Method of manufacturing embossed articles of preset configuration

• US 4,252,891 A
• Filed: 07/29/1977
• Issued: 02/24/1981
• Est. Priority Date: 07/29/1977
• Status: Expired due to Term

• Current Assignee: Maxim T. Kostyshin, Petr F. Romanenko
• Original Assignee: Maxim T. Kostyshin, Petr F. Romanenko
• Inventors: Romanenko, Petr F., Kostyshin, Maxim T.
• Primary Examiner(s): Pianalto, Bernard D.
• Application Number:
  US05/820,134
• Time in Patent Office: 1,306 Days
• Field of Search: 427/56, 96/35, 96/36, 430/273, 430/297, 430/313, 430/318, 430/325, 430/350, 430/353, 430/495
• US Class Current: 430/323
• CPC Class Codes: G03C 1/705 Compositions containing chalcogenides, metals or alloys thereof, as photosensitive substances, e.g. photodope systems used as photoresist G03F7/004

Abstract

A method of manufacturing embossed articles of a preset configuration utilizing a material sensitive to electromagnetic and corpuscular radiation. The method consists in coating a backing with a layer of metal, applying a barrier layer to the metal layer, coating the barrier layer with a layer of inorganic matter capable of interacting chemically with the metal layer and forming the products of interaction whose physical and chemical properties differ from those of the metal layer and the layer of inorganic matter, in projecting a picture of a preset configuration on the applied layers, exposure, and in the removal of the unnecessary portions of the layers until an embossed article of a preset configuration is produced. The barrier layer is made of a material different from the layer of metal and the layer of inorganic matter and inert with respect to the metal layer and the layer of inorganic matter in absence of electromagnetic and corpuscular radiation. The thickness of the barrier layer is made sufficient to prevent chemical interaction between the metal layer and the layer of inorganic matter in absence of electromagnetic and corpuscular radiation and permitting such interaction in presence of electromagnetic and corpuscular radiation.

Claims

1. A method of manufacturing embossed articles of a preset configuration with the use of material sensitive to actinic electromagnetic and corpuscular radiation consisting essentially of the following operations:

application of a metal layer to a backing;

coating said metal layer with a barrier layer consisting of matter chemically different from that of said metal layer;

coating said barrier layer with a layer of inorganic matter containing a substance selected from the group consisting of sulfur, selenium, and selenium and halogen, said inorganic matter chemically different from the barrier layer and will react chemically with said metal layer in the absence of the barrier layer to form the products of interaction whose physical and chemical properties differ from those of said metal layer and the layer of inorganic matter;

wherein the barrier layer is of sufficient thickness in the range of 20-300 A to permit said chemical interaction only in the presence of actinic electromagnetic or corpuscular radiation;

projecting a pattern of a preset configuration on said applied layers;

exposure;

removal of unnecessary portions of said layers until an embossed article of a preset configuration is produced.

2. A method of manufacturing embossed articles of a preset configuration according to claim 1 wherein said barrier layer is applied by treating the surface of the metal layer in the atmosphere of a gaseous substance selected from the group consisting of oxygen and/or fluorine, chlorine, bromine, iodine, sulphur, selenium, tellurium taken separately or in combination.

3. A method of manufacturing embossed articles of a preset configuration according to claim 1 wherein said barrier layer is applied by deposition in vacuo.

4. A method of manufacturing embossed articles of a preset configuration according to claim 1 wherein said barrier layer is applied by chemical precipitation.

5. A method of manufacturing embossed articles of a preset configuration according to claim 1 wherein said barrier layer is applied by dipping the work into a solution containing the substance of said barrier layer.

6. A method of manufacturing embossed articles of a preset configuration according to claim 1 wherein said barrier layer is applied by dipping the work into a chemically-active liquid medium.

7. A method of manufacturing embossed articles of preset configuration according to claim 1 wherein the actinic radiation is of the red and near infra-red regions of the spectrum.

8. A method of manufacturing embossed articles of a preset configuration with the use of a material sensitive to actinic electromagnetic and corpuscular radiation consisting essentially of the following operations:

applying a layer of metal to a backing;

coating said metal layer with a barrier layer consisting of matter differing from that of said metal layer;

coating said barrier layer with a layer of inorganic matter containing a substance selected from the group consisting of sulfur, selenium, and selenium and halogen, said inorganic matter differing from the matter of said barrier layer and capable of interacting chemically with said metal layer and forming the products of interaction whose physical and chemical properties differ from those of said metal layer and the layer of inorganic matter;

the thickness of said said barrier layer in the range of 20-300 A is such as to permit said chemical interaction only in the presence of said electromagnetic or corpuscular radiation;

projecting a pattern of a preset configuration on said applied layers;

exposure;

removal of unnecessary protions of said layers until the embossed article of a preset configuration is produced.

9. A method of manufacturing embossed articles of a pre-set configuration according to claim 8 wherein said barrier layer is applied by pouring.

10. A method of manufacturing embossed articles of a pre-set configuration according to claim 8 wherein said exposure is followed by removing said layer of inorganic matter that has not entered into chemical interaction with said layer of metal while said barrier layer at the non-exposed points is removed after the removal of said layer of inorganic matter.

11. A method of manufacturing embossed articles of a pre-set configuration according to claim 10 wherein the unnecessary portions of said barrier layer are removed by chemical etching.

