Method of plating the surface of a substrate

• US 4,241,105 A
• Filed: 12/17/1979
• Issued: 12/23/1980
• Est. Priority Date: 12/17/1979
• Status: Expired due to Term

• Current Assignee: AT&T, Inc.
• Original Assignee: Western Electric Co., Inc. (Nokia Corporation)
• Inventors: Mayweather, William T.
• Primary Examiner(s): Kendall, Ralph S.
• Application Number:
  US06/104,243
• Time in Patent Office: 372 Days
• Field of Search: 106/1.26, 106/1.23, 427/125, 427/118, 427/229, 427/343, 427/306, 427/404, 427/443.1, 427/436, 204/38 B, 204/20, 174/120 C, 174/126 C, 174/128 BL
• US Class Current: 427/125
• CPC Class Codes: C23C 18/1831 Use of metal, e.g. activation, sensitisation with noble metals
• CPC Class Codes: C23C 18/2006 by other methods than those of C23C18/22 - C23C18/30
• CPC Class Codes: C23C 18/208 with use of metal first

Abstract

A substrate is plated by a process which includes the steps of catalyzing a substrate by coating its surface with a silver-pyridine complex dissolved in an organic solvent, converting the complex to silver oxide by immersion in a basic solution, and reducing the silver oxide to metallic silver and then electroless plating. When the substrate is copper, the silver oxide is spontaneously converted to a reflective and continuous layer of metallic silver upon immersion in the basic solution. The process as disclosed is used in the manufacture of insulated conductors and cord from nylon filaments.

Claims

1. A method of plating a dielectric surface of a substrate comprising the steps of:

(a) coating the substrate with a solution comprising a silver-pyridine complex dissolved in a non-aqueous solvent;

(b) drying the substrate;

(c) immersing the substrate in a basic solution whereby the silver-pyridine complex is converted to a silver oxide; and

(d) reducing the silver oxide to metallic silver.

2. The method recited in claim 1 wherein the non-aqueous solvent comprises a member of the group consisting of a low molecular weight ketone, a low molecular weight alcohol and a mixture thereof.

3. The method recited in claim 2 wherein the ketone is an alkyl ketone having from 3-6 carbon atoms and the alcohol is selected from the group consisting of a primary alcohol and a secondary alcohol having from 1-3 carbon atoms.

4. The method recited in claim 2 wherein the solvent comprises a member of the group consisting of (1) a mixture of methyl ehtyl ketone with isopropanol and (2) methanol.

5. The method recited in claim 1 wherein said silver-pyridine complex is formed by dissolving a silver salt in pyridine.

6. The method recited in claim 5 wherein said silver salt is silver nitrate.

7. The method recited in claim 1 wherein the substrate is an organic polymer.

8. The method recited in claim 7 wherein the substrate is a polymer selected from the group consisting of polyamides and vinyls.

9. The method recited in claim 8 wherein the substrate is selected from the group consisting of nylon and polyvinyl chloride.

10. The method recited in claim 1 wherein said basic solution is non-aqueous and is an alkaline metal hydroxide in an alcohol solvent having from 1-3 carbon atoms.

11. The method recited in claim 10 wherein the alkaline metal hydroxide is selected from NaOH and KOH and the alcohol comprises a member of the group consisting of ethyl alcohol, methanol, propanol, isopropanol, and a mixture of the foregoing alcohols.

12. The method recited in claim 1 wherein the silver oxide is reduced to metallic silver by heating at a temperature greater than 100°

C. but less than the temperature at which the substrate melts or decomposes.

13. The method recited in claim 1 wherein the silver oxide is reduced by treating with a chemical reducing agent.

14. The method as recited in claim 13 wherein the chemical reducing agent is hydrazine.

15. The method as recited in claim 13 wherein the chemical reducing agent comprises a reducing gas selected from the group consisting of CO, H₂ and a mixture thereof.

16. The method as recited in claim 1 wherein the substrate is a continuous, non-twisted, fiber bundle.

17. The method as recited in claim 16 wherein the drying temperature is lower than the temperature at which the fibers adhere to each other.

18. The method recited in claim 1 wherein the substrate comprises a nylon textile yarn.

19. The method recited in claim 18 wherein the substrate is dried at a temperature between 104°

to 115°

C.

20. The method recited in claim 19 wherein said silver oxide is reduced to metallic silver by heating.

23. The method recited in claims 1 or 21 including the step of subjecting the metallic silver layered substrate to electroless plating.

24. The method recited in claim 23 including the step of electroplating a metal onto the substrate.

21. A method of spontaneously plating a continuous, reflective layer of silver on a substrate comprising the steps of:

(a) coating the substrate with a solution comprising a silver-pyridine complex dissolved in a non-aqueous solvent;

(b) drying the substrate; and

(c) immersing the substrate in a basic solution, whereby the silver-pyridine complex is directly converted to a continuous reflective silver layer.

22. A method as recited in claim 21 wherein said substrate is copper.

25. A method of making an insulated conductor comprising the steps of;

(a) immersing a substrate, selected from the group consisting of a continuous, dielectric fiber bundle, in a solution comprising a silver-pyridine complex dissolved in a non-aqueous solent;

(b) drying the fiber bundle;

(c) immersing the fiber bundle in a basic solution whereby the silver-pyridine complex is converted to a silver oxide;

27. The method recited in claim 25 wherein the substrate consists of a continuous non-twisted dielectric fiber bundle and including the step of twisting the fiber bundle subsequent to electroplating and prior to insulating.

28. The method recited in claim 25 wherein the fiber bundle is an organic polymer.

29. The method recited in claim 25 wherein the polymer is selected from the group consisting of polyamides and vinyls.

30. The method recited in claim 25 wherein the polymer is selected from the group consisting of nylon and polyvinyl chloride.

32. The method recited in claims 25 or 30 wherein a plurality of insulated conductors are twisted, and a polymer jacket is formed over the plurality of insulated conductors to form a conductive cord.

26. (d) reducing the silver oxide to metallic silver;

(e) electroless plating the fiber bundle;

(f) electroplating the fiber bundle; and

(g) insulting the fiber bundle.

31. A method of making an insulated conductor comprising the steps of:

(a) coating a continuous length of non-twisted nylon yarn with a solution comprising a silver-pyridine complex dissolved inl a non-aqueous solvent,

(b) drying the yarn at between 102°

to 114°

C.,

(c) converting the silver-pyridine complex to silver oxide by treating with a basic solution,

(d) reducing the silver oxide to metallic silver by heating at a temperature from about 165°

to 170°

C.,

(e) electroless plating the yarn with a conductive metal,

(f) electroplating the yarn with a conductive metal,

(g) twisting the plated yarn, and

(h) insulating the twisted yarn.