Silver halide optical information storage media

• US 4,239,338 A
• Filed: 10/22/1979
• Issued: 12/16/1980
• Est. Priority Date: 10/22/1979
• Status: Expired due to Term

• Current Assignee: Coltec Industries Incorporated (Enpro Industries Incorporated)
• Original Assignee: Corning Glass Works (Corning Incorporated)
• Inventors: Borrelli, Nicholas F., Young, Peter L.
• Primary Examiner(s): Welsh, John D.
• Application Number:
  US06/086,813
• Time in Patent Office: 421 Days
• Field of Search: 350/DIG. 1, 350/157, 350/158, 350/164, 350/155, 428/432, 428/913, 428/918, 430/502, 430/508, 430/509, 430/932, 346/135.1
• US Class Current: 430/508
• CPC Class Codes: G03C 1/4965 evaporated
• CPC Class Codes: G03C 7/02 Direct bleach-out processes; Materials therefor; Preparing or processing such materials
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10S 428/918 Material abnormally transparent
• CPC Class Codes: Y10S 430/133 Binder-free emulsion

Abstract

Optically bleachable multilayer films containing additively colored silver chloride which exhibit high infrared transmittance and good bleaching sensitivity, and optical information storage media incorporating such films, are described.

Claims

1. A visibly absorbing, optically bleachable inorganic film comprising multiple polycrystalline silver chloride layers containing crystals of additively colored silver chloride, having a thickness not exceeding about 2 microns, which exhibits, in the optically unbleached state, a light transmittance at 6300 A not exceeding about 0.3 and a light transmittance at 8500 A of at least about 0.5.

2. A multilayer photosensitive inorganic film having a thickness not exceeding about 2 microns and comprising alternating layers of PbO and AgCl, including at least three AgCl layers comprising additively colored AgCl crystals, wherein the film has, in the optically unbleached state, a light transmittance at 6300 A not exceeding about 0.3 and a light transmittance at 8500 A of at least about 0.5.

3. A film in accordance with claim 2 which has a thickness in the range of 0.5-2 microns.

4. A film in accordance with claim 3 which has, in the optically unbleached state, a transmittance at 8500 A of at least about 0.7.

5. A optical information storage medium which includes a visibly absorbing, optically bleachable inorganic film disposed on a support for the film, said film:

(a) comprising multiple polycrystalline silver chloride layers which comprise crystals of additively colored silver chloride;

(b) having a thickness not exceeding about 2 microns; and

(c) having, in the optically unbleached state, a light transmittance at 6300 A not exceeding about 0.3 and a light transmittance at 8500 A of at least about 0.5.

6. An optical information storage medium which includes a multilayer photosensitive inorganic film disposed on a film support, said film having a thickness not exceeding about 2 microns, comprising alternating layers of PbO and AgCl, and including at least three AgCl layers comprising additively colored AgCl crystals, wherein the film has, in the optically unbleached state, a light transmittance at 6300 A not exceeding about 0.3 and a light transmittance at 8500 A of at least about 0.5.

7. An optical information storage medium in accordance with claim 6 wherein the film support is a transparent glass sheet.

8. An optical information storage medium in accordance with claim 6 wherein the film support is a light-reflecting support.

9. An optical information storage medium in accordance with claim 6 wherein the film support consists of a supporting member comprising a light reflecting layer positioned between the member and the film.

10. An optical information storage medium in accordance with claim 9 wherein the light-reflecting layer consists of a metallic film.

11. An optical information storage medium in accordance with claim 9 wherein the film support further comprises a barrier layer positioned between said light-reflecting layer and said film.

12. An optical information storage medium in accordance with claim 11 wherein the barrier layer consists of a transparent metal oxide film.