Method and apparatus for converting alcohols to hydrocarbons

• US 4,251,484 A
• Filed: 10/30/1979
• Issued: 02/17/1981
• Est. Priority Date: 10/30/1979
• Status: Expired due to Term

• Current Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Original Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Inventors: Haddad, James H., Daviduk, Nicholas
• Primary Examiner(s): Richman, Barry
• Application Number:
  US06/089,705
• Time in Patent Office: 476 Days
• Field of Search: 422/146, 422/147, 422/49, 422/140, 422/143, 422/145
• US Class Current: 422/145
• CPC Class Codes: B01J 2208/00132 Tubes
• CPC Class Codes: B01J 2208/00141 Coils
• CPC Class Codes: B01J 29/08 of the faujasite type, e.g. type X or Y
• CPC Class Codes: B01J 29/18 of the mordenite type
• CPC Class Codes: B01J 29/40 of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
• CPC Class Codes: B01J 29/50 of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
• CPC Class Codes: B01J 29/60 of the type L, as exemplified by patent document US3216789
• CPC Class Codes: B01J 29/65 of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
• CPC Class Codes: B01J 29/70 of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
• CPC Class Codes: B01J 29/7003 A-type
• CPC Class Codes: B01J 29/7011 MAZ-type, e.g. Mazzite, Omega, ZSM-4 or LZ-202
• CPC Class Codes: B01J 8/1809 Controlling processes
• CPC Class Codes: C07C 1/20 starting from organic compounds containing only oxygen atoms as heteroatoms
• CPC Class Codes: C07C 2529/06 Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
• CPC Class Codes: C10G 2300/1022 Fischer-Tropsch products
• CPC Class Codes: C10G 2400/02 Gasoline
• CPC Class Codes: C10G 3/49 containing crystalline aluminosilicates, e.g. molecular sieves
• CPC Class Codes: C10G 3/57 according to the fluidised bed technique
• CPC Class Codes: C10G 3/60 Controlling or regulating the processes
• CPC Class Codes: F28D 13/00 Heat-exchange apparatus using a fluidised bed
• CPC Class Codes: Y02P 30/20 : using bio-feedstock

Abstract

Apparatus and method of utilization for controlling exothermic reactions such as the conversion of methanol to hydrocarbons are discussed. More particularly, the arrangement of apparatus comprising heat exchange tubes and open end baffle tubes for maintaining the hydraulic diameter within restricted limits during contact between vaporous reactant and a fluid bed of catalyst is discussed.

Claims

1. An apparatus for converting lower alcohols to hydrocarbons including gasoline boiling range hydrocarbons which comprises, in combination, an elongated substantially vertical cylindrical reactor vessel, a horizontal grid means positioned across a bottom cross-sectional portion of the vessel above a bottom semicircular closure member of the vessel,

a plurality of vertical heat exchanger tubes positioned within a lower portion of the vessel with the bottom of the tubes spaced vertically above the grid means,

a plurality of vertical open end baffle tubes slotted in the wall thereof throughout substantially the entire length thereof positioned interspersed with and adjacent to said heat exchange tubes and spaced horizontally from one another and from said heat exchange tubes to maintain a reactant hydraulic diameter of less than 24 inches during contact with a fluid mass of catalyst particles, the bottoms of said baffle tubes spaced vertically above said grid means,

conduit means for withdrawing particles of catalyst from the space intermediate the grid means and the bottom of said tubes,

conduit means for adding particles to an upper portion of a bed of fluid catalyst in which said heat exchange means is immersed,

a plurality of cyclone separating means located in an upper portion of said vessel provided with dipleg means extending downward through said vessel and terminating in the space above said grid means,

a plenum chamber in the upper portion of said vessel in open communication with said cyclone separating means and conduit withdrawal means for reaction products connected to the upper portion of said plenum chamber,

an open end conduit means extending from a bottom portion of said vessel beneath said grid means to an upper level of said vessel above said heat exchange and baffle tubes and terminating above the upper interface of a fluid bed of catalyst in the lower portion of the vessel, means for introducing separately controlled gases to the bottom of said open end conduit means,

means for charging reactant to said vessel beneath said grid means for flow upwardly through said vessel.

2. The apparatus of claim 1 wherein the vertical heat exchange tubes and said open end slotted baffle tubes are sized in diameter and horizontally positioned with respect to one another to maintain a hydraulic diameter relationship therein within the range of 4 to 8 inches during contact between vaporous material and fluid particles of catalyst.

3. The apparatus of claim 1 wherein the vertical heat exchange tubes are separated into a plurality of tube bundles which can be separately controlled for flow by liquid therethrough or removal from said vessel.

4. The apparatus of claim 1 wherein the tubes are 4 inch diameter tubes and the axis of the tubes is aligned with the cross marks of a 6 inch grid pattern in the vessel cross-section.

5. The apparatus of claim 1 wherein the tubes are grouped into 36 inch square bundles, each bundle comprising 4 steam tubes and 32 baffle tubes.