Radiant energy systems, memories and thermal imaging methods and apparatus

• US 4,250,384 A
• Filed: 08/24/1979
• Issued: 02/10/1981
• Est. Priority Date: 08/24/1979
• Status: Expired due to Term

• Current Assignee: Charles F. Pulvari
• Original Assignee: Charles F. Pulvari
• Inventors: Pulvari, Charles F.
• Primary Examiner(s): Sebastian, Leland A.
• Application Number:
  US06/069,477
• Time in Patent Office: 536 Days
• Field of Search: 136/206, 136/213, 136/214, 250/330, 250/338, 252/629, 307/401, 322/2 R
• US Class Current: 250/330
• CPC Class Codes: H10N 15/10 Thermoelectric devices using thermal change of the dielectric constant, e.g. working above and below the Curie point
• CPC Class Codes: H10N 19/00 Integrated devices, or assemblies of multiple devices, comprising at least one thermoelectric or thermomagnetic element covered by groups H10N10/00 - H10N15/00

Abstract

A very thin insulator having a dipole structure such as a dielectric material having ferroelectric properties and, preferably, also having thermodielectric properties, is used as the insulator insulating an electrode of an electrode pair from a semiconductor body sandwiched between said electrode pair. The utilization of the charge storage and transfer ability serves as a large scale memory device. Radiation detection and solar energy conversion systems based on establishment of an inversion layer by the bound charge of thermodielectric layer or an electret and irradiation of the semiconductor to separate the electron-hole pair and subsequent collection of minority carriers. Since there is no physical junction, the voltage is high, and can be an alternating current voltage which can be transformed. In one embodiment the dielectric material exhibiting thermodielectric properties provides the bound charge and is used in a thermal imaging system. In such system a matrix or mosaic of charged thermodielectric capacitors biased to near the Curie temperature, are exposed to a source of infrared to be detected. Such mosaic of thermodielectric capacitors is used to convert the IR image to electrical signals.

Claims

1. A radiant energy sensing element comprising a semiconductor capacitor having a semiconductor body member and at least one pair of electrodes and a second capacitor including a dielectric having a polarizable remanent dipole structure coupled to said semiconductor capacitor in such a way that an inversion layer is formed in said semiconductor body member, which when irradiated separates the electron /e/-hole/h/ pairs and collects the mobile carriers in the inversion layer.

2. The radiant energy sensing element defined in claim 1 wherein said second capacitor has thermodielectric properties.

3. A thermal imaging system comprising, a matrix of the radiant energy sensing elements defined in claim 2 and means for exposing said matrix to a thermal image, and means for scanning said elements to detect the portion of said thermal image at each of said elements, respectively.

4. Radiation detector comprising a semiconductor capacitor having a semiconductor body member and at least one pair of electrodes and a second capacitor coupled to said semiconductor capacitor in such a way that an inversion layer is formed in said semiconductor body member, which when irradiated generates the electron /e/-hole/h/ pairs and collects the mobile carriers in the depletion layer.

5. Radiation detector as defined in claim 4 characterized by a metal oxide semiconductor (MOS) capacitor with at least one pair of electrodes biased so as to establish said inversion layer.

6. Radiation detector as defined in claim 4 wherein one of the electrodes is transparent to the radiation to be detected.

7. Radiation detector as defined in claim 5 wherein said second capacitor include a ferroelectric pyroelectric capacitor interconnected with said MOS capacitor in such a way that when said MOS ferroelectric double capacitor is irradiated, the pyroelectric generated potential biases said MOS capacitor.

8. Radiation detector as defined in claim 5 wherein said bias source includes a ferroelectric thermodielectric capacitor interconnected with said MOS capacitor in such a way that when the MOS-ferroelectric double capacitor thus constituted is irradiated, the thermodielectrically generated potentital biases the MOS capacitor to produce said depletion layer.

9. Radiation detector as defined in claim 5 wherein said second capacitor is a ferroelectric capacitor and one of the electrodes on the ferroelectric capacitor is transparent to the radiation to be detected, and consists of two joint electrodes one of which is shared with said MOS capacitor while the other is shared with said ferroelectric capacitor.

10. Radiation detector as defined in claim 5 wherein said second capacitor is a ferroelectric capacitor and one of the electrodes of both said MOS capacitor and said ferroelectric capacitor is transparent to the radiation to be detected.

11. In a method of converting solar energy to electrical energy comprising establishing an inversion layer in a semiconductor body by applying a bias potential to a pair of electrodes one of which is insulated from said semiconductor body, subjecting said inversion layer to solar energy to generate the electron /e/--hole /h/ pairs, and collecting the minority carriers, the improvement wherein the bias potential applied to said pair of electrodes is generated in situ by solar to electrical energy conversion.

12. The invention defined in claim 11 wherein said bias potential is generated by a thermodielectric capacitor element.

13. The invention defined in claim 11 wherein said bias potential is generated by a pyroelectric capacitor element.

14. The invention defined in claim 11 wherein there is established a plurality (n) of said inversion layers in a common semiconductor body being subjected to a portion of the solar energy being converted to generate the electron-e/-hole/h/ pairs in each portion of the semiconductor commonly collecting said charge carriers from all said charged layers.

15. The invention defined in claim 14 wherein each of said inversion layers being formed by a MOS capacitor at the site of each semiconductor capacitor, generating a bias potential unique to each site by a further solar to electrical energy converter.

16. The invention defined in claim 15 wherein each said further solar to electrical energy converters is constituted by a thermodielectric capacitor element.

17. The invention defined in claim 14 wherein each step of commonly collecting said minority carriers includes scanning of each semiconductor capacitor and collecting the charge carriers at each capacitor site in said common semiconductor body.

21. The invention defined in any one of claims 17-20 wherein said dielectric material is a plastic co-polymer.

22. The invention defined in claim 21 wherein said copolymer is P(VDF-TFE).

18. A double capacitor comprising a pair of electrodes, a thin dielectric layer and a semiconductor body sandwiched between said pair of electrodes, said dielectric having ferroelectric properties and means for biasing said dielectric layer to near the Curie point thereof.

19. A thermal detector comprising

a pair of electrodes,

a layer of material having thermodielectric properties and a semiconductor layer sandwiched between said pair of electrodes,

means for biasing said layer of material having thermodielectric properties to near its Curie temperature,

voltage supply means for charging the electrodes and said dielectric to a selected potential,

means for exposing said layer to a source of thermal energy to be detected,

and readout means connected to said pair of electrodes.

20. An imaging system comprising

a pair of transversely oriented electrode arrays, at least one of said electrode array being transparent to radiant energy of a selected wave length (IR)

a dielectric means sandwiched between said electrode array, said dielectric means constituted of a dielectric having thermodielectric properties,

means for biasing said dielectric material to its Curie temperature,

means for applying a charging potential to said electrode arrays and said dielectric material,

means for projecting an energy image upon said dielectric material,

and readout means coupled to said electrode arrays for developing an electrical signal for each cross point of said array which is proportional to said energy image imaged upon said dielectric material at each cross point, respectively.

23. A night vision system comprising a pair of transversely oriented electrode arrays,

a thermodielectric material sandwiched between said electrode array,

means for biasing said thermodielectric material to near its Curie temperature,

means for applying a charging potential to said electrodes and said thermodielectric material,

means for focusing a radiant energy image upon said thermodielectric material,

and readout means coupled to said electrode arrays for developing an electrical signal for each cross point of said transversely oriented electrode arrays corresponding to the change in the thermal dielectric property of said thermal dielectric material due to the radiant energy impinging upon said dielectric material at each of the cross points of said transversely oriented electrode arrays, respectively.