Method of producing electrically insulating, highly flexible and/or solderable coatings

• US 4,239,814 A
• Filed: 08/31/1978
• Issued: 12/16/1980
• Est. Priority Date: 09/19/1977
• Status: Expired due to Term

• Current Assignee: Herberts Gesellschaft Mit Beschrankter Haftung
• Original Assignee: Herberts Gesellschaft Mit Beschrankter Haftung
• Inventors: Nagel, Klaus
• Primary Examiner(s): Hoffman, James R.
• Application Number:
  US05/938,650
• Time in Patent Office: 838 Days
• Field of Search: 427/120, 427/105, 427/106, 427/118, 427/120, 427/121, 260/30.2, 260/32.6 N
• US Class Current: 427/120
• CPC Class Codes: C08G 18/8061 masked with compounds having only one group containing active hydrogen
• CPC Class Codes: C09D 175/06 from polyesters
• CPC Class Codes: H01B 3/303 Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups H01B3/38 or H01B3/302
• CPC Class Codes: H01B 3/421 Polyesters

Abstract

A method of producing electrically insulating highly flexible and/or solderable coatings on electrical conductors or fibre materials which comprises

(A) coating on said conductor or fibre material with a solution comprising:

(i) isocyanates masked with compounds having reactive hydrogen atoms in the molecule and selected from the group consisting of acid amides having 1 or 2 amide hydrogen atoms, hydroxylamine, reaction products of hydroxylamine with carbonyl compounds, imines having an imine hydrogen atom, and lactams with melting or sublimation points below 25° C.;

(ii) polyester resins and modified polyester resin selected from the group consisting of imide-modified polyester resins, amide-modified polyester resins and mixtures thereof said polyester resins and modified polyester resins having a content of terminal hydroxyl groups of from 1 to 16% by weight and being derived from compounds selected from the group consisting of polyhydric alcohols, aliphatic carboxylic acids, polybasic carboxylic acids having carboxyl groups bonded to an aromatic ring, and amino group containing compounds; and

(iii) solvents having from 1 to 10 carbon atoms, a boiling point of at most 250° C. and being selected from the group consisting of araliphatic ketones; aliphatic ketones, araliphatic alcohols, aliphatic alcohols, ether oxygen containing araliphatic alcohols, ether oxygen-containing aliphatic alcohols, aliphatic keto-alcohols, araliphatic keto-alcohols, esterified aliphatic alcohols, and esterified araliphatic alcohols; and

(B) heating to a working temperature of above 140° C., and solutions for use in this method.

Claims

1. A method of producing electrically insulating highly flexible and/or solderable coatings on electrical conductors or fibre materials which comprise

(A) coating said conductor or fibre material with a solution comprising:

(i) isocyanates masked with compounds having reactive hydrogen atoms in the molecule and selected from the group consisting of acid amides having 1 or 2 amide hydrogen atoms, hydroxylamine, reaction products of hydroxylamine with carbonyl compounds, imines having an imine hydrogen atom, and lactams with melting or sublimation points below 25°

C.;

(ii) polyester resins and modified polyester resins selected from the group consisting of imide-modifed polyester resins, amide-modified polyester resins and mixtures thereof, said polyester resins and modified polyester resins having a content of terminal hydroxyl groups of from 1 to 16% by weight and being derived from compounds selected from the group consisting of polyhydric alcohols, aliphatic carboxylic acids, polybasic carboxylic acids having carboxyl groups bonded to an aromatic ring, and amino group containing compounds; and

(iii) solvents having from 1 to 10 carbon atoms, a boiling point of at most 250°

C. and being selected from the group consisting of araliphatic ketones, aliphatic ketones, araliphatic alcohols, aliphatic alcohols, ether oxygen-containing araliphatic alcohols, ether oxygen-containing aliphatic alcohols, aliphatic keto-alcohols, araliphatic keto-alcohols, esterified aliphatic alcohols, and esterified aliphatic alcohols, and

(B) heating to a working temperature of above 140°

C.

2. A method according to claim 1, characterised in that one or more of the components (i) to (iii) contains at least one compound having at least one five-membered imide ring.

3. A method according to claim 1, characterised in that the solution further comprises compounds selected from the group consisting of catalysts, additives and auxiliary material.

4. A method according to claim 1, characterised in that the isocyanate are masked with aliphatic oximes.

5. A method according to claim 1, characterised in that the isocyanates are those having isocyanate groups bonded to aromatic rings.

6. A solution for the production of electrically insulating highly flexible and/or solderable coatings on electric conductors or fibre materials, said solution comprising:

(i) isocyanates masked with compunds having reactive hydrogen atoms in the molecule and selected from the group consisting of acid amides having 1 to 2 amide hydrogen atoms, hydroxylamine, reaction products of hydroxylamine with carbonyl compounds, imines having an imine hydrogen atom, and lactams with melting or sublimation points below 25°

C.;

(ii) polyester resins and modified polyester resins selected from the group consisting of imide-modified polyester resins, amide-modified polyester resins and, mixtures thereof, said polyester resins and modified polyester resins having a content of terminal hydroxyl groups of from 1 to 16% by weight and being derived from compounds selected from the group consisting of polyhydric alcohols, aliphatic carboxylic acids, polybasic carboxylic acids having carboxyl groups bonded to an aromatic ring, and amino group containing compounds; and

(iii) solvents having from 1 to 10 carbon atoms, a boiling point of at most 250°

C. and being selected from the group consisting of araliphatic ketones, aliphatic ketones, araliphatic alcohols, aliphatic alcohols, ether oxygen-containing araliphatic alcohols, ether oxygen-containing aliphatic alcohols, araliphatic ketoalcohols, esterified aliphatic alcohols, and esterified araliphatic alcohols.

7. A solution according to claim 6, characterised in that one or more of the components (i) to (iii) contains at least one compound having at least one five-membered imide ring.

8. A solution according to claim 6, characterised in that it further comprises compounds selected from the group consisting of catalysts, additives and auxiliary materials.

9. A solution according to claim 6 characterised in that the isocyanate are masked with aliphtic oximes.

10. A solution according to claim 6 characterised in that the isocyanates are those having isocyanate groups bonded to aromatic rings.