Detergent composition comprising a hydrolyzable cationic surfactant and specific alkalinity source

• US 4,239,660 A
• Filed: 12/13/1978
• Issued: 12/16/1980
• Est. Priority Date: 12/13/1978
• Status: Expired due to Term

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Kingry, Gary W.
• Primary Examiner(s): Pitlick, Harris A.
• Application Number:
  US05/969,115
• Time in Patent Office: 734 Days
• Field of Search: 252/528, 252/547, 252/8.8, 252/117
• US Class Current: 510/331
• CPC Class Codes: C11D 1/62 Quaternary ammonium compounds
• CPC Class Codes: C11D 1/72 Ethers of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/835 Mixtures of non-ionic with cationic compounds
• CPC Class Codes: C11D 3/046 Salts
• CPC Class Codes: C11D 3/10 Carbonates ; Bicarbonates

Abstract

Laundry detergent compositions offering improved removal of particulate and greasy/oily soils, containing mixtures of selected nonionic and hydrolyzable cationic surfactants, together with specifically defined alkalinity sources, are disclosed. This invention permits the formulation of compositions which are alkaline in the laundry solution, and in which hydrolyzable cationic surfactants are stable during long periods of storage.

Claims

1. A laundry detergent composition which comprises:

(a) from about 2% to about 95% of a surfactant mixture consisting essentially of;

(1) a nonionic surfactant having an HLB of from about 5 to about 17; and

(2) a cationic surfactant selected from the group consisting of;

##STR28## wherein each R¹ is C₁ to C₄ alkyl or hydroxyalkyl;

R² is C₅ to C₃₀ straight or branched chain alkyl, alkenyl, alkylbenzyl, or alkyl phenyl group or ##STR29## wherein s is from 0 to 5;

R³ is C₁ to C₂₀ alkylene or alkenylene;

a is 0 or 1, n is 0 or 1, and a is 1 only when n is 1;

m is from 1 to 5;

Z¹ and Z² are each selected from the group consisting of;

##STR30## and wherein at least one of said groups is selected from the group consisting of ester, reverse ester, amide and reverse amide and X is an anion which makes the surfactant at least water-dispersible;

##STR31## wherein each R¹ is C₁ to C₄ alkyl or hydroxyalkyl;

each R² is either hydrogen or C₁ to C₃ alkyl;

R³ is C₄ to C₃₀ straight or branched chain alkyl, alkenyl or alkylbenzyl, R⁴ is C₁ to C₁₀ alkylene or alkenylene;

n is from 2 to 4;

y is from 1 to 20;

a is 0 or 1, t is 0 or 1, and a can be 1 only when t is 1;

m is from 1 to 5;

Z² is selected from the group consisting of ##STR32## Z¹ is selected from the group consisting of ##STR33## said selections being made so that ##STR34## is an alkyl or alkenyl group which can be interrupted by only structures selected from the group consisting of;

##STR35## and wherein at least one of said Z¹ and Z² groups is selected from the group consisting of ester, reverse ester, amide, and reverse amide; and

X is an anion which makes the surfactant at least water-dispersible; and

(iii) mixtures thereof;

wherein the ratio of said nonionic surfactant to said cationic surfactant is in the range of from about 1;

1 to about 100;

1; and

(b) from about 1% to about 25% of an inorganic alkaline component selected from the group consisting of borax decahydrate, borax pentahydrate, sodium carbonate, and mixtures thereof, and which is present in an amount such that the detergent composition forms a solution having a pH of from about 8 to about 10 within about 3 minutes after it is placed in 100°

F. water at a concentration of about 0.15%.

2. The composition according to claim 1 wherein the nonionic surfactant is biodegradable and has the formula R(OC₂ H₄)_n OH wherein R is a primary or secondary alkyl chain of from about 8 to about 22 carbon atoms and n is an average of from about 2 to about 12.

3. The composition according to claim 2 which contains from about 5% to about 20% of said inorganic alkaline component.

4. The composition according to claim 3 wherein said alkaline component is contained in an amount such that the composition forms a solution having a pH of from about 8.5 to about 9.5, within about 2 minutes, when placed in 100°

F. water at a concentration of about 0.15%.

5. The composition according to claim 4 which contains from about 8% to about 16% of said alkaline component.

6. The composition according to claim 2 which contains from about 10% to about 90% of said cationic/nonionic surfactant mixture.

7. The composition according to claim 6 which contains from about 15% to about 85% of a said cationic/nonionic surfactant mixture.

8. The composition according to claim 7 wherein the ratio of nonionic surfactant to cationic surfactant is from about 5:

3 to about 50;

1.

9. The composition according to claim 8 wherein, in the nonionic surfactant, R is a C₁₀ -C₂₀ alkyl group.

10. The composition according to claim 9 wherein, in the nonionic surfactant, n is from 2 to 9.

11. The composition according to claim 10 wherein the ratio of nonionic surfactant to cationic surfactant is from about 5:

3 to about 20;

1.

12. The composition according to claim 11 wherein the cationic surfactant has the formula ##STR36## wherein Z² is selected from the group consisting of ester, reverse ester, amide, and reverse amide.

13. The composition according to claim 12 wherein Z² is ##STR37##

14. The composition according to claim 13 wherein n is 0 and a is 0.

15. The composition according to claim 14 wherein R² is a C₈ -C₂₀ alkyl group.

16. The composition according to claim 15 wherein m is 2.

17. The composition according to claim 11 wherein the cationic surfactant has the formula ##STR38## and wherein Z² is selected from the group consisting of ester, reverse ester, amide, and reverse amide.

18. The composition according to claim 17 wherein Z² is ##STR39##

19. The composition according to claim 18 wherein n is 2 and R² is hydrogen.

20. The composition according to claim 19 wherein a is 0, m is 2, R⁴ is methylene, t is 1, y is from 1 to 10, and R³ is a C₈ -C₁₈ alkyl group.

21. The composition according to claim 17 wherein the ratio of nonionic surfactant to cationic surfactant is from about 5:

3 to about 5;

1.

22. The composition according to claim 11 which contains from about 5% to about 20% of said inorganic alkaline component.

23. The composition according to claim 22 wherein said alkaline component is contained in an amount such that the composition forms a solution having a pH of from about 8.5 to about 9.5 within about 2 minutes, when placed in 100°

F. water at a concentration of about 0.15%.

24. The composition according to claim 12 which contains from about 5% to about 20% of said inorganic alkaline component.

25. The composition according to claim 24 wherein said alkaline component is included in an amount such that said composition forms a solution having a pH of from about 8.5 to about 9.5, within about 2 minutes, when placed in 100°

F. water at a concentration of about 0.15%.

26. The composition according to claim 25 wherein the ratio of said nonionic surfactant to said cationic surfactant is from about 5:

3 to about 5;

1.

27. The composition according to claim 26 wherein said alkaline component is selected from the group consisting of borax decahydrate, borax pentahydrate, and mixtures thereof.

28. The composition according to claim 27 which contains from about 8% to about 16% of said alkaline component.

29. The composition according to claim 28 wherein, in said cationic component, R¹ is CH₃, R² is C₁₇ alkyl, and X is a chlorine anion.

30. The composition according to claim 29 wherein the ratio of said nonionic component to said cationic component is about 5:

2.

31. The composition according to claim 13 wherein n is 0, a is 0, m is 2, R² is C₁₇ alkyl, R¹ is CH₃, and X is chlorine anion.

32. A process for laundering fabrics comprising the agitation of said fabrics in an aqueous solution containing from about 0.01 to about 0.3% of the detergent composition of claim 1.