Detergent compositions containing nonionic and cationic surfactants, the cationic surfactant having a long alkyl chain of from about 20 to about 30 carbon atoms

• US 4,239,659 A
• Filed: 12/15/1978
• Issued: 12/16/1980
• Est. Priority Date: 12/15/1978
• Status: Expired due to Term

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Murphy, Alan P.
• Primary Examiner(s): Pitlick, Harris A.
• Application Number:
  US05/969,909
• Time in Patent Office: 732 Days
• Field of Search: 252/547, 252/528, 252/117, 252/8.8, 252/542, 252/524
• US Class Current: 510/331
• CPC Class Codes: C11D 1/62 Quaternary ammonium compounds
• CPC Class Codes: C11D 1/72 Ethers of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/835 Mixtures of non-ionic with cationic compounds

Abstract

Laundry detergent compositions, which are either free of phosphate materials or contain only low levels of such materials, containing a nonionic surfactant, preferably specific alcohol ethoxylate nonionic surfactants, together with selected single long chain (C₂₀ --C₃₀) alkyl cationic surfactants, are disclosed. These compositions provide both excellent particulate and greasy/oily soil removal and, additionally, provide fabric softening, static control, color fidelity, and dye transfer inhibition benefits to fabrics laundered therewith. A process for laundering fabrics, using these compositions, is also disclosed.

Claims

1. A detergent composition, containing from 0 to about 20% phosphate materials, comprising from about 5% to about 100% of a surfactant mixture consisting essentially of:

(a) a nonionic surfactant having an HLB of from about 5 to about 17; and

(b) a cationic surfactant having the formula R(R'"'"')₃ N⁺ Z^-, wherein R is an alkyl group containing an average of from about 20 to about 30 carbon atoms, each R'"'"' is an alkyl or hydroxyalkyl group containing from 1 to 4 carbon atoms, or a benzyl group with no more than one R'"'"' in a molecule being benzyl, and Z is an anion selected from the group consisting of halides, hydroxide, nitrate, sulfate, and alkyl sulfates;

the ratio, by weight, of said nonionic surfactant to said cationic surfactant being from about 3;

1 to about 15;

1.

2. A composition according to claim 1 which contains from about 10% to about 95% of said surfactant mixture.

3. A composition according to claim 2 wherein the ratio of said nonionic surfactant to said cationic surfactant is from about 4:

1 to about 10.1.

4. A composition according to claim 3 wherein the cationic surfactant is selected from the group consisting of ##STR5## wherein one of said R¹, R², R³ and R⁴ substituents is an alkyl chain averaging from about 20 to about 30 carbon atoms, the remainder of said substituents being selected from the group consisting of C₁ -C₄ alkyl, or C₁ -C₄ hydroxyalkyl groups and Z is selected from the group consisting of halides, hydroxide, nitrate, sulfate, or alkyl sulfate.

5. A composition according to claim 4 wherein, in said cationic surfactant, R is an alkyl group containing an average of from about 20 to about 25 carbon atoms.

6. A composition according to claim 1 wherein said nonionic surfactant has the formula R(OC₂ H₄)_n OH, wherein R is a primary or secondary alkyl chain of from about 8 to about 22 carbon atoms and n is an average of from about 2 to about 12.

7. A composition according to claim 1 wherein the pH of said composition is above about 7.5.

8. The composition of claim 7 wherein the pH is above about 8.

9. The composition of claim 8 containing reserve alkalinity sufficient to maintain wash solutions prepared therewith within the pH range of from about 8 to about 11.

10. A composition according to claim 7 which contains from about 10% to about 95% of said surfactant mixture.

11. A composition according to claim 10 wherein the ratio of said nonionic surfactant to said cationic surfactant is from about 4:

1 to about 10;

1.

12. A composition according to claim 11 wherein, in said nonionic surfactant, R is an alkyl chain of from about 10 to about 18 carbon atoms.

13. A composition according to claim 12 wherein, in said nonionic surfactant, n is an average of from about 2 to about 9.

