Process and amine-solvent absorbent for removing acidic gases from gaseous mixtures

• US 4,240,922 A
• Filed: 09/22/1977
• Issued: 12/23/1980
• Est. Priority Date: 09/22/1977
• Status: Expired due to Term

• Current Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Original Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Inventors: Savage, David W., Sartori, Guido
• Primary Examiner(s): Padgett, Benjamin R.
• Assistant Examiner(s): Barr, J. L.
• Application Number:
  US05/835,811
• Time in Patent Office: 1,188 Days
• Field of Search: 423/220, 423/223, 423/226, 423/228, 260/584 R, 252/189, 252/190
• US Class Current: 252/189
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: B01D 53/526 Mixtures of hydrogen sulfide and carbon dioxide

Abstract

Acidic gases are substantially removed from a normally gaseous mixture by a process comprising contacting the normally gaseous mixture with an amine-solvent liquid absorbent comprising (i) an amine mixture comprised of at least about 50 mol % of a sterically hindered amine and at least about 10 mol % of a tertiary amino alcohol, wherein said sterically hindered amine contains at least one secondary amino group which is part of a ring and is attached to either a secondary or tertiary carbon atom or a primary amino group attached to a tertiary carbon atom, and (ii) a solvent for said amine mixture which is also a physical absorbent for said acidic gases. The liquid absorbent may also include up to about 35 weight percent water. The coaction of the sterically hindered amine and the tertiary amino alcohol in conjunction with the solvent provides an increase in the amount of CO₂ containing acidic gases absorbed compared to the use of the same sterically hindered amines alone and lowers the heat of reaction.

Claims

1. An amine-solvent liquid composition, comprising:

(a) an amine mixture comprised of at least 50 mol % of a sterically hindered amine and at least about 10 mol % of a tertiary amino alcohol, wherein said sterically hindered amine contains at least one secondary amino group which is part of a ring and is attached to either a secondary or tertiary carbon atom or a primary amino group attached to a tertiary carbon atom, and

(b) a nonreactive solvent for said amine mixture, said solvent being a member selected from the group consisting of sulfones;

sulfoxides;

glycols, mono- and diethers thereof;

1,3-dioxo compounds characterized by being a 5- to 6-membered heterocyclic ring;

aromatic ethers;

aromatic hydrocarbons;

pryyolidones;

piperidones; and

mixtures thereof.

2. The amine-solvent liquid absorbent composition of claim 1 wherein said sterically hindered amine is a member selected from the group consisting of 2-piperidine methanol, 2-piperidine ethanol, 2-(1-hydroxy-ethyl)-piperidine, 5-hydroxy-2-methyl piperidine, 2-methyl-3-hydroxy piperidine, 2,6-dimethyl-3-hydroxy piperidine, 2,5-dimethyl-4-hydroxy piperidine, 3-amino-3-methyl-1-butanol, 2-amino-2-methyl-1-butanol, 2-amino-2-methyl-3-butanol and 3-amino-3-methyl-2-pentanol.

3. The amine-solvent liquid composition of claim 1 wherein the sterically hindered amine is a 2-piperidine alkanol.

4. The amine-solvent liquid composition of claim 1 wherein the tertiary amino alcohol is a member selected from the group consisting of 3-dimethylamino-1-propanol, 1-diethylamino-2-propanol, 2-diethylamino ethanol, 3-diethylamino-1-propanol, N-methyl diethanolamine and 1-methyl-3-hydroxy piperidine.

5. The amine-solvent liquid composition of claim 1 wherein the nonreactive solvent is a suflone.

6. The amine-solvent liquid absorbent composition of claim 5 wherein said nonreactive solvent is a cyclotetramethylene sulfone.

7. The amine-solvent liquid absorbent composition of claim 6 wherein said sulfone is solfolane.

13. The composition of claim 1 wherein the composition additionally includes additives selected from the group consisting of antifoaming agents, antioxidants and corrosion inhibitors.

8. An amine-solvent liquid absorbent composition comprising:

(a) an amine mixture comprised of at least 50 mol % of a sterically hindered amine and at least 10 mol % of a tertiary amino alcohol, wherein said sterically hindered amine is a member selected from the group consisting of 2-piperidine methanol and 2-piperidine ethanol and said tertiary amino alcohol is a member selected from the group consisting of 3-dimethylamino-1-propanol, 1-diethylamino-2-propanol and 2-diethylamino ethanol; and

(b) a nonreactive solvent for said amine mixture, said solvent being a cyclotetramethylene sulfone.

9. The amine-solvent liquid absorbent composition of claim 8 wherein said nonreactive solvent is sulfolane.

10. The amine-solvent liquid absorbent composition of claim 8 which additionally include up to about 35 weight percent water.

11. The amine-solvent liquid absorbent composition of claim 10 wherein the water content is in the range from about 10 to about 20 weight percent.

14. The composition of claim 8 wherein the composition additionally includes additives selected from the group consisting of antifoaming agents, antioxidants and corrosion inhibitors.

12. An amine-solvent liquid absorbent composition comprising:

(a) an amine mixture comprised of at least about 65 mol % of 2-piperidine ethanol and 20 to about 35 mol % of a tertiary amino alcohol selected from the group consisting of 3-dimethylamino-1-propanol, 1-diethylamino-2-propanol and 2-diethylamino ethanol, wherein the total amine concentration in said liquid absorbent is in the range from about 10 weight % to about 65 weight %;

(b) water, in an amount ranging from about 10 to about 20 weight %; and

(c) essentially all of the balance being sulfolane.

15. The composition of claim 12 wherein the composition additionally includes additives selected from the group consisting of antifoaming agents, antioxidants and corrosion inhibitors.