Repressurization technique for pressure swing adsorption

• US 4,256,469 A
• Filed: 11/06/1978
• Issued: 03/17/1981
• Est. Priority Date: 11/06/1978
• Status: Expired due to Term

• Current Assignee: Bergwerksverband GmbH
• Original Assignee: Linde AG (Linde Plc)
• Inventors: Leitgeb, Paul
• Primary Examiner(s): Spitzer, Robert H.
• Application Number:
  US05/957,783
• Time in Patent Office: 862 Days
• Field of Search: 55/25, 55/26, 55/58, 55/62, 55/68, 55/74, 55/75
• US Class Current: 95/96
• CPC Class Codes: B01D 2253/116 Molecular sieves other than zeolites
• CPC Class Codes: B01D 2253/25 Coated, impregnated or composite adsorbents
• CPC Class Codes: B01D 2256/10 Nitrogen
• CPC Class Codes: B01D 2257/104 Oxygen
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2257/80 Water
• CPC Class Codes: B01D 2259/40015 with two sub-steps
• CPC Class Codes: B01D 2259/4003 with two sub-steps
• CPC Class Codes: B01D 2259/40037 with two sub-steps
• CPC Class Codes: B01D 2259/40066 Six
• CPC Class Codes: B01D 2259/402 using two beds
• CPC Class Codes: B01D 53/0473 Rapid pressure swing adsorption
• CPC Class Codes: B01D 53/0476 Vacuum pressure swing adsorption
• CPC Class Codes: B01D 53/261 by adsorption
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

In a pressure swing adsorption process, the adsorbent being for example a carbon molecular sieve, the usual initial surge of an undesired component, e.g., O₂ in a nitrogen stream, from the outlet of a freshly repressurized adsorber, is reduced or eliminated by conducting repressurization in a stage-wise manner with the final part of the repressurization being conducted substantially more slowly than the initial stage of repressurization.

Claims

1. In a pressure swing adsorption process for the separation of a gaseous mixture comprising conducting the gaseous mixture under pressure over a carbon molecular sieve adsorbent in a pressurized adsorber having an inlet and an outlet, said adsorbent being capable of adsorbing at least one component selectively over the other components;

discharging from said outlet a gaseous stream enriched in one or more other components;

lowering the pressure above the adsorbent for regenerating purposes wit liberation of a gaseous stream enriched in at least the one component;

repressurizing the adsorber; and

repeating the cycle thereover, the improvement which comprises conducting said repressurizing in at least two stages, wherein the pressure buildup in the first stage or stages to an intermediate pressure is effected relatively rapidly, and the pressure buildup in the last stage to the final adsorption pressure is conducted substantially more gradually, said improvement resulting in the diminution of a surge of undesired component in the initial stream discharged from the repressurized bed.

2. A process according to claim 1, wherein the pressure buildup in the last stage is conducted with unseparated gaseous mixture passed in to the inlet of the adsorber.

3. A process according to claim 2, wherein during the pressure buildup in the last stage, a gaseous stream enriched in one or more other components is discharged from the outlet of the adsorber.

4. A process according to claim 3, wherein the end of the pressure buildup in the last stage coincides with the end of the adsorption cycle.

5. A process according to claim 2 comprising a three-stage pressure buildup, the pressure buildup in the second stage also being conducted by passing unseparated gaseous mixture into the adsorber.

6. A process according to claim 1, wherein a complete cycle is conducted in about 2 minutes, the pressure buildup in the first stages is conducted in 2 to 5 seconds, and the pressure buildup on the last stage is conducted in 20 to 30 seconds.

7. A process according to claim 1, wherein a complete cycle is conducted in about 2 minutes, the pressure buildup in the first stages is conducted in 2 to 5 seconds and the pressure buildup in the last stage is conducted in 20 seconds up to the end of the adsorption cycle.

8. A process according to claim 1, wherein the pressure ratio between the adsorption pressure and the desorption pressure is 4:

1 to 8;

1.

9. A process according to claim 1, wherein the pressure ratio between the adsorption pressure and the desorption pressure is 4:

1 to 20;

1.

10. A process according to claim 1, wherein the pressure ratio between the adsorption pressure and the desorption pressure is about 20:

1 to 60;

1.

11. A process according to claim 1, wherein in the first stage or stages the pressure is increased to 40 to 70% of the total adsorption pressure in 3 to 10% of the total time, and in the second stage the pressure is increased to 70 to 100% of the total adsorption pressure in 30 to 85% of the total time, and in the third stage the final adsorption pressure is achieved in 70 to 15% of the total time.

12. A process according to claim 11, wherein the total repressurization occurs in 5 to 60 seconds.

13. A process according to claim 12, wherein the total repressurization occurs in 30 to 60 seconds.

14. A process according to claim 1, wherein the gaseous mixture comprises air and wherein oxygen is preferentially adsorbed over the carbon molecular sieve adsorbent, thereby producing nitrogen-enriched gas.

15. A process according to claim 14, wherein the nitrogen enriched gas has a residual oxygen content of 0.1 to 5% by volume.

16. A process according to claim 1, wherein the adsorption pressure is 2 to 14 bars.

17. A process according to claim 16, wherein the adsorption pressure is 4 to 10 bars.