Electrochromic display cell

• US 4,253,742 A
• Filed: 08/29/1979
• Issued: 03/03/1981
• Est. Priority Date: 09/25/1978
• Status: Expired due to Term

• Current Assignee: Toshiba Corporation
• Original Assignee: Toshiba Corporation
• Inventors: Morita, Hiroshi
• Primary Examiner(s): Davie, James W.
• Application Number:
  US06/070,706
• Time in Patent Office: 552 Days
• Field of Search: 350/357, 252/408
• US Class Current: 359/270
• CPC Class Codes: G02F 1/1508 using a solid electrolyte
• CPC Class Codes: G02F 1/1525 characterised by a particular ion transporting layer, e.g. electrolyte

Abstract

An electrochromic display cell comprising a display electrode, a counter electrode spaced from and facing the display electrode, and an electrochromic layer deposited on the display electrode, and a solid electrolyte layer conductive to lithium ion disposed between the electrodes. The solid electrolyte layer is formed from materials selected from the group consisting of Li₃ N, Li_2+x C_1-x B_x O₃, Li_4+x Si_1-x P_x O₄ and Li_5+x Ag_1-x Si_x O₄ where 0<x<1.

Claims

1. In an electrochromic display cell comprising

a display electrode;

a counter electrode facing said display electrode;

an electrochromic layer and an ion conductive solid electrolyte layer situated between said electrodes, the improvement comprising said ion conductive solid electrolyte layer being formed from materials selected from the group consisting of Li₃ N, Li_2+x C_1-x B_x O₃, Li_4+x Si_1-x P_x O₄ and Li_5+x AG_1-x Si_x O₄ where 0<

x<

1, wherein the charge carrier through said electrolyte layer is lithium ion.

2. An electrochromic display cell according to claim 1 wherein said ion conductive solid electrolyte layer has a thickness from about 1000A to about 3000A.

3. An electrochromic display cell according to claim 1 wherein said display electrode comprises a transparent layer and said counter electrode comprises a metal having a highly reflective surface.

4. An electrochromic display cell according to claim 1 wherein said electrochromic layer comprises tungsten oxide.

5. An electrochromic display cell according to claim 1 wherein said cell further comprises a lithium ion reserving layer means, contiguous with said ion conductive solid electrolyte, for absorbing and releasing lithium ions given off by said ion conductive solid electrolyte.

6. An electrochromic display cell according to claim 5 wherein said reserving layer means is further contiguous with said electrochromic layer.

7. An electrochromic display cell according to claim 5 wherein said reserving layer means is further contiguous with said counter electrode.

8. An electrochromic display cell according to claim 5 wherein said reserving layer means being formed from materials selected from the group consisting of Li_x WO₃ (where 0<

x<

1), polycrystaline WO₃, SiO₂, Li-Si alloy, and Li-Al alloy.