Method and composition for testing for the presence of an alkali metal

• US 4,244,693 A
• Filed: 02/28/1977
• Issued: 01/13/1981
• Est. Priority Date: 02/28/1977
• Status: Expired due to Term

• Current Assignee: United States Department of Energy (Government of the United States of America)
• Original Assignee: United States Department of Energy (Government of the United States of America)
• Inventors: Guon, Jerold
• Primary Examiner(s): Reese, Robert M.
• Application Number:
  US05/772,627
• Time in Patent Office: 1,415 Days
• Field of Search: 23/230 L, 23/230 R, 252/408 R
• US Class Current: 436/5
• CPC Class Codes: G01N 31/22 using chemical indicators G01N31/02 takes precedence
• CPC Class Codes: G01N 33/2028 Metallic constituents
• CPC Class Codes: G01N 33/208 Coatings, e.g. platings

Abstract

A method and composition for detecting the presence of an alkali metal on the surface of a body such as a metal plate, tank, pipe or the like is provided. The method comprises contacting the surface with a thin film of a liquid composition comprising a light-colored pigment, an acid-base indicator, and a nonionic wetting agent dispersed in a liquid carrier comprising a minor amount of water and a major amount of an organic solvent selected from the group consisting of the lower aliphatic alcohols, ketones and ethers. Any alkali metal present on the surface in elemental form or as an alkali metal hydroxide or alkali metal carbonate will react with the acid-base indicator to produce a contrasting color change in the thin film, which is readily discernible by visual observation or automatic techniques.

Claims

1. A liquid composition for detecting the presence of an alkali metal on the surface of a body comprising:

a light-colored pigment, an acid-base indicator, and a nonionic wetting agent dispersed in a liquid carrier which comprises a minor amount of water and a major amount of an organic solvent selected from the group consisting of lower aliphatic alcohols, ketones and ethers.

2. The composition of claim 1 wherein said acid-base indicator is one which undergoes a color change at a pH of between about 4 and 11.

3. The liquid composition of claim 1 wherein said organic solvent is selected from the group consisting of alcohols and ketones containing from 1 to 3 carbon atoms and ethers containing from 1 to 5 carbon atoms, and said organic solvent is present in said liquid carrier in an amount to provide a solvent-to-water ratio within the range from about 2:

1 to 10;

1.

4. The liquid composition of claim 1 wherein said light-colored pigment is talc.

5. A method for detecting the presence of an alkali metal on the surface of a body comprising:

applying to said surface a thin film of a liquid composition comprising a light-colored pigment, an acid-base indicator and a nonionic wetting agent dispersed in a liquid carrier which comprises a minor amount of water and a major amount of an organic solvent selected from the group consisting of lower aliphatic alcohols, ketones and ethers, whereby any alkali metal present on the surface will react with the acid-base indicator to produce a contrasting color change in the thin film which is readily discernable.

6. The method of claim 5 wherein said organic solvent is selected from the group consisting of alcohols and ketones containing from 1 to 3 carbon atoms and ethers containing from 1 to 5 carbon atoms, and said organic solvent is present in said liquid carrier in an amount to provide a solvent-to-water ratio within the range of from about 2:

1 to 10;

1.

7. The method of claim 5 wherein said light-colored pigment is talc.

8. The method of claim 5 wherein said acid-base indicator is one which undergoes a color change at a pH of between about 7 and 9.

9. The method of claim 8 wherein said acid-base indicator is phenol red.