Battery sensor

• US 4,247,811 A
• Filed: 10/12/1978
• Issued: 01/27/1981
• Est. Priority Date: 10/12/1978
• Status: Expired due to Term

• Current Assignee: Eugene Findl
• Original Assignee: Bioresearch Incorporated
• Inventors: Findl, Eugene
• Primary Examiner(s): Hickey, Robert J.
• Application Number:
  US05/950,554
• Time in Patent Office: 838 Days
• Field of Search: 320/46, 320/48, 320/35, 340/636, 324/29.5, 324/432, 324/437, 429/90-93
• US Class Current: 320/134
• CPC Class Codes: G01R 31/378 specially adapted for the type of battery or accumulator
• CPC Class Codes: H01M 10/48 Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569
• CPC Class Codes: H01M 10/484 for measuring electrolyte level, electrolyte density or electrolyte conductivity
• CPC Class Codes: H01M 2200/10 Temperature sensitive devices
• CPC Class Codes: H01M 6/505 Cells combined with indicating means for external visualization of the condition, e.g. by change of colour or of light intensity
• CPC Class Codes: H02J 7/007188 the charge cycle being controlled or terminated in response to non-electric parameters
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A battery sensor for measuring the state of charge, temperature and electrolyte level of a battery. The state of charge is determined by a concentration cell. The concentration cell comprises an ionic fluid of known concentration separated from the electrolyte by an ionically porous plug. When a first electrode is placed in the electrolyte and a second electrode is placed in the fluid, a voltage, which is a function of the difference in the concentration of each, is generated so that a state of charge of the electrolyte may be determined. Temperature determination is made by positioning thermistors above the electrolyte thereby measuring the gas temperature over the aqueous electrolyte. By positioning one of the thermistors in contact with a catalyst for recombining the gaseous hydrogen, produced by a fully charged battery, with oxygen, sensing means are established for indicating an overcharge situation. The porous plug is positioned at the minimum safety level for the electrolyte such that when the electrolyte falls below the minimum level, the concentration cell voltage between the two electrodes becomes erratic and can be used to activate a warning signal. The sensor is constructed such that the sensing apparatus and voltage generating device can be contained within a battery cap.

Claims

1. A battery sensor for measuring the state of charge, temperature, and electrolyte level of a battery comprising:

a first electrode positioned at a minimum safety level in the electrolyte of the battery;

an ionic fluid of known concentration in a reservoir;

a second electrode immersed in the ionic fluid;

an ionically porous plug positioned at a minimum safety level in the electrolyte, said porous plug separating the electrolyte and the ionic fluid and being in contact with both fluids and a voltage being generated between said electrodes which is a function of the difference in concentration between the electrolyte and ionic fluid so as to determine the state of charge of the battery;

a first thermistor positioned above the electrolyte adapted to measure the temperature of the battery; and

a second thermistor connected to the first thermistor to form a thermistor pair, one of said thermistors being in contact with a catalyst, used as a reaction surface, for promoting the heat-producing recombination of gaseous hydrogen and oxygen evolved by recharging a full or nearly fully charged battery, whereby a temperature differential between the first and second thermistors produces an electrical output signal.

3. The battery sensor described in claim 1 wherein the thermistor, electrodes, and porous plug are disposed within a battery cap.

8. The battery sensor described in claim 1 wherein the thermistor pair, electrodes, and porous plug are disposed within a battery cap.

10. The battery sensor described in claim 1 wherein said thermistor activates a switch for controlling the charge or discharge of the battery to prevent battery overheating.

2. A battery sensor for measuring the state of charge, temperature, and electrolyte level of a battery comprising:

a first electrode positioned at a minimum safety level in the electrolyte of the battery;

an ionic fluid of known concentration in a reservoir;

a second electrode immersed in the ionic fluid;

an ionically porous plug positioned at a minimum safety level in the electrolyte, said porous plug separating the electrolyte and the ionic fluid and being in contact with both fluids and a voltage being generated between said electrodes which is a function of the difference in concentration between the electrolyte and ionic fluid so as to determine the state of charge of the battery;

at least one thermistor positioned above the electrolyte adapted to measure the temperature of the battery; and

means associated with said first electrode for detecting an erratic voltage produced when the electrolyte falls below the minimum safety level so as to monitor the electrolyte level, said sensor further including means responsive to an input signal from said thermistor for compensating for potential changes due to temperature changes.

4. The battery sensor described in claim 2 wherein said ionic fluid is a gel.

5. The battery sensor described in claim 2 wherein said electrolyte and said ionic fluid are both H₂ SO₄.

6. The battery sensor described in claim 2 wherein said catalyst is composed of a noble metal or mixture of noble metals.

7. The battery sensor described in claim 2 wherein the thermistor pair activates a switch for controlling a battery charging process when the battery is nearing or at full charge.

9. The battery sensor described in claim 2 wherein said electrolyte and said ionic fluid are both KOH.