

,═

S--.sup.⊕

--COO.sup.⊖

or --SO₃.sup.⊖

groups per 100 grams.

8. The process of claim 1 wherein the ratio of total isocyanate groups to total isocyanate-reactive groups is from 0.8:

1 to 2.5;

1.

9. Polyurethanes having a substantially linear molecular structure and being dispersible in water, characterized by

(a) polyalkylene oxide polyether end chains containing from 0.5 to 10%, by weight, of ethylene oxide units based on the total quantity of polyurethane, and

(b) from 0.1 to 15 milliequivalents of ═

N═

.sup.⊕

, ═

S--.sup.⊕

,--COO.sup.⊖

or --SO₃.sup.⊖

groups per 100 grams.

10. The aqueous dispersion of the polyurethane of claim 9.