Method of manufacture of material reinforced with a three-dimensional textile structure

• US 4,257,835 A
• Filed: 07/30/1979
• Issued: 03/24/1981
• Est. Priority Date: 08/08/1978
• Status: Expired due to Term

• Current Assignee: Commissariat a L'Energie Atomique (AES Corporation)
• Original Assignee: Commissariat a L'Energie Atomique (AES Corporation)
• Inventors: Bompard, Bruno
• Primary Examiner(s): Powell, William A.
• Assistant Examiner(s): Dawson, Robert A.
• Application Number:
  US06/062,020
• Time in Patent Office: 603 Days
• Field of Search: 112/403, 112/417, 156/92, 156/93, 156/148, 156/155, 156/252, 156/253, 156/296, 428/102, 428/137, 428/223, 428/238, 428/239, 428/902, 428/367, 428/368, 428/218, 264/29.1, 264/29.2, 264/29.5
• US Class Current: 156/92
• CPC Class Codes: B29C 70/24 oriented in at least three directions forming a three dimensional structure
• CPC Class Codes: B29C 70/545 Perforating, cutting or machining during or after moulding
• CPC Class Codes: C04B 35/83 Carbon fibres in a carbon matrix
• CPC Class Codes: D04H 3/002 Inorganic yarns or filaments
• CPC Class Codes: D04H 3/004 Glass yarns or filaments
• CPC Class Codes: D04H 3/005 Synthetic yarns or filaments D04H3/013 takes precedence
• CPC Class Codes: D04H 3/04 in rectilinear paths, e.g. crossing at right angles
• CPC Class Codes: D04H 3/12 with filaments or yarns secured together by chemical or thermo-activatable bonding agents, e.g. adhesives, applied or incorporated in liquid or solid form
• CPC Class Codes: F16D 69/023 Composite materials containing carbon and carbon fibres or fibres made of carbonizable material
• CPC Class Codes: F16D 69/026 containing fibres
• CPC Class Codes: Y10S 428/902 High modulus filament or fiber
• CPC Class Codes: Y10T 156/1056 Perforating lamina
• CPC Class Codes: Y10T 428/24322 Composite web or sheet
• CPC Class Codes: Y10T 428/24992 Density or compression of components
• CPC Class Codes: Y10T 428/249923 Including interlaminar mechanical fastener
• CPC Class Codes: Y10T 428/2918 including free carbon or carbide or therewith [not as steel]
• CPC Class Codes: Y10T 428/292 In coating or impregnation
• CPC Class Codes: Y10T 428/30 Self-sustaining carbon mass or layer with impregnant or other layer

Abstract

The method consists in realizing densified layers of fibers, in forming a stack with said layers of fibers provided with holes and so arranged that the fibers of the layers extend within the stack in at least two directions designated as first and second directions which define the plane of the layers and that the holes form passages within the stack in a third direction, in implanting in said passages fibers which extend in the third direction, and in increasing the density of the assembly, for example by filling the gaps of the structure with a resin or a carbon matrix.

Claims

1. A method of manufacture of material reinforced with a three-dimensional textile structure, wherein said method consists:

(a) in realizing densified layers of fibers,

(b) in forming a stack of layers from said fibers provided with holes and so arranged that the fibers of said layers extend within said stack in at least two directions designated as first and second directions which define the plane of the layers and that said holes form within said stack passages which extend in a third direction, each passage having a given dimension,

(c) in implanting in said passages rods constituted by an assembly of densified fibers, said rods extending in the third direction,

(d) in increasing the density of the assembly thus obtained.

2. A method according to claim 1, wherein said stack is formed by means of layers of densified fibers by placing said layers one above the other and then by perforating the layers which have thus been stacked so as to form in said stack the passages which extend in the third direction.

3. A method according to claim 1, wherein said stack is formed by means of densified layers of fibers by perforating said layers beforehand, the layers which have thus been perforated being then placed one above the other in such a manner as to ensure that the perforations of the successive layers form within said stack the passages which extend in the third direction.

4. A method according to claim 1, wherein said densified layers of fibers are constituted by a two-directional fabric.

5. A method according to claim 1, wherein the densified layers of fibers are constituted by densified parallel fibers.

6. A method according to claim 1, wherein the stack is realized by placing densified layers of fibers constituted by a densified two-directional fabric and densified layers of fibers constituted by densified parallel fibers one above the other.

7. A method according to claim 1, wherein said densified layers of fibers are obtained by impregnating layers of fibers with a polymerizable or pyrolyzable resin and by subsequently polymerizing or pyrolyzing said resin to a partial extent.

8. A method according to claim 1, wherein each rod is constituted by an assembly of densified parallel fibers held together by means of a prepolymerized resin.

9. A method according to claim 1, wherein the assembly thus obtained is densified by impregnation with a polymerizable or pyrolyzable resin and by then polymerizing or pyrolyzing said resin.

10. A method according to claim 1, wherein the assembly thus obtained is densified by depositing pyrolytic carbon from a flow of gaseous hydrocarbon.

11. A method according to claim 1, wherein said fibers are selected from the group comprising carbon fibers, graphite fibers, glass fibers, silica fibers and aromatic fibers.

12. A method according to claim 7, wherein said resin is selected from the group comprising the phenolic resins, the epoxy resins, the polyester resins and polyvinyl acetate.

13. A method of manufacture of material reinforced with a three-dimension textile structure, wherein said method consists:

(a) in realizing densified layers of fibers by one of the means consisting of impregnating said layers of fibers with a polymerizable resin and then polymerizing said resin to a partial extent, and impregnating said layers of fibers with a pyrolyzable resin and then pyrolyzing said resin to a partial extent,

(b) in forming calibrated rods constituted by an assembly of densified parallel fibers held together by means of a prepolymerized resin,

(c) in forming a stack with said layers of fibers, said layers being provided with holes and so arranged that the fibers of said layers extend within said stack in at least two directions designated as first and second directions, which define the plane of the layers and that said holes form within said stack passages which extend in a third direction, each passage having a given diameter,

(d) in implanting said rods in said passages, said rods being calibrated to the diameter of the passages, whereby the latters are completely filled by the rods, to define a three-dimensional assembly, and

(e) densifying this assembly by one of the means consisting of impregnating the assembly with a polymerizable resin and then polymerizing said resin, impregnating the assembly with a pyrolyzable resin and then pyrolyzing said resin, and depositing pyrolytic carbon from a flow of gaseous hydrocarbon.