Process for producing a silicone elastomer emulsion and use thereof

• US 4,248,751 A
• Filed: 08/31/1979
• Issued: 02/03/1981
• Est. Priority Date: 08/31/1979
• Status: Expired due to Term

• Current Assignee: Dow, Inc.
• Original Assignee: Dow, Inc.
• Inventors: Willing, David N.
• Primary Examiner(s): Marquis, Melvyn I.
• Application Number:
  US06/071,459
• Time in Patent Office: 522 Days
• Field of Search: 427/374 R, 427/387, 428/447, 428/452, 260/29.2 M, 528/15, 528/31, 528/32
• US Class Current: 524/588
• CPC Class Codes: C08J 2383/04 Polysiloxanes
• CPC Class Codes: C08J 3/03 in aqueous media
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane

Abstract

A latex of crosslinked silicone is prepared by emulsifying a vinyl endblocked polydiorganosiloxane and an organosilicon compound having silicon-bonded hydrogen atoms with water and surfactant, adding a platinum catalyst and then heating the emulsion to form the latex. Colloidal silica can be added to the latex to provide a product which is tougher. The water in the latex can be evaporated to provide an elastomer film. Coating the latex on a substrate, such as a textile or paper, provides an elastomeric coated substrate, which provides water repellency, insulation and release properties to the substrate.

Claims

1. A process for producing a silicone elastomer emulsion comprising emulsifying

(A) a vinyl endblocked polydiorganosiloxane, and

(B) an organosilicon compound having silicon-bonded hydrogen atoms using water and surfactant to form an emulsion, adding a platinum catalyst, and heating the emulsion forming a latex of crosslinked silicone.

2. A crosslinked silicone latex produced by the method of claim 1.

3. The process in accordance with claim 1 in which a colloidal silica is added to the latex of crosslinked silicone.

4. A crosslinked silicone latex produced by the method of claim 3.

5. The process in accordance with claim 1 in which the vinyl endblocked polydiorganosiloxane (A) is a polydiorganosiloxane terminated by triorganosiloxy groups and having two vinyl radicals per molecule, no silicon atom having more than one vinyl radical bonded thereto, the remaining organic radicals being selected from the group consisting of methyl, ethyl, phenyl and 3,3,3-trifluoropropyl radicals, at least 50 percent of the organic radicals being methyl radicals, and said polydiorganosiloxane having a viscosity of from 0.1 to 100 Pa·

s at 25°

C., and the organo-silicon compound (B) is a mixture of silicon compounds providing from 0.75 to 1.50 silicon-bonded hydrogen atoms per vinyl radical of (A), said mixture (B) consisting essentially of

(1) an organosiloxane compound containing two silicon-bonded hydrogen atoms per molecule and the organic radicals being selected from the group consisting of alkyl radicals having from 1 to 12 carbon atoms inclusive, phenyl and 3,3,3-trifluoropropyl, no silicon atom having bonded thereto more than one silicon-bonded hydrogen atom, and said organosiloxane compound (1) having no more than 500 silicon atoms per molecule, and

(2) an organosiloxane compound containing at least 3 silicon-bonded hydrogen atoms per molecule, the organic radicals being selected from the group consisting of alkyl radicals having from 1 to 12 carbon atoms inclusive, phenyl and 3,3,3-trifluoropropyl radicals, no silicon atom having bonded thereto more than one silicon-bonded hydrogen atom and said organosiloxane compound (2) having no more than 75 silicon atoms per molecule, said mixture (B) being such that at least 10 percent of the silicon-bonded hydrogen atoms are derived from (1) and at least 10 percent of the silicon-bonded hydrogen atoms are derived from (2), (1) and (2) composing 100 weight percent of mixture (B).

6. A crosslinked silicone latex produced by the method of claim 5.

7. The process in accordance with claim 5 in which a colloidal silica is added to the latex of crosslinked silicone.

8. A process in which a crosslinked silicone latex is produced in accordance with claim 1 and thereafter the water is evaporated from the crosslinked silicone latex to form an elastomeric film.

9. The process in accordance with claim 8 in which the latex is coated on a substrate before evaporating the water.

10. A process in which a crosslinked silicone latex is produced in accordance with claim 5 and thereafter the water is evaporated from the crosslinked silicone latex to form an elastomeric film.

11. The process in accordance with claim 10 in which the latex is coated on a substrate before evaporating the water.

12. A process in which a crosslinked silicone latex is produced in accordance with claim 7 and thereafter the water is evaporated from the crosslinked silicone latex to form an elastomeric film.

13. The process in accordance with claim 12 in which the latex is coated on a substrate before evaporating the water.

14. The process in accordance with claim 13 in which the substrate is a textile.

15. The process in accordance with claim 14 in which the substrate is paper.