Sulfur transfer process in catalytic cracking

• US 4,240,899 A
• Filed: 11/05/1979
• Issued: 12/23/1980
• Est. Priority Date: 11/05/1979
• Status: Expired due to Term

• Current Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Original Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Inventors: Schuette, William L., Reid, Terry A., Gladrow, Elroy M.
• Primary Examiner(s): Gantz, Delbert E.
• Assistant Examiner(s): Schmitkons, G. E.
• Application Number:
  US06/091,153
• Time in Patent Office: 414 Days
• Field of Search: 208/120
• US Class Current: 208/120.25
• CPC Class Codes: B01J 29/068 Noble metals
• CPC Class Codes: C10G 11/05 Crystalline alumino-silicates, e.g. molecular sieves
• CPC Class Codes: Y10S 502/517 Sulfur or sulfur compound removal

Abstract

An improved catalyst, and process utilizing said catalyst for catalytically cracking a sulfur-containing hydrocarbon feed, and for the fixation of sulfur by the catalyst and transfer thereof from the catalyst regeneration zone to the reaction zone of a catalytic cracking unit. The catalyst comprises an admixture of composite particles, one present in major concentration for providing principally cracking and combustion promoting functions, and the other present in minor concentration for providing principally sulfur fixation and transfer functions. The particle present in major concentration, on the one hand, is constituted essentially of one of more Group VIII noble metals, preferably platinum, composited with a support comprised of a crystalline alumino silicate component distributed in an active cracking catalyst matrix, suitably one constituted of silica-alumina. The minor component particle, on the other hand, is comprised of one or more Group II-A metals, preferably magnesium, composited with a support, suitably silica-magnesia or silica-alumina, which may also contain a crystalline aluminosilicate zeolite component dispersed within the silica-magnesia or silica-alumina support matrix.

Claims

1. In a process for cracking a sulfur-containing hydrocarbon feed in a cracking zone at cracking conditions by contact with a particulate cracking catalyst to produce C₃⁺ product liquids and gases, flue gas being formed and coke and sulfur deposited on said catalyst during cracking, the catalyst is transferred to a catalyst regeneration zone wherein it is contacted with an oxygen-containing gas and the coke and sulfur deposits gasified and removed from the catalyst by burning, and the coke-depleted catalyst is recycled to said cracking zone for contact with additional fresh feed hydrocarbon,

the improvement comprising,

contacting the sulfur-containing hydrocarbon feed in the cracking zone with a catalyst composition comprising an admixture of composite particles, a major component particle in concentration of greater than 50 percent, based on the total weight of the catalyst, constituted of a Group VIII noble metal composited on an aluminosilicate zeolite-containing refractory inorganic oxide support in concentration ranging from about 1 part to about 50 parts, per million parts by weight of total catalyst, for providing principally cracking and combustion promoting functions, and a minor component particle present in the admixture in concentration of less than 50 percent, based on the total weight of the catalyst, constituted of a Group II-A metal composited with a refractory inorganic oxide support in concentration ranging from about 1 percent to about 50 percent, based on the weight of the minor component particles, to crack said feed and promote combustion reactions, and then

transferring the catalyst composition to the regeneration zone whereby sulfur is fixed on the minor component particles, sulfur dioxide is converted to sulfur trioxide and formed into a Group II-A metal sulfate thus suppressing the sulfur oxides emission which normally occurs with release of the regeneration zone flue gas, and then,

recycling the catalyst composition to the reaction zone, whereby the Group II-A metal sulfate is reacted to form from said sulfate principally hydrogen sulfide which is released with the flue gases from the reaction zone.

2. The process of claim 1 wherein the support of the major component particles of the composition is comprised of an aluminosilicate zeolite dispersed in a silica-alumina matrix.

3. The process of claim 2 wherein the zeolite of the support of the major component particles of the composition is rare earth exchanged.

4. The process of claim 1 wherein the support of the major component particles of the composition is comprised of ultrastable Y faujasite and porous alumina dispersed in a silica alumina matrix.

5. The process of claim 1 wherein the refractory inorganic oxide support of the minor component particles of the composition is comprised of an aluminosilicate zeolite dispersed in a silica magnesia matrix.

6. The process of claim 5 wherein the aluminosilicate zeolite of the support of the major component particles of the composition is rare earth exchanged.

7. The process of claim 1 wherein the major component particles are present in the catalyst admixture in concentration ranging greater than 50 percent to about 95 percent.

8. The process of claim 1 wherein the major component particles are present in the catalyst admixture in concentration ranging from about 90 percent to about 95 percent.

9. The process of claim 1 wherein the minor component particles are present in the catalyst admixture in concentration ranging from about 5 percent to just below 50 percent.

10. The process of claim 1 wherein the minor component particles are present in the catalyst admixture in concentration ranging from about 5 percent to about 10 percent.

11. The process of claim 1 wherein the Group VIII noble metal contained on the major component particles of the catalyst admixture is platinum or palladium.

12. The process of claim 11 wherein the concentration of the Group VIII noble metal component ranges from about 0.1 part to about 10 parts, per million parts by weight of total catalyst.

13. The process of claim 12 wherein the concentration of the Group VIII noble metal ranges from about 0.1 part to about 1 part.

14. The process of claim 1 wherein the Group II-A metal component contained on the minor component particles of the catalyst admixture is magnesium.

15. The process of claim 1 wherein the concentration of the Group II-A metal component contained of the Group II-A metal component contained on the minor component particles of the catalyst admixture ranges from about 5 percent to about 20 percent.