Process for removing acidic compounds from gaseous mixtures using a two liquid phase scrubbing solution

• US 4,251,494 A
• Filed: 12/21/1979
• Issued: 02/17/1981
• Est. Priority Date: 12/21/1979
• Status: Expired due to Term

• Current Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Original Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Inventors: Say, Geoffrey R.
• Primary Examiner(s): Thomas, Earl C.
• Application Number:
  US06/106,097
• Time in Patent Office: 424 Days
• Field of Search: 423/228, 423/229, 423/232, 423/234
• US Class Current: 423/228
• CPC Class Codes: B01D 53/1406 Multiple stage absorption
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1475 Removing carbon dioxide
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

An improved process for removing carbon dioxide from a gaseous feed including carbon dioxide is described. The carbon dioxide is removed from a gaseous feed by contacting the feed in a contacting zone with a scrubbing solution comprising a sterically hindered amine and an alkali metal salt or alkali metal hydroxide, which at least partially absorbs the carbon dioxide. The scrubbing solution subsequently is desorbed and separated into a two-phase liquid system, an upper phase relatively rich in sterically hindered amine and having a relatively high ratio of alkali bicarbonate to alkali carbonate and a lower liquid phase having a relatively low ratio of alkali bicarbonate to alkali carbonate. The lower liquid phase is returned to the contacting zone at a location above that at which the upper liquid phase is returned to the contacting zone.

Claims

1. A process for at least partially removing carbon dioxide from a gaseous feed including carbon dioxide comprising:

(a) contacting the gaseous feed in a contacting zone with a scrubbing solution comprising;

(i) an alkaline material selected from the class consisting of alkali metal salts and alkali metal hydroxides; and

(ii) a sterically hindered amine to thereby at least partially absorb the carbon dioxide from the gaseous feed;

(b) passing the scrubbing solution containing the absorbed carbon dioxide from the contacting zone into a regeneration zone wherein the scrubbing solution is at least partially desorbed;

(c) separating the at least partially desorbed scrubbing solution into an upper liquid phase having a relatively high alkali bicarbonate to alkali carbonate ratio and a lower liquid phase having a relatively low alkali bicarbonate to alkali carbonate ratio; and

,

(d) directing at least a portion of the lower liquid phase into the contacting zone at a first location and at least a portion of the upper liquid phase into the contacting zone at a second location, the second location disposed below the first location in the contacting zone.

2. The process of claim 1 wherein the concentration of sterically hindered amine is higher in the upper liquid phase than in the lower liquid phase.

3. The process of claim 1 wherein the contacting zone comprises an absorber, the carbon dioxide being at least partially absorbed in the absorber by the scrubbing solution.

4. The process of claim 3 wherein the regeneration zone comprises a regenerator and reboiler, the scrubbing solution passing from the absorber into the regenerator and from the regenerator into the reboiler, the scrubbing solution being at least partially desorbed in the regenerator and reboiler.

5. The process of claim 4 wherein the separation of the at least partially desorbed scrubbing solution into an upper phase relatively rich in sterically hindered amine and having a relatively high alkali bicarbonate to alkali carbonate ratio and a lower liquid phase having a relatively low alkali bicarbonate to alkali carbonate ratio is effected in the reboiler.

6. The process of claim 5 wherein the sterically hindered amine is selected from the class consisting of N-cyclohexyl-1,3-propanediamine;

1,8-p-methanediamine;

1,7-bissecbutyl-diethylenetriamine;

2,2,5,5-tetramethyl diethylenetriamine;

3-amino-3-methyl-1-butanol;

2-amino-2-methyl-1-propanol;

N₁ -isopropyl-2-methyl-1,2-propanediamine;

N₁ (1,1-dimethyl-2-hydroxyethyl)-2-methyl-1,2-propanediamine; and

N₁ -isopropyl-N₂ -(3-amino-propyl)-2-methyl-1,2-propanediamine.

7. The process of claim 6 wherein the alkaline material is selected from the class consisting of potassium hydroxide, potassium carbonate, sodium hydroxide, and sodium carbonate.

8. The process of claim 6 wherein the scrubbing solution comprises about 3 to about 15 wt.% sterically hindered amine, about 15 to about 35 wt.% alkaline material and about 50 to about 80 wt.% water.

9. The process of claim 8 wherein the sterically hindered amine is N-cyclohexyl-1,3-propanediamine.

10. The process of claim 9 wherein the alkaline material comprises potassium bicarbonate.

11. A process for at least partially removing CO₂ from a gaseous feed including CO₂ comprising:

(a) contacting the gaseous feed in an absorber with a scrubbing solution comprising;

(i) about 3 to about 15 wt.% of a sterically hindered amine;

(ii) about 15 to about 35 wt.% of an alkaline material selected from the class consisting of alkali metal salts and alkali metal hydroxides; and

(iii) about 50 to about 80 wt.% of water to thereby at least partially absorb the acidic compound;

(b) passing the scrubbing solution containing the absorbed CO₂ from the absorber into a regenerator wherein the scrubbing solution is at least partially desorbed;

(c) passing the at least partially desorbed scrubbing solution from the regenerator into a reboiler, wherein the at least partially desorbed scrubbing solution is separated into an upper liquid phase relatively rich in sterically hindered amine and having a relatively high ratio of alkali bicarbonate to carbonate ratio and a lower liquid phase having a relatively low ratio of alkali bicarbonate to carbonate ratio; and

(d) directing at least a portion of the lower liquid phase from the reboiler into the absorber at a first location and directing at least a portion of the upper liquid phase from the reboiler into the absorber at a second location, the second location disposed below the first location.