12. A method of manufacturing embossed articles of a pre-set configuration according to claim 10 wherein the unnecessary portions of said barrier layer are removed mechanically.

13. A method of manufacturing embossed articles of a pre-set configuration according to claim 10 wherein the unnecessary portions of said barrier layer are removed by thermal sublimation.

14. A method of manufacturing embossed articles of a pre-set configuration according to claim 8, wherein during said exposure an electric field is applied to said material.

15. A method of manufacturing embossed articles of preset configuration according to claim 8 wherein the electromagnetic and corpuscular radiation is of the red and near infra-red regions of the spectrum.

16. A method of manufacturing embossed articles of a preset configuration with the use of a material sensitive to actinic electromagnetic and corpuscular radiation consisting essentially of the following operations:

applying a layer of inorganic matter containing a substance selected from the group consisting of sulfur, selenium, and selenium and halogen to a backing;

coating said layer of inorganic matter with a barrier layer consisting of matter different from that of said layer of inorganic matter;

coating said barrier layer with a layer of metal which differs from the matter of said barrier layer and is capable of interacting chemically with said layer of inorganic matter and forming the products of interaction whose physical and chemical properties differ from those of said metal layer and the layer of inorganic matter;

the thickness of said barrier layer in the range of 20-300 A is such as to permit said chemical interaction only in the presence of electromagnetic or corpuscular radiation;

projecting a pattern of a preset configuration on said applied layers;

exposure;

removal of unnecessary portions of said layers until an embossed article of a preset configuration is produced.

17. A method of manufacturing embossed articles of a pre-set configuration according to claim 16 wherein said barrier layer is applied by pouring.

18. A method of;

manufacturing embossed articles of a pre-set configuration according to claim 16 wherein said exposure is followed by removing said layer of metal that has not entered into chemical interaction with said layer of inorganic matter while said barrier layer at the non-exposed points is removed after the removal of said metal layer.

19. A method of manufacturing embossed articles of a pre-set configuration according to claim 18 wherein the unnecessary portions of said barrier layer are removed by chemical etching.

20. A method of manufacturing embossed articles of a pre-set configuration according to claim 18 wherein the unnecessary portions of said barrier layer are removed mechanically.

21. A method of manufacturing embossed articles of a pre-set configuration according to claim 18 wherein the unnecessary portions of said barrier layer are removed by thermal sublimation.

22. A method, of manufacturing embossed articles of a pre-set configuration according to claim 16, wherein during said exposure an electric field is applied to said material.

23. A method of manufacturing embossed articles of preset configuration according to claim 16 wherein the electromagnetic and corpuscular radiation is of the red and near infra-red regions of the spectrum.

24. A method for manufacturing embossed articles of a preset configuration with the use of a material sensitive to actinic electromagnetic and corpuscular radiation consisting essentially of:

applying to a backing a metal layer selected from the group consisting of silver, gold, copper, chromium, manganese and aluminum;

coating said metal layer with a barrier layer material chemically different from said metal layer and selected from the group consisting of arsenic trisulfide, chromium, germanium, diselenide, arsenic triselenide, germanium disulfide, colophony, silicon oxide, and arsenic pentasulfide;

coating said barrier layer with a layer of inorganic material containing a substance selected from the group consisting of sulfur, selenium, and selenium and halogen, wherein said inorganic material is chemically different from the material of said barrier layer and will chemically react with the metal layer in the absence of the barrier layer to form products of reaction whose physical and chemical properties differ from the metal layer and the layer of inorganic material; and

wherein the barrier layer is of sufficient thickness in the range of 20-300 A, to permit said chemical reaction only in the presence of actinic radiation;

projecting a pattern of a preset configuration on said applied layers;

exposure;

removal of unnecessary portions of said layers until an embossed article of a preset configuration is produced.

25. A method of manufacturing embossed articles of a preset configuration according to claim 24 wherein said barrier layer is applied by dipping the work into a solution containing the substance of said barrier layer.

26. A method of manufacturing embossed articles of a preset configuration according to claim 24 wherein said barrier layer is applied by dipping the work into, a chemically-active liquid medium.

27. The method of claim 24 wherein the inorganic material is selected from the group consisting of arsenic trisulfide, arsenic triselenide and germanium diselenide.

28. The method of claim 24 wherein the metal layer is selected from the group consisting of:

silver, copper, silver-manganese alloy, and gold;

the barrier layer is selected from the group consisting of;

arsenic sulfides, germanium sulfides, silicon oxide, chromium, silver and colophony; and

the inorganic layer is selected from the group consisting of;

arsenic selenides, arsenic sulfides, germanium selenides, and silver-aluminum alloys.

29. The method of claim 28 wherein the metal-barrier-inorganic layers, respectively, are selected from the group consisting of:

silver-arsenic trisulfide-arsenic triselenide,

copper-chromium-arsenic trisulfide,

silver-arsenic trisulfide-germanium diselenide,

silver-germanium disulfide-arsenic triselenide,

copper-silver-arsenic trisulfide,

copper-chromium-arsenic trisulfide,

silver-chromium-arsenic triselenide,

Ag₇₀ Mn₃₀ -colophony-As₃₅ Se₅₅ J₁₀,

copper-silicon oxide-germanium diselenide,

silver-arsenic pentasulfide-arsenic triselenide, and

gold-arsenic triselenide-silver aluminum.