Consumable replaceable anodes for batteries

• US 4,246,324 A
• Filed: 04/09/1979
• Issued: 01/20/1981
• Est. Priority Date: 04/09/1979
• Status: Expired due to Term

• Current Assignee: Electrode Corporation
• Original Assignee: Diamond Shamrock Technologies SA
• Inventors: de Nora, Vittorio, Spaziante, Placido M.
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US06/028,364
• Time in Patent Office: 652 Days
• Field of Search: 429/17, 429/27, 429/34, 429/38, 429/39, 429/210, 429/12, 429/19, 429/96
• US Class Current: 429/406
• CPC Class Codes: H01M 12/065 with plate-like electrodes or stacks of plate-like electrodes
• CPC Class Codes: H01M 2004/024 Insertable electrodes
• CPC Class Codes: H01M 2004/8689 Positive electrodes
• CPC Class Codes: H01M 4/8626 characterised by the form
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A battery comprising an inert container housing a plurality of corrosion resistant gas depolarized metal cathode elements in hollow box-like form and consumable anode elements in spaced relationship with said cathode elements. At least one wall of each cathode element has a gas-permeable porous cathode formed of sintered particles impregnated with a catalyst and, on the inside, with a hydrophobic resin. The consumable anode elements are mounted on non-consumable metal supports so as to be removable (with or without their supports) and replaceable in the container. In operation, depolarizing gas is fed inside the cathode elements and an electrolyte is maintained between the facing cathodes and anodes.

Claims

1. A battery comprising an inert container, housing a plurality of hollow, box-like cathode elements and consumable metal anode elements in spaced relationship, each of said box-like cathode elements having at least one gas-permeable, porous cathode in at least one wall and at least one consumable metal anode separate from and removably supported opposite said gas-permeable, porous cathode, and cathode and anode of adjacent elements being disposed in spaced facing relationship;

means to maintain an electrolyte in the spaces between the cathodes and anodes;

means to feed a depolarizing gas through the interior of said box-like cathode elements to the porous cathodes;

means for collecting precipitated material below said anode and cathode elements, and means to electrically connect said cathode and anode elements to an external load, said anode elements being removable and reinsertable in said container.

3. The battery of claim 1 in which there is a gas-permeable cathode in both the front and back walls of said hollow, box-like cathode elements, and each anode element comprises consumable metal anodes mounted on opposite sides of a non-consumable metal anode support plate, said non-consumable anode support plates being removable and reinsertable in said container.

5. The battery of claims 1, 2, 3 or 4 in which said container has means in which the hollow box-like cathode elements are slidably received.

6. The battery of claim 3 in which said container has means into which said non-consumable metal anode support plates are slidably received.

7. The battery of claims 1, 2 or 3 in which the porous cathodes comprises a layer of sintered metal particles.

8. The battery of claim 1 in which each hollow box-like element is a bipolar element having a plurality of hollow pervious cathode fingers protruding from one wall and communicating with the interior of said element, and an impervious opposite wall having a plurality of consumable metal anodes removably supported thereon.

9. The battery of claim 8 in which said opposite wall has a plurality of consumable metal anodes projecting at substantially right angles therefrom.

2. A battery comprising an inert container, housing a plurality of hollow, box-like cathode elements and consumable metal anode elements in spaced relationship, each of said box-like cathode elements having at least one gas-permeable, porous cathode in at least one wall and at least one consumable metal anode separate from and removably supported opposite said gas-permeable, porous cathode, the cathode and anode of adjacent elements being disposed in spaced facing relationship;

means to maintain an electrolyte in the spaces between the cathodes and anodes;

means to feed a depolarizing gas through the interior of said box-like cathode elements to the porous cathodes;

means for collecting precipitated material below said anode and cathode elements, and means to electrically connect said cathode and anode elements to an external load, said anode elements being removable and reinsertable in said container, said gas-permeable, porous cathodes form a substantial part of one wall of said hollow box-like cathode elements, the opposite wall being impervious and having means for removably supporting a generally flat consumable metal anode on said impervious cathode element wall.

4. The battery of claim 2 in which the means for removably supporting the consumable metal anodes on said impervious cathode element wall comprises electrically conductive spring clips disposed adjacent to the edges of said impervious cathode element wall.

10. A battery comprising a plurality of hollow, box-like bipolar elements operatively located between two terminal elements and housed in a slotted, inert container, each of said bipolar elements having a gas-permeable, porous, gas-depolarized cathode in one wall and a consumable metal anode supported, in electrical conducting relationship with the box-like element on the external surface of the other wall of said box-like element, means to maintain an electrolyte in the space between the gas-depolarized cathode of one of said elements and the consumable metal anode of the adjacent element, means to feed a depolarizing gas into the interior of said box-like bipolar elements and into the interior of the terminal cathodic element, and means to connect said terminal elements to an external load.

11. The battery of claim 10 having means to feed a depolarizing gas into the interior of said box-like elements and to remove gas from said elements, and means to control the gas pressure inside said box-like elements.

12. The battery of claim 10 in which said box-like elements are constructed of a valve metal and the gas-depolarized cathode is made of sintered valve metal having a catalyst thereon.

13. The battery of claim 12 in which the inwardly facing side of said gas-depolarized cathode is impregnated with lipophobic (e.g. hydrophobic) resin.

