Mineral accretion of large surface structures, building components and elements

• US 4,246,075 A
• Filed: 03/19/1979
• Issued: 01/20/1981
• Est. Priority Date: 03/19/1979
• Status: Expired due to Term

• Current Assignee: Marine Resources Incorporated
• Original Assignee: Marine Resources Incorporated
• Inventors: Hilbertz, Wolf H.
• Primary Examiner(s): Tufariello, T. M.
• Application Number:
  US06/021,844
• Time in Patent Office: 673 Days
• Field of Search: 204/23, 204/56 R, 204/145 R, 204/24, 204/25, 204/26, 204/27, 204/1 R
• US Class Current: 205/107
• CPC Class Codes: C04B 28/00 Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
• CPC Class Codes: C04B 32/00 Artificial stone not provided for in other groups of this subclass
• CPC Class Codes: C25B 1/00 Electrolytic production of inorganic compounds or non-metals
• CPC Class Codes: C25D 9/08 by cathodic processes

Abstract

By establishing a direct electrical current between electrodes in an electrolyte like seawater, calcium carbonates, magnesium hydroxides, and hydrogen are precipitated at the cathode, while at the anode, oxygen and chlorine are produced. The electrodeposition of minerals is utilized to construct large surface area (i.e. greater than 100 square feet) structures, building components and elements of a hard, strong material (i.e. 1000-8000 P.S.I. compression strength). To make a large surface area structure, building component or element of hard, strong material, a preshaped form of electrically conductive material is disposed in a volume of electrolyte, such as seawater, to serve as a cathode, one or more are anodes disposed in proximity to the form, and a direct electrical current is established between the electrodes for a period of time sufficient to accrete a solid covering of material on the form.

Claims

1. A method for constructing a large surface area building component, comprising the steps of:

disposing a large surface area preshaped substrate form having inner and outer surfaces in a volume of electrolyte, said form serving as a cathode;

disposing an anode in the electrolyte in proximity to the preshaped form; and

establishing a direct electrical current between the cathode and the anode for a time sufficient for accreting a solid mass of high strength electrodeposited mineral material surrounding the form and covering the inner and outer surfaces to a desired thickness, such that the form becomes embedded within the accreted material.

2. The method of claim 1 wherein the electrical current density is 1-15000 mA/sq.ft.

3. The method of claim 1 wherein the electric field potential between the electrodes is 1-30,000 volts.

4. The method of claim 1 wherein the electrolyte is a mineral containing liquid.

5. The method of claim 1 wherein the preshaped form is at least partially of an electrically conductive material.

6. A large surface area building component of a hard, strong material made by:

disposing a large surface area form shaped in the configuration desired for the large surface area building component and having inner and outer surfaces in a volume of electrolyte, said form serving as a cathode;

disposing an anode in the electrolyte in proximity to the shaped form; and

establishing a direct electrical current between the shaped cathodic form and the anode for a time sufficient to accrete a mass of electrodeposited mineral material that surrounds the shaped form and covers the inner and outer surfaces to a desired thickness such that the form becomes embedded therein.

7. The component of claim 6 wherein the form is at least partially an electrically conductive material.

8. A large surface area building component of a hard strong material made by:

disposing a large surface area form of nonstructural material having inner and outer surfaces and shaped in the configuration desired for the large building component in a volume conductive and serving as a cathode;

disposing an anode in the electrolyte in proximity to the shaped form; and

establishing a direct electrical current between the electrodes for a time sufficient to accrete a solid mass of high strength electrodeposited mineral material covering the inner and outer surfaces to a desired thickness, the electrical current being of a density of 1-15,000 mA/sq.ft. with an electric field potential between the electrodes of 1-30,000 volts.

9. A method of constructing a large surface area building component, which comprises the step of accreting a hard, strong material on a preshaped form having inner and outer surfaces by electrodeposition of minerals, the accreted material covering the inner and outer surfaces to a desired thickness.

10. A method of constructing a large surface area building component, which comprises the step of covering a non-structural preshaped form having inner and outer surfaces with a hard, strong material through an electrodeposition process, the inner and outer surfaces of the form being covered to a desired thickness of the material.

11. A method of constructing a large surface area building component, which comprises the step of covering a non-structural preshaped form having inner and outer surfaces with a hard, strong material of high structural integrity made by:

disposing the large surface area preshaped form in a volume of electrolyte, said form serving as a cathode;

disposing an anode in the electrolyte in proximity to the preshaped form; and

establishing a direct electrical current between the cathode and the anode for a time sufficient to accrete the solid covering of material on the inner and outer surfaces of the form.

12. A method of constructing a large surface area building component, comprising the steps of:

disposing a large surface area preshaped form having inner and outer surfaces in a volume of electrolyte, said form serving as a cathode;

disposing an anode in the electrolyte in proximity to the preshaped form;

establishing a direct electrical current between the cathode and the anode for a period of time sufficient to accrete a layer of high strength material on the inner and outer surfaces of the form;

discontinuing the electrical current between the cathode and anode for a period of time; and

re-establishing direct electrical current between the cathode and anode.

13. The method of claim 12 wherein the steps of interrupting current between the cathode and anode and re-establishing a current between the cathode and anode is repeated a multiplicity of times until a solid covering of accreted material of desired thickness and composition is formed on the inner and outer surfaces of the large surface area preshaped form.

14. A method of constructing a large surface area building component, comprising the steps of:

disposing a large surface area preshaped form having inner and outer surfaces in a volume of electrolyte, said form serving as an electrode;

disposing a second electrode in the electrolyte in proximity to the preshaped form;

establishing a direct electrical current between the electrodes in one direction for a period of time;

switching the polarity of the electrical current between the electrodes to establish a direct electrical current between the electrodes in an opposite direction; and

re-establishing the original polarity of direct electrical current between the electrodes, thereby accreting a solid mass of mineral of a desired thickness on the inner and outer surfaces of the form.

15. A method of constructing a large surface area building component, comprising steps:

disposing a large surface area preshaped form having inner and outer surfaces in a volume of electrolyte, said form serving as a cathode;

disposing an anode in the electrolyte in proximity to the preshaped form;

establishing a direct electrical current between the cathode and anode; and

varying the electrical current density of the electrical current to accrete a solid covering of mineral material of a desired thickness and composition on the inner and outer surfaces of the form.