Rapid curing of epoxy resin coating compositions by combination of photoinitiation and controlled heat application

• US 4,246,298 A
• Filed: 03/14/1979
• Issued: 01/20/1981
• Est. Priority Date: 03/14/1979
• Status: Expired due to Term

• Current Assignee: American Can Co (Citigroup Incorporated)
• Original Assignee: American Can Co (Citigroup Incorporated)
• Inventors: Watt, William R., Guarnery, Joseph M.
• Primary Examiner(s): Newsome, John H.
• Application Number:
  US06/020,515
• Time in Patent Office: 678 Days
• Field of Search: 427/54, 427/45, 427/46, 427/55, 427/386, 204/159.11, 528/89
• US Class Current: 427/493
• CPC Class Codes: C08G 59/18 Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
• CPC Class Codes: C08J 2363/00 Characterised by the use of epoxy resins; Derivatives of epoxy resins
• CPC Class Codes: C08J 3/24 Crosslinking, e.g. vulcanising, of macromolecules mechanical aspects B29C35/00; crosslinking agents C08K
• CPC Class Codes: C09D 163/00 Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins

Abstract

A method for the high speed coating of various substrates utilizes an epoxy composition containing a radiation-sensitive catalyst precursor which will decompose upon exposure to electromagnetic radiation to provide a Lewis acid effective to induce cationic polymerization of the epoxy composition. The formulation does not require any special epoxy monomeric materials or accelerators and is stable until so exposed. Subsequent to applying the formulation to the substrate, the coating is exposed to electromagnetic radiation and a controlled temperature of 50°-90° C. is maintained in the coating for a limited period of time to effect polymerization of the formulation to a tack free surface condition within a period of less than 30 seconds. Maintenance at the elevated temperature following initiation of irradiation may be for a period of as little as 0.5 second.

Claims

1. In a method for coating substrates with an epoxy coating material to develop a tack-free surface condition in relatively short periods of time, the steps comprising:

A. applying to a substrate a fluid coating of a polymerizable composition comprising at least one epoxidic prepolymer material polymerizable to a higher molecular weight at which it is tack-free and up to 5 percent by weight of said polymerizable composition of a radiation-sensitive catalyst precursor which decomposes upon exposure to electromagnetic radiation to provide a Lewis acid effective to initiate polymerization of said epoxidic prepolymer material, said catalyst precursor being ineffective to cure said epoxidic prepolymer material to a tack-free surface condition at ambient temperatures in a period of two minutes following exposure to radiation to effect decomposition thereof, said epoxidic prepolymer material containing less than about 15 percent by weight thereof of epoxidic prepolymer material having two epoxycycloalkyl groups per molecule;

B. exposing said coating to said electromagnetic radiation to effect decomposition of said catalyst precursor and thereby generate a Lewis acid; and

C. maintaining said coating at a temperature of about 50°

-90°

C. for a period of at least about 0.5 second and less than about 2 minutes following initiation of said exposure to radiation to effect polymerization to a substantially tack-free surface condition in a period of less than 30 seconds following the combination of said steps of radiation exposure and temperature maintenance.

2. The method in accordance with claim 1 wherein said epoxidic prepolymer material is substantially free from epoxidic prepolymer material having two epoxycycloalkyl groups.

3. The method in accordance with claim 1 wherein said epoxidic prepolymer material is a glycidyl ether of an aromatic alcohol.

4. The method in accordance with claim 1 wherein said epoxidic prepolymer material is the reaction product of bis-phenol A and epichlorohydrin.

5. The method in accordance with claim 1 wherein the amount of said catalyst precursor is not more than 3 percent of said polymerizable composition.

6. The method in accordance with claim 1 wherein said catalyst precursor is an aromatic onium salt selected from the group consisting of onium salts of group Va elements, onium salts of group VIa elements, and halonium salts.

7. The method in accordance with claim 1 wherein said catalyst precursor is an aromatic diazonium salt.

8. The method in accordance with claim 1 wherein said substrate is metallic and heating of said coating to said temperature is effected by induction heating of said substrate.

9. The method in accordance with claim 1 wherein the heating of said coating to said temperature is effected by conduction of heat through said substrate.

10. The method in accordance with claim 1 wherein the heating of said coating to said temperature is effected by infrared radiation directed upon said coating.

11. The method in accordance with claim 1 wherein said electromagnetic radiation comprises ultraviolet radiation.

12. The method in accordance with claim 1 wherein said polymerization of said coating to a substantially tack-free surface condition occurs in a period of less than five seconds.

13. The method in accordance with claim 1 wherein said temperature at which said coating is maintained is within the range of 55°

-75°

C.

14. The method in accordance with claim 1 wherein said coating is maintained at said temperature for a period of less than about ten seconds following said initiation of said exposure to said radiation.