Oxygen pulping with recycled liquor

• US 4,248,662 A
• Filed: 01/22/1979
• Issued: 02/03/1981
• Est. Priority Date: 01/22/1979
• Status: Expired due to Term

• Current Assignee: Bank One Insurance Holdings Incorporated (JP Morgan Chase & Co)
• Original Assignee: The Black Clawson Company
• Inventors: Wallick, Scott A.
• Primary Examiner(s): Smith, William F.
• Application Number:
  US06/005,354
• Time in Patent Office: 743 Days
• Field of Search: 162/65, 162/25, 162/19, 162/29, 162/41, 162/45, 162/38, 162/80, 162/32, 162/40
• US Class Current: 162/19
• CPC Class Codes: D21C 3/026 in presence of O2, e.g. air
• CPC Class Codes: D21C 3/222 Use of compounds accelerating the pulping processes
• CPC Class Codes: D21C 7/14 Means for circulating the lye

Abstract

Fibrous material is pre-steamed, impregnated with alkali liquor, refined, and then oxygen pulped at a low consistency (about 3 to 8 percent solids) using an alkali liquor which contains boron compounds. The pulping step of the process is carried out in stages with recycle of liquor to preceding stages after it has been reoxygenated. By recycling a major portion of the pulping liquor, the actual liquor to fibrous material ratio at each stage of the pulping step is maintained at a relatively high level (12/1 to 30/1) while the effective liquor to fibrous material ratio for the overall process is much lower (4/1 to 8/1). This results in a bright pulp of acceptable strength as well as a high solids content spent liquor which is economically recoverable.

Claims

1. A process for the oxygen delignification of wood chips comprising the steps of:

subjecting the wood chips to steam for a time sufficient to form a softened fibrous material,

refining said softened fibrous material to form a refined material,

delignifying said refined material at a consistency of about 3 to about 8% solids content in the presence of oxygen and an alkali liquor containing sodium tetraborate in a plurality of stages in which a major portion of partially spent alkali liquor from each stage is recycled to the next preceding deliqnification stage.

2. The process of claim 1 including the step of impregnating said softened fibrous material with an alkali material containing sodium tetraborate prior to said refining step.

3. The process of claim 2, where the partially spent alkali liquor is reoxygenated prior to being recycled.

4. The process of claim 3, where fresh alkali liquor containing said alkali materials is continuously added to the final delignification stage and spent alkali liquor is continuously withdrawn from the first delignification stage.

5. The process of claims 2 or 1 wherein said alkali material is at a dosage of from about 3 to about 150 percent by weight of the boron-containing compound based on the initial dry weight of said wood chips.

6. The process of claim 5, where the alkali liquor comprises an aqueous solution of said alkali materials compounds at a dosage of 60 percent by weight based on the initial dry weight of said wood chips.

7. The process of claim 6, where the impregnation step is carried out at from 90°

to 200°

C. for 3 to 10 minutes.

8. The process of claim 7, where the delignification step is carried out at 120°

to 180°

C. at a total oxygen pressure of 50 to 275 psi.

9. The process of claim 1 in which said delignification step includes in digester spraying of recycled alkali liquor over the delignified material.

10. The process of claim 1, including the additional step of in digester dewatering of the delignified material as the last stage of the delignification step.