14. A composition according to claim 13 wherein the cationic surfactant is selected form the group consisting of ##STR6## wherein one of said R¹, R², R³ and R⁴ substituents is an alkyl chain averaging from about 20 to about 30 carbon atoms, the remainder of said substituents are selected from the group consisting of C₁ -C₄ alkyl, or C₁ -C₄ hydroxyalkyl groups and Z is selected from the group consisting of halides, hydroxide, nitrate, sulfate, or alkyl sulfate.

15. A composition according to claim 10 wherein, in said cationic surfactant, R is an alkyl group containing an average of from about 20 to about 25 carbon atoms.

16. A composition according to claim 13 wherein, in said cationic surfactant, R is an alkyl group containing an average of from about 20 to about 25 carbon atoms.

17. A composition according to claim 10 wherein said nonionic surfactant has an HLB of from about 8.5 to about 14.

18. A composition according to claim 16 wherein said nonionic surfactant has an HLB of from about 8.5 to about 14.

19. A composition according to claim 18 wherein said nonionic surfactant is selected from the group consisting of the condensation product of coconut alcohol with 5 or 7 moles of ethylene oxide, the condensation product of tallow alcohol with 6, 9, or 11 moles of ethylene oxide, the condensation product of secondary C₁₅ alcohol with 5 or 9 moles ethylene oxide, the condensation product of C_12-13 alcohol with 4, 5, 6.5, or 9 moles of ethylene oxide, the condensation product of C_12-15 alcohol with 7 or 9 moles of ethylene oxide, the condensation product of C₁₂ alcohol with 5 moles of ethylene oxide, the condensation product of C_14-15 alcohol with 4, 5, 7, or 9 moles of ethylene oxide, and mixtures thereof.

20. A composition of claim 18 wherein said nonionic surfactant has an HLB of from about 10 to about 13.5.

21. A composition according to claim 19 wherein said nonionic surfactant is selected from the group consisting of the condensation product of C₁₂ alcohol with 5 moles of ethylene oxide, the condensation product of C_12-13 alcohol with 6.5 moles of ethylene oxide, the condensation product of C_12-13 alcohol with 9 moles of ethylene oxide, the condensation product of C_14-15 alcohol with 7 moles of ethylene oxide, and mixtures thereof.

22. A composition according to claim 13 wherein said nonionic surfactant is selected from the group consisting of the condensation product of C₁₂ alcohol with 5 moles of ethylene oxide, the condensation product of C_12-13 alcohol with 3 moles of ethylene oxide, and the same condensation which is stripped so as to remove unethoxylated and lower ethoxylate fractions, the condensation product of C_12-13 alcohol with 6.5 moles of ethylene oxide, the condensation product of C_14-15 alcohol with 4 moles of ethylene oxide, the condensation product of C_14-15 alcohol with 7 moles of ethylene oxide, and mixtures thereof.

23. A composition according to claim 16 wherein, in said cationic surfactant, each R'"'"' is a methyl group.

24. A composition according to claim 23 wherein, in said cationic surfactant, R is an alkyl group containing an average of from about 20 to about 22 carbon atoms.

25. A composition according to claim 24 wherein, in said cationic surfactant, Z is selected from the group consisting of chloride, bromide, methyl sulfate, and mixtures thereof.

26. A composition according to claim 10 wherein, in said cationic surfactant, each R'"'"' is a methyl group.

27. A composition according to claim 26 wherein, in said cationic surfactant, R is an alkyl group containing an average of from about 20 to about 22 carbon atoms.

28. A composition according to claim 10 which contains from 0 to about 10% phosphate materials.

29. A composition according to claim 28 which is substantially free of phosphate materials.

30. A composition according to claim 10 which contains from about 20% to about 90% of said surfactant mixture.

31. A composition according to claim 6 wherein said surfactant mixture has a cloud point of from about 10°

C. to about 70°

C.

32. A composition according to claim 31 wherein said surfactant mixture has a reduced cationic monomer concentration of from about 0.002 to about 0.2.

33. A composition according to claim 6 wherein said surfactant mixture has a reduced cationic monomer concentration of from about 0.005 to about 0.2.

34. A method of cleaning fabrics, while simultaneously providing fabric softening, static control, color fidelity, and dye transfer inhibition benefits, said method comprising the agitation of the fabrics in an aqueous solution containing from about 0.01 to about 0.3% of the detergent composition of claim 1.