14. The battery of claim 10 in which the hollow, box-like bipolar elements are made of metals from the group consisting of valve metals and nickel, the porous, gas-permeable cathode is made of sintered valve metal or nickel and is activated with catalytic oxides, and the consumable anodes are made of a metal more electropositive than oxygen.

15. A battery comprising an inert container having a plurality of hollow, box-like cathode elements therein, porous, sintered, gas-permeable, depolarized cathodes on both the front and back faces of said box-like cathode elements, a plurality of anode elements each comprising consumable metal anodes mounted on each side of a non-consumable support plate, means for removably mounting the anode elements and support plates in the container whereby the cathodes and anodes of adjacent elements are disposed in facing relationship, means to circulate an electrolyte in the spaces between the cathodes and anodes, means to feed a depolarizing gas through the interior of said box-like cathode elements to the porous cathodes, means to connect said box-like cathode elements together and to a terminal connected to a load, and means to connect said anode support plates together and to a terminal connected to a load.

16. The battery of claim 15 wherein said means for removably supporting said non-consumable support plates comprise spaced slots in the walls of said battery container in which said support plates are slidably mounted.

17. The battery of claim 15 wherein each porous cathode comprises a wall of sintered metal particles impregnated with a catalyst.

18. The battery of claim 17 in which the inner wall of sintered metal particles forming said cathodes has a lipophobic resin thereon from the group consisting of a polypropylene, polychlorofluoroethylene and vinyl resins, and the resin is on the inner surface of said porous cathodes but is not on the outer surface of the particles of said porous, sintered metal cathodes.

19. A battery comprising an insulating casing, a plurality of hollow, box-like corrosion resistant metal cathode elements having pervious cathode walls therein and a plurality of consumable anodes mounted in spaced relationship in said casing, an electrolyte between the anodes and cathodes, non-consumable support plates on which the consumable anodes are mounted, and means whereby said support plates may be removed from said casing when the anodes are substantially consumed, the consumable metal replaced on said anode support plates, and the recoated support plates reinserted in said casing.

20. A gas-depolarized electrochemical cell comprising an insulating cell container, a plurality of cell units in said container, each full cell unit comprising a hollow element for receiving a depolarizing gas, means to introduce and remove gas from said elements, electrolyte chambers between said elements, hollow, porous fingers of controlled porosity extending from a first wall of each element into said electrolyte chambers, said hollow, porous fingers forming the cathodes of said cell units, consumable metal anodes in said electrolyte chambers forming an electrode gap with adjacent hollow, porous cathode fingers, insulating guides on said first walls of said hollow elements between said hollow cathode fingers into which one edge of said consumable metal anodes is inserted, clips of a conducting metal on the opposite walls of the hollow elements making electrical contact with the edges of said consumable anodes opposite said insulating guides, an electrolyte in said electrolyte chambers, and means to pass a depolarizing gas through said hollow elements into said hollow, porous cathode fingers.

21. The cell of claim 20 in which a half-cell unit at each end of said container has negative and positive terminals connecting the cell to an external load.

22. The cell of claim 20 in which the means to introduce and remove depolarizing gas from said elements is provided with means to maintain the gas in said elements at a substantially constant superatmospheric pressure.

23. The method of operating an electrochemical cell comprising a slotted container having hollow, box-like, metal cathode elements carrying porous, oxygen-reducing cathodes on at least one side of said box-like elements and consumable anodes removably mounted on non-consumable supports opposite said oxygen-reducing cathodes, an electrolyte in the spaces between said anodes and said oxygen-reducing cathodes;

means to circulate a depolarizing gas through said cathode elements and means to supply an electrolyte to said cell, which comprises discharging current from said cell until one or more of said anodes are substantially consumed, draining said electrolyte and consumed anode material from said container, removing the remaining parts of the consumable anodes from said container, replacing the consumed anodes with new anodes and reintroducing an electrolyte into said container.

24. The method of claim 23 in which the cathode elements are a non-consumable metal from the group consisting of valve metals and nickel, the oxygen-reducing cathode is porous, sintered valve metal or nickel, and the anode is zinc and is removably attached to one side of each of said box-like cathode elements.

25. As a product of manufacture, a bipolar element for a battery, comprising a hollow metal box-like structure carrying a porous, oxygen-reducing cathode on one side of said box-like element and a consumable anode removably mounted on the other side of said box-like bipolar element and means to circulate an oxygen-containing gas through said box-like structure.

26. The product of claim 25 in which the consumable anode is from the group consisting of solid or porous zinc, iron, cadmium, and metalloids and alloys thereof.

27. A battery comprising an inert container, housing a plurality of hollow box-like cathode elements and consumable metal anode elements in spaced relationship between a terminal consumable metal anode element and a terminal hollow cathode element, each of said box-like cathode elements having at least one gas-permeable, porous cathode in at least one wall, and each anode element comprising at least one consumable metal anode mounted on a non-consumable metal support;

means to removably mount at least said consumable metal anodes of the anode elements in the container to permit removal and insertion of the consumable metal anodes in the container;

means to maintain an electrolyte in the spaces between the cathodes and anodes;

means to feed a depolarizing gas through the interior of said hollow cathode elements to the porous cathodes; and

means to connect said terminal elements to an external load.