Electrolytic production of alkali metal hypohalite

• US 4,240,884 A
• Filed: 06/19/1979
• Issued: 12/23/1980
• Est. Priority Date: 02/15/1979
• Status: Expired due to Term

• Current Assignee: Oronzio de NORA Impianti Elettrochimici SPA (Industrie De Nora S.p.A)
• Original Assignee: Oronzio de NORA Impianti Elettrochimici SPA (Industrie De Nora S.p.A)
• Inventors: Pellegri, Alberto
• Primary Examiner(s): Prescott, Arthur C.
• Application Number:
  US06/050,143
• Time in Patent Office: 553 Days
• Field of Search: 204/95, 204/151, 204/180 P, 204/128
• US Class Current: 205/500
• CPC Class Codes: C25B 1/26 Chlorine; Compounds thereof by simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine C25B1/34
• CPC Class Codes: C25B 9/19 with diaphragms

Abstract

A process and an apparatus for producing alkali metal hypohalite by passing an alkali metal brine solution through the anode compartment of an electrolytic cell in which the anode compartment and the cathode compartment are separated by a fluid impervious, anion-permeable membrane, providing an aqueous support catholyte into the cathode compartment, impressing an electric potential across the anode and cathode to evolve halogen at the anode and hydrogen at the cathode and recovering alkali metal hypohalite from the anode compartment.

Claims

1. An electrolytic process for producing an alkali metal hypohalite solution comprising passing an aqueous alkali metal halide solution through the anode compartment of an electrolysis cell having an anode compartment and a cathode compartment separated by a fluid-impervious anion-permeable membrane with an anode in the anode compartment and a cathode in the cathode compartment, providing an aqueous support catholyte in the cathode compartment, applying an electric potential across the cell sufficient to evolve halogen at the anode and reduce water at the cathode and recovering an effluent solution from the anode compartment containing alkali metal hypohalite.

2. The process of claim 1, wherein the alkali metal halide is sodium chloride, the support catholyte is an aqueous solution of sodium hydroxide and sodium chloride and the alkali metal hypohalite is sodium hypochlorite.

3. The process of claim 1 wherein the support catholyte contains a film forming agent from the group consisting of alkali metal chromates and dichromates.